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First example of crystal structure of the nitrosoruthenium(II) trinitrato complex. / Vorobyev, V. A.; Emelyanov, V. A.; Baidina, I. A. et al.

In: Journal of Structural Chemistry, Vol. 58, No. 5, 01.09.2017, p. 975-982.

Research output: Contribution to journal › Article › peer-review

Harvard

Vorobyev, VA, Emelyanov, VA, Baidina, IA & Piryazev, DA 2017, 'First example of crystal structure of the nitrosoruthenium(II) trinitrato complex', Journal of Structural Chemistry, vol. 58, no. 5, pp. 975-982. https://doi.org/10.1134/S0022476617050171

APA

Vorobyev, V. A., Emelyanov, V. A., Baidina, I. A., & Piryazev, D. A. (2017). First example of crystal structure of the nitrosoruthenium(II) trinitrato complex. Journal of Structural Chemistry, 58(5), 975-982. https://doi.org/10.1134/S0022476617050171

Vancouver

Vorobyev VA, Emelyanov VA, Baidina IA, Piryazev DA. First example of crystal structure of the nitrosoruthenium(II) trinitrato complex. Journal of Structural Chemistry. 2017 Sept 1;58(5):975-982. doi: 10.1134/S0022476617050171

Author

Vorobyev, V. A. ; Emelyanov, V. A. ; Baidina, I. A. et al. / First example of crystal structure of the nitrosoruthenium(II) trinitrato complex. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 5. pp. 975-982.

BibTeX

@article{dceaeee9b8f747cdae6d2834345f61c3,
title = "First example of crystal structure of the nitrosoruthenium(II) trinitrato complex",
abstract = "Single crystal X-ray diffraction is used to study the nitrosoruthenium mer-trinitrato complex [RuNO(NH3)2(NO3)3]. The crystallographic data for H6N6O10Ru are as follows: a = 7.6477(1) {\AA}, b = 10.8404(2) {\AA}, c = 24.0168(6) {\AA}, α = β = γ = 90°, V = 1991.09(7) {\AA}3, Z = 8, dcalc = 2/338 g/cm3, space group P212121. The structure is formed of two structurally non-equivalent uncharged mer-[RuNO(NH3)2(NO3)3] complexes. The complex crystallizes as yellow needles or orange powder belonging to the orthorhombic system. The substance is poorly soluble in water, ethanol, and acetone, stable in dark storage. The comparisons with the EXAFS data for this complex and the theoretical DFT calculations with different functionals are performed.",
keywords = "ammine complexes, DFT calculations, nitrato complexes, nitrosyl complexes, ruthenium, single crystal X-ray diffraction analysis, spent nuclear fuel, NITRIC-ACID SOLUTIONS, BEHAVIOR, CORRELATION-ENERGY, RUTHENIUM, GENERALIZED GRADIENT APPROXIMATION, DENSITY, NITROSYLRUTHENIUM, EXTRACTION, METALS, CHEMISTRY",
author = "Vorobyev, {V. A.} and Emelyanov, {V. A.} and Baidina, {I. A.} and Piryazev, {D. A.}",
year = "2017",
month = sep,
day = "1",
doi = "10.1134/S0022476617050171",
language = "English",
volume = "58",
pages = "975--982",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "5",

}

RIS

TY - JOUR

T1 - First example of crystal structure of the nitrosoruthenium(II) trinitrato complex

AU - Vorobyev, V. A.

AU - Emelyanov, V. A.

AU - Baidina, I. A.

AU - Piryazev, D. A.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - Single crystal X-ray diffraction is used to study the nitrosoruthenium mer-trinitrato complex [RuNO(NH3)2(NO3)3]. The crystallographic data for H6N6O10Ru are as follows: a = 7.6477(1) Å, b = 10.8404(2) Å, c = 24.0168(6) Å, α = β = γ = 90°, V = 1991.09(7) Å3, Z = 8, dcalc = 2/338 g/cm3, space group P212121. The structure is formed of two structurally non-equivalent uncharged mer-[RuNO(NH3)2(NO3)3] complexes. The complex crystallizes as yellow needles or orange powder belonging to the orthorhombic system. The substance is poorly soluble in water, ethanol, and acetone, stable in dark storage. The comparisons with the EXAFS data for this complex and the theoretical DFT calculations with different functionals are performed.

AB - Single crystal X-ray diffraction is used to study the nitrosoruthenium mer-trinitrato complex [RuNO(NH3)2(NO3)3]. The crystallographic data for H6N6O10Ru are as follows: a = 7.6477(1) Å, b = 10.8404(2) Å, c = 24.0168(6) Å, α = β = γ = 90°, V = 1991.09(7) Å3, Z = 8, dcalc = 2/338 g/cm3, space group P212121. The structure is formed of two structurally non-equivalent uncharged mer-[RuNO(NH3)2(NO3)3] complexes. The complex crystallizes as yellow needles or orange powder belonging to the orthorhombic system. The substance is poorly soluble in water, ethanol, and acetone, stable in dark storage. The comparisons with the EXAFS data for this complex and the theoretical DFT calculations with different functionals are performed.

KW - ammine complexes

KW - DFT calculations

KW - nitrato complexes

KW - nitrosyl complexes

KW - ruthenium

KW - single crystal X-ray diffraction analysis

KW - spent nuclear fuel

KW - NITRIC-ACID SOLUTIONS

KW - BEHAVIOR

KW - CORRELATION-ENERGY

KW - RUTHENIUM

KW - GENERALIZED GRADIENT APPROXIMATION

KW - DENSITY

KW - NITROSYLRUTHENIUM

KW - EXTRACTION

KW - METALS

KW - CHEMISTRY

UR - http://www.scopus.com/inward/record.url?scp=85032269728&partnerID=8YFLogxK

U2 - 10.1134/S0022476617050171

DO - 10.1134/S0022476617050171

M3 - Article

AN - SCOPUS:85032269728

VL - 58

SP - 975

EP - 982

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 9873607