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From oxide to a new type of molecular tungsten compound : formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−. / Yarovoy, Spartak S.; Smolentsev, Anton I.; Kozlova, Svetlana G. et al.

In: Chemical Communications, Vol. 54, No. 98, 21.12.2018, p. 13837-13840.

Research output: Contribution to journal › Article › peer-review

Harvard

Yarovoy, SS, Smolentsev, AI, Kozlova, SG, Kompankov, NB, Gayfulin, YM, Asanov, IP, Yanshole, VV & Mironov, YV 2018, 'From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−', Chemical Communications, vol. 54, no. 98, pp. 13837-13840. https://doi.org/10.1039/c8cc07746k

APA

Yarovoy, S. S., Smolentsev, A. I., Kozlova, S. G., Kompankov, N. B., Gayfulin, Y. M., Asanov, I. P., Yanshole, V. V., & Mironov, Y. V. (2018). From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−. Chemical Communications, 54(98), 13837-13840. https://doi.org/10.1039/c8cc07746k

Vancouver

Yarovoy SS, Smolentsev AI, Kozlova SG, Kompankov NB, Gayfulin YM, Asanov IP et al. From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−. Chemical Communications. 2018 Dec 21;54(98):13837-13840. doi: 10.1039/c8cc07746k

Author

Yarovoy, Spartak S. ; Smolentsev, Anton I. ; Kozlova, Svetlana G. et al. / From oxide to a new type of molecular tungsten compound : formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−. In: Chemical Communications. 2018 ; Vol. 54, No. 98. pp. 13837-13840.

BibTeX

@article{b768f4b535ed451da807926fb0f81dfe,
title = "From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−",
abstract = "Tungsten trioxide has been found to be a convenient precursor for the synthesis of metal cluster compounds with new types of cluster cores. The reaction between WO3 and KCN led to the formation of the cluster complex [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10−. Unexpectedly, it includes the fully deprotonated form of acetonitrile, the CCN3− anion, as a μ3-bridging ligand coordinated to the trigonal faces of the bitetrahedral W6 metallocluster. A similar complex [{W6(μ4-O)2(μ3-As)4}(CN)16]10− containing μ3-As3− ligands instead of μ3-CCN3− ones has been synthesized by the reaction between WO3, As and KCN.",
keywords = "STRUCTURAL-CHARACTERIZATION, CYANO COMPLEXES, MOLYBDENUM",
author = "Yarovoy, {Spartak S.} and Smolentsev, {Anton I.} and Kozlova, {Svetlana G.} and Kompankov, {Nikolay B.} and Gayfulin, {Yakov M.} and Asanov, {Igor P.} and Yanshole, {Vadim V.} and Mironov, {Yuri V.}",
note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",
year = "2018",
month = dec,
day = "21",
doi = "10.1039/c8cc07746k",
language = "English",
volume = "54",
pages = "13837--13840",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "98",

}

RIS

TY - JOUR

T1 - From oxide to a new type of molecular tungsten compound

T2 - formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−

AU - Yarovoy, Spartak S.

AU - Smolentsev, Anton I.

AU - Kozlova, Svetlana G.

AU - Kompankov, Nikolay B.

AU - Gayfulin, Yakov M.

AU - Asanov, Igor P.

AU - Yanshole, Vadim V.

AU - Mironov, Yuri V.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2018/12/21

Y1 - 2018/12/21

N2 - Tungsten trioxide has been found to be a convenient precursor for the synthesis of metal cluster compounds with new types of cluster cores. The reaction between WO3 and KCN led to the formation of the cluster complex [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10−. Unexpectedly, it includes the fully deprotonated form of acetonitrile, the CCN3− anion, as a μ3-bridging ligand coordinated to the trigonal faces of the bitetrahedral W6 metallocluster. A similar complex [{W6(μ4-O)2(μ3-As)4}(CN)16]10− containing μ3-As3− ligands instead of μ3-CCN3− ones has been synthesized by the reaction between WO3, As and KCN.

AB - Tungsten trioxide has been found to be a convenient precursor for the synthesis of metal cluster compounds with new types of cluster cores. The reaction between WO3 and KCN led to the formation of the cluster complex [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10−. Unexpectedly, it includes the fully deprotonated form of acetonitrile, the CCN3− anion, as a μ3-bridging ligand coordinated to the trigonal faces of the bitetrahedral W6 metallocluster. A similar complex [{W6(μ4-O)2(μ3-As)4}(CN)16]10− containing μ3-As3− ligands instead of μ3-CCN3− ones has been synthesized by the reaction between WO3, As and KCN.

KW - STRUCTURAL-CHARACTERIZATION

KW - CYANO COMPLEXES

KW - MOLYBDENUM

UR - http://www.scopus.com/inward/record.url?scp=85058076987&partnerID=8YFLogxK

U2 - 10.1039/c8cc07746k

DO - 10.1039/c8cc07746k

M3 - Article

C2 - 30467571

AN - SCOPUS:85058076987

VL - 54

SP - 13837

EP - 13840

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 98

ER -

ID: 17822584