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Fist oxidovanadium complexes containing chiral derivatives of dihydrophenanthroline and diazafluorene. / Fomenko, Yakov S.; Gushchin, Artem L.; Tkachev, Aleksey V. et al.

In: Polyhedron, Vol. 135, 15.10.2017, p. 96-100.

Research output: Contribution to journal › Article › peer-review

Harvard

Fomenko, YS, Gushchin, AL, Tkachev, AV, Vasilyev, ES, Abramov, PA, Nadolinny, VA, Syrokvashin, MM & Sokolov, MN 2017, 'Fist oxidovanadium complexes containing chiral derivatives of dihydrophenanthroline and diazafluorene', Polyhedron, vol. 135, pp. 96-100. https://doi.org/10.1016/j.poly.2017.07.003

APA

Fomenko, Y. S., Gushchin, A. L., Tkachev, A. V., Vasilyev, E. S., Abramov, P. A., Nadolinny, V. A., Syrokvashin, M. M., & Sokolov, M. N. (2017). Fist oxidovanadium complexes containing chiral derivatives of dihydrophenanthroline and diazafluorene. Polyhedron, 135, 96-100. https://doi.org/10.1016/j.poly.2017.07.003

Vancouver

Fomenko YS, Gushchin AL, Tkachev AV, Vasilyev ES, Abramov PA, Nadolinny VA et al. Fist oxidovanadium complexes containing chiral derivatives of dihydrophenanthroline and diazafluorene. Polyhedron. 2017 Oct 15;135:96-100. doi: 10.1016/j.poly.2017.07.003

Author

Fomenko, Yakov S. ; Gushchin, Artem L. ; Tkachev, Aleksey V. et al. / Fist oxidovanadium complexes containing chiral derivatives of dihydrophenanthroline and diazafluorene. In: Polyhedron. 2017 ; Vol. 135. pp. 96-100.

BibTeX

@article{716e7826ee3d42feb30d60bf43d677f9,
title = "Fist oxidovanadium complexes containing chiral derivatives of dihydrophenanthroline and diazafluorene",
abstract = "Reactions of VCl3 with chiral derivatives of dihydrophenanthroline (2R,4R,9R,11R)-3,3,10,10-tetramethyl-1,2,3,4,6,7,9,10,11,12-decahydro-2,4:9,11-dimethanodibenzo[b,j][1,10]phenanthroline (L1) and diazafluorene (1R,3R,8R,10R)-2,2,9,9-tetramethyl-2,3,4,7,8,9,10,12-octahydro-1H-1,3:8,10-dimethanocyclopenta[1,2-b:5,4-b′]diquinoline (L2) in acetonitrile in air yield mixtures of [VIII(L1/L2)(CH3CN)Cl3] and [VIVO(L1/L2)(CH3CN)Cl2] (I, II) which were characterized by elemental analysis, IR spectroscopy and magnetic susceptibility data. The behavior of these mixtures in different solvents was investigated by 51V NMR and EPR spectroscopies as well as optical rotation. Recrystallization of a [VIII(L1)(CH3CN)Cl3]/[VIVO(L1)(CH3CN)Cl2] mixture from CH2Cl2/Et2O affords a V(IV) complex, [VIVO(L1)(H2O)Cl2]·nCH2Cl2 (III). Recrystallization from MeOH/Et2O leads to complete oxidation to V(V) complex [VVO(L1)(OMe)Cl2] (IV), which was characterized by X-ray crystallography, IR, 51V and 1H NMR spectroscopies.",
keywords = "Chiral ligands, Crystal structure, EPR, Oxido complexes, Vanadium, OXOVANADIUM(IV) COMPOUNDS, VANADIUM, LIGANDS, GENERAL FORMULA",
author = "Fomenko, {Yakov S.} and Gushchin, {Artem L.} and Tkachev, {Aleksey V.} and Vasilyev, {Evgene S.} and Abramov, {Pavel A.} and Nadolinny, {Vladimir A.} and Syrokvashin, {Mikhail M.} and Sokolov, {Maxim N.}",
year = "2017",
month = oct,
day = "15",
doi = "10.1016/j.poly.2017.07.003",
language = "English",
volume = "135",
pages = "96--100",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Fist oxidovanadium complexes containing chiral derivatives of dihydrophenanthroline and diazafluorene

AU - Fomenko, Yakov S.

AU - Gushchin, Artem L.

AU - Tkachev, Aleksey V.

AU - Vasilyev, Evgene S.

AU - Abramov, Pavel A.

AU - Nadolinny, Vladimir A.

AU - Syrokvashin, Mikhail M.

AU - Sokolov, Maxim N.

PY - 2017/10/15

Y1 - 2017/10/15

N2 - Reactions of VCl3 with chiral derivatives of dihydrophenanthroline (2R,4R,9R,11R)-3,3,10,10-tetramethyl-1,2,3,4,6,7,9,10,11,12-decahydro-2,4:9,11-dimethanodibenzo[b,j][1,10]phenanthroline (L1) and diazafluorene (1R,3R,8R,10R)-2,2,9,9-tetramethyl-2,3,4,7,8,9,10,12-octahydro-1H-1,3:8,10-dimethanocyclopenta[1,2-b:5,4-b′]diquinoline (L2) in acetonitrile in air yield mixtures of [VIII(L1/L2)(CH3CN)Cl3] and [VIVO(L1/L2)(CH3CN)Cl2] (I, II) which were characterized by elemental analysis, IR spectroscopy and magnetic susceptibility data. The behavior of these mixtures in different solvents was investigated by 51V NMR and EPR spectroscopies as well as optical rotation. Recrystallization of a [VIII(L1)(CH3CN)Cl3]/[VIVO(L1)(CH3CN)Cl2] mixture from CH2Cl2/Et2O affords a V(IV) complex, [VIVO(L1)(H2O)Cl2]·nCH2Cl2 (III). Recrystallization from MeOH/Et2O leads to complete oxidation to V(V) complex [VVO(L1)(OMe)Cl2] (IV), which was characterized by X-ray crystallography, IR, 51V and 1H NMR spectroscopies.

AB - Reactions of VCl3 with chiral derivatives of dihydrophenanthroline (2R,4R,9R,11R)-3,3,10,10-tetramethyl-1,2,3,4,6,7,9,10,11,12-decahydro-2,4:9,11-dimethanodibenzo[b,j][1,10]phenanthroline (L1) and diazafluorene (1R,3R,8R,10R)-2,2,9,9-tetramethyl-2,3,4,7,8,9,10,12-octahydro-1H-1,3:8,10-dimethanocyclopenta[1,2-b:5,4-b′]diquinoline (L2) in acetonitrile in air yield mixtures of [VIII(L1/L2)(CH3CN)Cl3] and [VIVO(L1/L2)(CH3CN)Cl2] (I, II) which were characterized by elemental analysis, IR spectroscopy and magnetic susceptibility data. The behavior of these mixtures in different solvents was investigated by 51V NMR and EPR spectroscopies as well as optical rotation. Recrystallization of a [VIII(L1)(CH3CN)Cl3]/[VIVO(L1)(CH3CN)Cl2] mixture from CH2Cl2/Et2O affords a V(IV) complex, [VIVO(L1)(H2O)Cl2]·nCH2Cl2 (III). Recrystallization from MeOH/Et2O leads to complete oxidation to V(V) complex [VVO(L1)(OMe)Cl2] (IV), which was characterized by X-ray crystallography, IR, 51V and 1H NMR spectroscopies.

KW - Chiral ligands

KW - Crystal structure

KW - EPR

KW - Oxido complexes

KW - Vanadium

KW - OXOVANADIUM(IV) COMPOUNDS

KW - VANADIUM

KW - LIGANDS

KW - GENERAL FORMULA

UR - http://www.scopus.com/inward/record.url?scp=85024928860&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2017.07.003

DO - 10.1016/j.poly.2017.07.003

M3 - Article

AN - SCOPUS:85024928860

VL - 135

SP - 96

EP - 100

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 9960004