Research output: Contribution to journal › Article › peer-review
Fluorinated graphene nanoparticles with 1-3 nm electrically active graphene quantum dots. / Nebogatikova, Nadezhda A.; Antonova, Irina V.; Ivanov, Artem I. et al.
In: Nanotechnology, Vol. 31, No. 29, 295602, 01.05.2020.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Fluorinated graphene nanoparticles with 1-3 nm electrically active graphene quantum dots
AU - Nebogatikova, Nadezhda A.
AU - Antonova, Irina V.
AU - Ivanov, Artem I.
AU - Demin, Victor A.
AU - Kvashnin, Dmitry G.
AU - Olejniczak, Andrzej
AU - Gutakovskii, Anton K.
AU - Kornieieva, Kateryna A.
AU - Renault, Paul L.J.
AU - Skuratov, Vladimir A.
AU - Chernozatonskii, Leonid A.
N1 - Publisher Copyright: © 2020 IOP Publishing Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/5/1
Y1 - 2020/5/1
N2 - A new approach to creating a new and locally nanostructured graphene-based material is reported. We studied the electric and structural properties of partially fluorinated graphene (FG) films obtained from an FG-suspension and nanostructured by high-energy Xe ions. Local shock heating in ion tracks is suggested to be the main force driving the changes. It was found that ion irradiation leads to the formation of locally thermally expanded FG and its cracking into nanoparticles with small (∼1.5-3 nm) graphene quantum dots (GQD), embedded in them. The bandgap of GQD was estimated as 1 -1.5 eV. A further developed approach was applied to correct the functional properties of printed FG-based crossbar memristors. Dielectric FG films with small quantum dots may offer prospects in graphene-based electronics due to their stability and promising properties.
AB - A new approach to creating a new and locally nanostructured graphene-based material is reported. We studied the electric and structural properties of partially fluorinated graphene (FG) films obtained from an FG-suspension and nanostructured by high-energy Xe ions. Local shock heating in ion tracks is suggested to be the main force driving the changes. It was found that ion irradiation leads to the formation of locally thermally expanded FG and its cracking into nanoparticles with small (∼1.5-3 nm) graphene quantum dots (GQD), embedded in them. The bandgap of GQD was estimated as 1 -1.5 eV. A further developed approach was applied to correct the functional properties of printed FG-based crossbar memristors. Dielectric FG films with small quantum dots may offer prospects in graphene-based electronics due to their stability and promising properties.
KW - nanostructuring
KW - graphene quantum dots
KW - fluorinated graphene
KW - swift ion irradiation
KW - molecular dynamics simulation
KW - memristor
KW - HEAVY-ION IRRADIATION
KW - THERMAL-CONDUCTIVITY
KW - CARBON
KW - FILMS
KW - DYNAMICS
KW - fluorinated grapheme
UR - http://www.scopus.com/inward/record.url?scp=85084693477&partnerID=8YFLogxK
U2 - 10.1088/1361-6528/ab83b8
DO - 10.1088/1361-6528/ab83b8
M3 - Article
C2 - 32213679
AN - SCOPUS:85084693477
VL - 31
JO - Nanotechnology
JF - Nanotechnology
SN - 0957-4484
IS - 29
M1 - 295602
ER -
ID: 24301796