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Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements. / Demakov, P. A.; Sapchenko, S. A.; Samsonenko, D. G. et al.

In: Journal of Structural Chemistry, Vol. 60, No. 5, 01.05.2019, p. 815-822.

Research output: Contribution to journal › Article › peer-review

Harvard

Demakov, PA, Sapchenko, SA, Samsonenko, DG, Dybtsev, DN & Fedin, VP 2019, 'Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements', Journal of Structural Chemistry, vol. 60, no. 5, pp. 815-822. https://doi.org/10.1134/S0022476619050159

APA

Demakov, P. A., Sapchenko, S. A., Samsonenko, D. G., Dybtsev, D. N., & Fedin, V. P. (2019). Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements. Journal of Structural Chemistry, 60(5), 815-822. https://doi.org/10.1134/S0022476619050159

Vancouver

Demakov PA, Sapchenko SA, Samsonenko DG, Dybtsev DN, Fedin VP. Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements. Journal of Structural Chemistry. 2019 May 1;60(5):815-822. doi: 10.1134/S0022476619050159

Author

Demakov, P. A. ; Sapchenko, S. A. ; Samsonenko, D. G. et al. / Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements. In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 5. pp. 815-822.

BibTeX

@article{f4ff00de28ec47b7ae0f9327f64460bf,
title = "Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements",
abstract = "By a reaction of lanthanide nitrates with trans-1,4-cyclohexane dicarboxylic acid H2chdc in an aqueous medium new coordination polymers with the composition [Ln2(H2O)4(chdc)3] (Ln = Ce (1), Sm (2), Eu (3), Gd (4)) are obtained. Crystallization conditions are optimized with the use of a hexamine-based pH buffer. Compound 1 is additionally characterized by powder X-ray diffraction, elemental and thermogravimetric analyses, and IR spectroscopy. The structure of the obtained compounds is determined by single crystal X-ray diffraction. In a series of isostructural three-dimensional frameworks [Ln2(H2O)4(chdc)3] (Ln = La—Eu, except Pm) a regular change in the structural features is analyzed. The [Gd2(H2O)4(chdc)3] compound has a similar composition but the topology of the three-dimensional network differs from that of the previous ones due to a decrease in the coordination number of metal centers. Heavier lanthanides, starting from Tb3+, and also yttrium(III) do not form compounds with the mentioned composition under similar reaction conditions.",
keywords = "coordination polymers, lanthanide compression, lanthanides, metal-organic frameworks, single crystal X-ray diffraction analysis",
author = "Demakov, {P. A.} and Sapchenko, {S. A.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",
year = "2019",
month = may,
day = "1",
doi = "10.1134/S0022476619050159",
language = "English",
volume = "60",
pages = "815--822",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "5",

}

RIS

TY - JOUR

T1 - Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements

AU - Demakov, P. A.

AU - Sapchenko, S. A.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2019/5/1

Y1 - 2019/5/1

N2 - By a reaction of lanthanide nitrates with trans-1,4-cyclohexane dicarboxylic acid H2chdc in an aqueous medium new coordination polymers with the composition [Ln2(H2O)4(chdc)3] (Ln = Ce (1), Sm (2), Eu (3), Gd (4)) are obtained. Crystallization conditions are optimized with the use of a hexamine-based pH buffer. Compound 1 is additionally characterized by powder X-ray diffraction, elemental and thermogravimetric analyses, and IR spectroscopy. The structure of the obtained compounds is determined by single crystal X-ray diffraction. In a series of isostructural three-dimensional frameworks [Ln2(H2O)4(chdc)3] (Ln = La—Eu, except Pm) a regular change in the structural features is analyzed. The [Gd2(H2O)4(chdc)3] compound has a similar composition but the topology of the three-dimensional network differs from that of the previous ones due to a decrease in the coordination number of metal centers. Heavier lanthanides, starting from Tb3+, and also yttrium(III) do not form compounds with the mentioned composition under similar reaction conditions.

AB - By a reaction of lanthanide nitrates with trans-1,4-cyclohexane dicarboxylic acid H2chdc in an aqueous medium new coordination polymers with the composition [Ln2(H2O)4(chdc)3] (Ln = Ce (1), Sm (2), Eu (3), Gd (4)) are obtained. Crystallization conditions are optimized with the use of a hexamine-based pH buffer. Compound 1 is additionally characterized by powder X-ray diffraction, elemental and thermogravimetric analyses, and IR spectroscopy. The structure of the obtained compounds is determined by single crystal X-ray diffraction. In a series of isostructural three-dimensional frameworks [Ln2(H2O)4(chdc)3] (Ln = La—Eu, except Pm) a regular change in the structural features is analyzed. The [Gd2(H2O)4(chdc)3] compound has a similar composition but the topology of the three-dimensional network differs from that of the previous ones due to a decrease in the coordination number of metal centers. Heavier lanthanides, starting from Tb3+, and also yttrium(III) do not form compounds with the mentioned composition under similar reaction conditions.

KW - coordination polymers

KW - lanthanide compression

KW - lanthanides

KW - metal-organic frameworks

KW - single crystal X-ray diffraction analysis

UR - http://www.scopus.com/inward/record.url?scp=85067351270&partnerID=8YFLogxK

U2 - 10.1134/S0022476619050159

DO - 10.1134/S0022476619050159

M3 - Article

AN - SCOPUS:85067351270

VL - 60

SP - 815

EP - 822

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 20584023