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Formal Kinetic Description of Photocatalytic Hydrogen Evolution from Ethanol Aqueous Solutions in the Presence of Sodium Hydroxide. / Markovskaya, D. V.; Kozlova, E. A.

In: Kinetics and Catalysis, Vol. 59, No. 6, 01.11.2018, p. 727-734.

Research output: Contribution to journal › Article › peer-review

Harvard

Markovskaya, DV & Kozlova, EA 2018, 'Formal Kinetic Description of Photocatalytic Hydrogen Evolution from Ethanol Aqueous Solutions in the Presence of Sodium Hydroxide', Kinetics and Catalysis, vol. 59, no. 6, pp. 727-734. https://doi.org/10.1134/S0023158418060101

APA

Markovskaya, D. V., & Kozlova, E. A. (2018). Formal Kinetic Description of Photocatalytic Hydrogen Evolution from Ethanol Aqueous Solutions in the Presence of Sodium Hydroxide. Kinetics and Catalysis, 59(6), 727-734. https://doi.org/10.1134/S0023158418060101

Vancouver

Markovskaya DV, Kozlova EA. Formal Kinetic Description of Photocatalytic Hydrogen Evolution from Ethanol Aqueous Solutions in the Presence of Sodium Hydroxide. Kinetics and Catalysis. 2018 Nov 1;59(6):727-734. doi: 10.1134/S0023158418060101

Author

Markovskaya, D. V. ; Kozlova, E. A. / Formal Kinetic Description of Photocatalytic Hydrogen Evolution from Ethanol Aqueous Solutions in the Presence of Sodium Hydroxide. In: Kinetics and Catalysis. 2018 ; Vol. 59, No. 6. pp. 727-734.

BibTeX

@article{2f3d785f193f48e69c41cdd3fb6e05aa,
title = "Formal Kinetic Description of Photocatalytic Hydrogen Evolution from Ethanol Aqueous Solutions in the Presence of Sodium Hydroxide",
abstract = " Abstract: The dependences of the rate of the photocatalytic hydrogen production in ethanol aqueous solutions on the concentration of ethanol and sodium hydroxide on the 1% Pt/10% Ni(OH) 2 /Cd 0.3 Zn 0.7 S photocatalyst under visible light irradiation (λ = 450 nm) are studied. To describe kinetic data, the Langmuir–Hinshelwood equation was modified. An equation was proposed that reflects the dependence of the reaction rate on the concentration of NaOH, and an equation was derived for the first time that shows the dependence of the rate of photocatalytic hydrogen production from the concentrations of both reactants, ethanol and sodium hydroxide. The validity of the proposed equations was confirmed by their use for the description of the experimental data obtained in this work and reported earlier. ",
keywords = "Cd Zn S, hydrogen production, Langmuir–Hinshelwood equation, photocatalysis, simulations, ACID, MECHANISM, GLYCEROL, DECOMPOSITION, ZINC SULFIDES, H-2, Langmuir-Hinshelwood equation, IRRADIATION, CADMIUM, Cd1-xZnxS, GLUCOSE, GENERATION",
author = "Markovskaya, {D. V.} and Kozlova, {E. A.}",
note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",
year = "2018",
month = nov,
day = "1",
doi = "10.1134/S0023158418060101",
language = "English",
volume = "59",
pages = "727--734",
journal = "Kinetics and Catalysis",
issn = "0023-1584",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "6",

}

RIS

TY - JOUR

T1 - Formal Kinetic Description of Photocatalytic Hydrogen Evolution from Ethanol Aqueous Solutions in the Presence of Sodium Hydroxide

AU - Markovskaya, D. V.

AU - Kozlova, E. A.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - Abstract: The dependences of the rate of the photocatalytic hydrogen production in ethanol aqueous solutions on the concentration of ethanol and sodium hydroxide on the 1% Pt/10% Ni(OH) 2 /Cd 0.3 Zn 0.7 S photocatalyst under visible light irradiation (λ = 450 nm) are studied. To describe kinetic data, the Langmuir–Hinshelwood equation was modified. An equation was proposed that reflects the dependence of the reaction rate on the concentration of NaOH, and an equation was derived for the first time that shows the dependence of the rate of photocatalytic hydrogen production from the concentrations of both reactants, ethanol and sodium hydroxide. The validity of the proposed equations was confirmed by their use for the description of the experimental data obtained in this work and reported earlier.

AB - Abstract: The dependences of the rate of the photocatalytic hydrogen production in ethanol aqueous solutions on the concentration of ethanol and sodium hydroxide on the 1% Pt/10% Ni(OH) 2 /Cd 0.3 Zn 0.7 S photocatalyst under visible light irradiation (λ = 450 nm) are studied. To describe kinetic data, the Langmuir–Hinshelwood equation was modified. An equation was proposed that reflects the dependence of the reaction rate on the concentration of NaOH, and an equation was derived for the first time that shows the dependence of the rate of photocatalytic hydrogen production from the concentrations of both reactants, ethanol and sodium hydroxide. The validity of the proposed equations was confirmed by their use for the description of the experimental data obtained in this work and reported earlier.

KW - Cd Zn S

KW - hydrogen production

KW - Langmuir–Hinshelwood equation

KW - photocatalysis

KW - simulations

KW - ACID

KW - MECHANISM

KW - GLYCEROL

KW - DECOMPOSITION

KW - ZINC SULFIDES

KW - H-2

KW - Langmuir-Hinshelwood equation

KW - IRRADIATION

KW - CADMIUM

KW - Cd1-xZnxS

KW - GLUCOSE

KW - GENERATION

UR - http://www.scopus.com/inward/record.url?scp=85062590803&partnerID=8YFLogxK

U2 - 10.1134/S0023158418060101

DO - 10.1134/S0023158418060101

M3 - Article

AN - SCOPUS:85062590803

VL - 59

SP - 727

EP - 734

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

SN - 0023-1584

IS - 6

ER -

ID: 18816401