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First hexagonal close packed high-entropy alloy with outstanding stability under extreme conditions and electrocatalytic activity for methanol oxidation. / Yusenko, Kirill V.; Riva, Sephira; Carvalho, Patricia A. et al.

In: Scripta Materialia, Vol. 138, 01.09.2017, p. 22-27.

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Yusenko KV, Riva S, Carvalho PA, Yusenko MV, Arnaboldi S, Sukhikh AS et al. First hexagonal close packed high-entropy alloy with outstanding stability under extreme conditions and electrocatalytic activity for methanol oxidation. Scripta Materialia. 2017 Sept 1;138:22-27. doi: 10.1016/j.scriptamat.2017.05.022

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Yusenko, Kirill V. ; Riva, Sephira ; Carvalho, Patricia A. et al. / First hexagonal close packed high-entropy alloy with outstanding stability under extreme conditions and electrocatalytic activity for methanol oxidation. In: Scripta Materialia. 2017 ; Vol. 138. pp. 22-27.

BibTeX

@article{0f48ba3aa37645099fcf0c016a1431cd,
title = "First hexagonal close packed high-entropy alloy with outstanding stability under extreme conditions and electrocatalytic activity for methanol oxidation",
abstract = "High-entropy alloys containing 5 and 6 platinum group metals have been prepared by thermal decomposition of single-source precursors non requiring high temperature or mechanical alloying. The prepared Ir0.19Os0.22Re0.21Rh0.20Ru0.19 alloy is the first example of a single-phase hexagonal high-entropy alloy. Heat treatment up to 1500 K and compression up to 45 GPa do not result in phase changes, a record temperature and pressure stability for a single-phase high-entropy alloy. The alloys show pronounced electrocatalytic activity in methanol oxidation, which opens a route for the use of high-entropy alloys as materials for sustainable energy conversion.",
keywords = "Electrochemistry, High-entropy alloys, Platinum group alloys, X-ray diffraction, FORMIC-ACID, IRIDIUM, MULTIELEMENT NANOPARTICLES, BINARY, ELECTROOXIDATION, TERNARY, CATALYST, OSMIUM, ABSOLUTE-ZERO",
author = "Yusenko, {Kirill V.} and Sephira Riva and Carvalho, {Patricia A.} and Yusenko, {Maria V.} and Serena Arnaboldi and Sukhikh, {Aleksandr S.} and Michael Hanfland and Gromilov, {Sergey A.}",
note = "Publisher Copyright: {\textcopyright} 2017 Acta Materialia Inc.",
year = "2017",
month = sep,
day = "1",
doi = "10.1016/j.scriptamat.2017.05.022",
language = "English",
volume = "138",
pages = "22--27",
journal = "Scripta Materialia",
issn = "1359-6462",
publisher = "Elsevier Ltd",

}

RIS

TY - JOUR

T1 - First hexagonal close packed high-entropy alloy with outstanding stability under extreme conditions and electrocatalytic activity for methanol oxidation

AU - Yusenko, Kirill V.

AU - Riva, Sephira

AU - Carvalho, Patricia A.

AU - Yusenko, Maria V.

AU - Arnaboldi, Serena

AU - Sukhikh, Aleksandr S.

AU - Hanfland, Michael

AU - Gromilov, Sergey A.

N1 - Publisher Copyright: © 2017 Acta Materialia Inc.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - High-entropy alloys containing 5 and 6 platinum group metals have been prepared by thermal decomposition of single-source precursors non requiring high temperature or mechanical alloying. The prepared Ir0.19Os0.22Re0.21Rh0.20Ru0.19 alloy is the first example of a single-phase hexagonal high-entropy alloy. Heat treatment up to 1500 K and compression up to 45 GPa do not result in phase changes, a record temperature and pressure stability for a single-phase high-entropy alloy. The alloys show pronounced electrocatalytic activity in methanol oxidation, which opens a route for the use of high-entropy alloys as materials for sustainable energy conversion.

AB - High-entropy alloys containing 5 and 6 platinum group metals have been prepared by thermal decomposition of single-source precursors non requiring high temperature or mechanical alloying. The prepared Ir0.19Os0.22Re0.21Rh0.20Ru0.19 alloy is the first example of a single-phase hexagonal high-entropy alloy. Heat treatment up to 1500 K and compression up to 45 GPa do not result in phase changes, a record temperature and pressure stability for a single-phase high-entropy alloy. The alloys show pronounced electrocatalytic activity in methanol oxidation, which opens a route for the use of high-entropy alloys as materials for sustainable energy conversion.

KW - Electrochemistry

KW - High-entropy alloys

KW - Platinum group alloys

KW - X-ray diffraction

KW - FORMIC-ACID

KW - IRIDIUM

KW - MULTIELEMENT NANOPARTICLES

KW - BINARY

KW - ELECTROOXIDATION

KW - TERNARY

KW - CATALYST

KW - OSMIUM

KW - ABSOLUTE-ZERO

UR - http://www.scopus.com/inward/record.url?scp=85019555801&partnerID=8YFLogxK

U2 - 10.1016/j.scriptamat.2017.05.022

DO - 10.1016/j.scriptamat.2017.05.022

M3 - Article

AN - SCOPUS:85019555801

VL - 138

SP - 22

EP - 27

JO - Scripta Materialia

JF - Scripta Materialia

SN - 1359-6462

ER -

ID: 9076555