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Formation of Active Sites of Carbon Nanofibers Growth in Self-Organizing Ni-Pd Catalyst during Hydrogen-Assisted Decomposition of 1,2-Dichloroethane. / Bauman, Yurii I.; Mishakov, Ilya V.; Rudneva, Yulia V. et al.

In: Industrial and Engineering Chemistry Research, Vol. 58, No. 2, 16.01.2019, p. 685-694.

Research output: Contribution to journal › Article › peer-review

Harvard

Bauman, YI, Mishakov, IV, Rudneva, YV, Plyusnin, PE, Shubin, YV, Korneev, DV & Vedyagin, AA 2019, 'Formation of Active Sites of Carbon Nanofibers Growth in Self-Organizing Ni-Pd Catalyst during Hydrogen-Assisted Decomposition of 1,2-Dichloroethane', Industrial and Engineering Chemistry Research, vol. 58, no. 2, pp. 685-694. https://doi.org/10.1021/acs.iecr.8b02186

APA

Bauman, Y. I., Mishakov, I. V., Rudneva, Y. V., Plyusnin, P. E., Shubin, Y. V., Korneev, D. V., & Vedyagin, A. A. (2019). Formation of Active Sites of Carbon Nanofibers Growth in Self-Organizing Ni-Pd Catalyst during Hydrogen-Assisted Decomposition of 1,2-Dichloroethane. Industrial and Engineering Chemistry Research, 58(2), 685-694. https://doi.org/10.1021/acs.iecr.8b02186

Vancouver

Bauman YI, Mishakov IV, Rudneva YV, Plyusnin PE, Shubin YV, Korneev DV et al. Formation of Active Sites of Carbon Nanofibers Growth in Self-Organizing Ni-Pd Catalyst during Hydrogen-Assisted Decomposition of 1,2-Dichloroethane. Industrial and Engineering Chemistry Research. 2019 Jan 16;58(2):685-694. doi: 10.1021/acs.iecr.8b02186

Author

Bauman, Yurii I. ; Mishakov, Ilya V. ; Rudneva, Yulia V. et al. / Formation of Active Sites of Carbon Nanofibers Growth in Self-Organizing Ni-Pd Catalyst during Hydrogen-Assisted Decomposition of 1,2-Dichloroethane. In: Industrial and Engineering Chemistry Research. 2019 ; Vol. 58, No. 2. pp. 685-694.

BibTeX

@article{27e54f89744a42059158c9c219e11d82,
title = "Formation of Active Sites of Carbon Nanofibers Growth in Self-Organizing Ni-Pd Catalyst during Hydrogen-Assisted Decomposition of 1,2-Dichloroethane",
abstract = "The Ni-Pd alloys synthesized by the coprecipitation method were studied as precursors for the self-organizing particles catalyzing the growth of carbon nanofibers. The addition of palladium was found to enhance both the activity, stability, and productivity of the catalyst in the hydrogen-assisted decomposition of 1,2-dichloroethane. The evolution of reflex (331) for the 95Ni-5Pd sample treated under the reaction conditions has revealed the formation of the interstitial solid solution phase NixPd1-xCδ. According to data of scanning electron microscopy, the formation of separated particles active in carbon growth takes place by 18th minute of exposure with the reaction mixture. After 60 min of interaction the bulk Ni-Pd alloy undergoes complete disintegration with formation of dispersed active centers sized in a range of 0.4-0.6 μm. The elemental mapping of the formed particles showed that palladium is uniformly distributed within the bulk of active particles. The obtained carbon product is represented by prolonged carbon fibers with segmental structure.",
keywords = "IRON-SUBGROUP METALS, CHLORINATED HYDROCARBONS, NICKEL, ALLOYS, GAS, CO, HYDRODECHLORINATION, DEACTIVATION, REACTIVITY, MORPHOLOGY",
author = "Bauman, {Yurii I.} and Mishakov, {Ilya V.} and Rudneva, {Yulia V.} and Plyusnin, {Pavel E.} and Shubin, {Yury V.} and Korneev, {Denis V.} and Vedyagin, {Aleksey A.}",
year = "2019",
month = jan,
day = "16",
doi = "10.1021/acs.iecr.8b02186",
language = "English",
volume = "58",
pages = "685--694",
journal = "Industrial & Engineering Chemistry Research",
issn = "0888-5885",
publisher = "American Chemical Society",
number = "2",

}

RIS

TY - JOUR

T1 - Formation of Active Sites of Carbon Nanofibers Growth in Self-Organizing Ni-Pd Catalyst during Hydrogen-Assisted Decomposition of 1,2-Dichloroethane

AU - Bauman, Yurii I.

AU - Mishakov, Ilya V.

AU - Rudneva, Yulia V.

AU - Plyusnin, Pavel E.

AU - Shubin, Yury V.

AU - Korneev, Denis V.

AU - Vedyagin, Aleksey A.

PY - 2019/1/16

Y1 - 2019/1/16

N2 - The Ni-Pd alloys synthesized by the coprecipitation method were studied as precursors for the self-organizing particles catalyzing the growth of carbon nanofibers. The addition of palladium was found to enhance both the activity, stability, and productivity of the catalyst in the hydrogen-assisted decomposition of 1,2-dichloroethane. The evolution of reflex (331) for the 95Ni-5Pd sample treated under the reaction conditions has revealed the formation of the interstitial solid solution phase NixPd1-xCδ. According to data of scanning electron microscopy, the formation of separated particles active in carbon growth takes place by 18th minute of exposure with the reaction mixture. After 60 min of interaction the bulk Ni-Pd alloy undergoes complete disintegration with formation of dispersed active centers sized in a range of 0.4-0.6 μm. The elemental mapping of the formed particles showed that palladium is uniformly distributed within the bulk of active particles. The obtained carbon product is represented by prolonged carbon fibers with segmental structure.

AB - The Ni-Pd alloys synthesized by the coprecipitation method were studied as precursors for the self-organizing particles catalyzing the growth of carbon nanofibers. The addition of palladium was found to enhance both the activity, stability, and productivity of the catalyst in the hydrogen-assisted decomposition of 1,2-dichloroethane. The evolution of reflex (331) for the 95Ni-5Pd sample treated under the reaction conditions has revealed the formation of the interstitial solid solution phase NixPd1-xCδ. According to data of scanning electron microscopy, the formation of separated particles active in carbon growth takes place by 18th minute of exposure with the reaction mixture. After 60 min of interaction the bulk Ni-Pd alloy undergoes complete disintegration with formation of dispersed active centers sized in a range of 0.4-0.6 μm. The elemental mapping of the formed particles showed that palladium is uniformly distributed within the bulk of active particles. The obtained carbon product is represented by prolonged carbon fibers with segmental structure.

KW - IRON-SUBGROUP METALS

KW - CHLORINATED HYDROCARBONS

KW - NICKEL

KW - ALLOYS

KW - GAS

KW - CO

KW - HYDRODECHLORINATION

KW - DEACTIVATION

KW - REACTIVITY

KW - MORPHOLOGY

UR - http://www.scopus.com/inward/record.url?scp=85052308055&partnerID=8YFLogxK

U2 - 10.1021/acs.iecr.8b02186

DO - 10.1021/acs.iecr.8b02186

M3 - Article

AN - SCOPUS:85052308055

VL - 58

SP - 685

EP - 694

JO - Industrial & Engineering Chemistry Research

JF - Industrial & Engineering Chemistry Research

SN - 0888-5885

IS - 2

ER -

ID: 18291926