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Ferromagnetically Coupled S=1 Chains in Crystals of Verdazyl-Nitronyl Nitroxide Diradicals. / Tretyakov, Evgeny V.; Zhivetyeva, Svetlana I.; Kazantsev, Maxim S. et al.

In: Advanced Materials, Vol. 132, No. 46, 2020, p. 20885-20891.

Research output: Contribution to journal › Article › peer-review

Harvard

Tretyakov, EV, Zhivetyeva, SI, Kazantsev, MS, Shundrina, IK, Zaytseva, EV, Parkhomenko, DA, Bagryanskaya, EG, Gorbunov, DE, Bagryanskaya, IY, Petunin, PV, Postnikov, PS, Trusova, ME, Gritsan, NP, Bogomyakov, AS, Ovcharenko, VI & Postnikov, PS 2020, 'Ferromagnetically Coupled S=1 Chains in Crystals of Verdazyl-Nitronyl Nitroxide Diradicals', Advanced Materials, vol. 132, no. 46, pp. 20885-20891. https://doi.org/10.1002/ANGE.202010041

APA

Tretyakov, E. V., Zhivetyeva, S. I., Kazantsev, M. S., Shundrina, I. K., Zaytseva, E. V., Parkhomenko, D. A., Bagryanskaya, E. G., Gorbunov, D. E., Bagryanskaya, I. Y., Petunin, P. V., Postnikov, P. S., Trusova, M. E., Gritsan, N. P., Bogomyakov, A. S., Ovcharenko, V. I., & Postnikov, P. S. (2020). Ferromagnetically Coupled S=1 Chains in Crystals of Verdazyl-Nitronyl Nitroxide Diradicals. Advanced Materials, 132(46), 20885-20891. https://doi.org/10.1002/ANGE.202010041

Vancouver

Tretyakov EV, Zhivetyeva SI, Kazantsev MS, Shundrina IK, Zaytseva EV, Parkhomenko DA et al. Ferromagnetically Coupled S=1 Chains in Crystals of Verdazyl-Nitronyl Nitroxide Diradicals. Advanced Materials. 2020;132(46):20885-20891. doi: 10.1002/ANGE.202010041

Author

Tretyakov, Evgeny V. ; Zhivetyeva, Svetlana I. ; Kazantsev, Maxim S. et al. / Ferromagnetically Coupled S=1 Chains in Crystals of Verdazyl-Nitronyl Nitroxide Diradicals. In: Advanced Materials. 2020 ; Vol. 132, No. 46. pp. 20885-20891.

BibTeX

@article{ec7ca4b05d9445e09998c165657e214a,
title = "Ferromagnetically Coupled S=1 Chains in Crystals of Verdazyl-Nitronyl Nitroxide Diradicals",
abstract = "Thermally stable organic diradicals with a triplet ground state along with large singlet-triplet energy gap have significant potential for advanced technological applications. A series of phenylene-bridged diradicals with oxoverdazyl and nitronyl nitroxide units were synthesized via a palladiumcatalyzed cross-coupling reaction of iodoverdazyls with a nitronyl nitroxide-2-ide gold(I) complex with high yields. The diradicals exhibit high stability and do not decompose in an inert atmosphere up to 180°C. For the diradicals, both substantial AF (∆EST≈-64 cm-1) and FM (∆EST≥ 25 and 100 cm-1) intramolecular exchange interactions were observed. The sign of the exchange interaction is determined both by the bridging moiety (para- or meta-phenylene) and by the type of oxoverdazyl block (C-linked or N-linked). Upon crystallization, diradicals with the triplet ground state form unique onedimensional exchange-coupled chains with strong intra- and weak inter-diradical ferromagnetic coupling.",
keywords = "ferromagnetically coupled chain, high-spin molecules, nitroxides, triplet diradicals, verdazyl radicals",
author = "Tretyakov, {Evgeny V.} and Zhivetyeva, {Svetlana I.} and Kazantsev, {Maxim S.} and Shundrina, {Inna K.} and Zaytseva, {Elena V.} and Parkhomenko, {Dmitriy A.} and Bagryanskaya, {Elena G.} and Gorbunov, {Dmitry E.} and Bagryanskaya, {Irina Yu} and Petunin, {Pavel V.} and Postnikov, {Pavel S.} and Trusova, {Marina E.} and Gritsan, {Nina P.} and Bogomyakov, {Artem S.} and Ovcharenko, {Victor I.} and Postnikov, {Pavel S.}",
note = "Funding Information: This research was supported by the Ministry of Science and Higher Education of the Russian Federation (State Project „Science“ No. FSWW-2020-0011) and the Russian Science Foundation (grant No. 18-13-00173, synthesis and characterization). A.S.B. and V.I.O. are thankful to the Russian Science Foundation (grant No. 18-13-00380, magnetochemistry). D.E.G. and N.P.G. acknowledge support of the Ministry of Science and Higher Education of the Russian Federation (project No. 0304-2017-0008) and the Irkutsk Supercomputer Centre of the Siberian Branch of the Russian Academy of Sciences for computational resources. The authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. Publisher Copyright: {\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2020",
doi = "10.1002/ANGE.202010041",
language = "English",
volume = "132",
pages = "20885--20891",
journal = "Advanced Materials",
issn = "0935-9648",
publisher = "Wiley-Blackwell",
number = "46",

}

RIS

TY - JOUR

T1 - Ferromagnetically Coupled S=1 Chains in Crystals of Verdazyl-Nitronyl Nitroxide Diradicals

AU - Tretyakov, Evgeny V.

AU - Zhivetyeva, Svetlana I.

AU - Kazantsev, Maxim S.

AU - Shundrina, Inna K.

AU - Zaytseva, Elena V.

AU - Parkhomenko, Dmitriy A.

AU - Bagryanskaya, Elena G.

AU - Gorbunov, Dmitry E.

AU - Bagryanskaya, Irina Yu

AU - Petunin, Pavel V.

AU - Postnikov, Pavel S.

AU - Trusova, Marina E.

AU - Gritsan, Nina P.

AU - Bogomyakov, Artem S.

AU - Ovcharenko, Victor I.

AU - Postnikov, Pavel S.

N1 - Funding Information: This research was supported by the Ministry of Science and Higher Education of the Russian Federation (State Project „Science“ No. FSWW-2020-0011) and the Russian Science Foundation (grant No. 18-13-00173, synthesis and characterization). A.S.B. and V.I.O. are thankful to the Russian Science Foundation (grant No. 18-13-00380, magnetochemistry). D.E.G. and N.P.G. acknowledge support of the Ministry of Science and Higher Education of the Russian Federation (project No. 0304-2017-0008) and the Irkutsk Supercomputer Centre of the Siberian Branch of the Russian Academy of Sciences for computational resources. The authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. Publisher Copyright: © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2020

Y1 - 2020

N2 - Thermally stable organic diradicals with a triplet ground state along with large singlet-triplet energy gap have significant potential for advanced technological applications. A series of phenylene-bridged diradicals with oxoverdazyl and nitronyl nitroxide units were synthesized via a palladiumcatalyzed cross-coupling reaction of iodoverdazyls with a nitronyl nitroxide-2-ide gold(I) complex with high yields. The diradicals exhibit high stability and do not decompose in an inert atmosphere up to 180°C. For the diradicals, both substantial AF (∆EST≈-64 cm-1) and FM (∆EST≥ 25 and 100 cm-1) intramolecular exchange interactions were observed. The sign of the exchange interaction is determined both by the bridging moiety (para- or meta-phenylene) and by the type of oxoverdazyl block (C-linked or N-linked). Upon crystallization, diradicals with the triplet ground state form unique onedimensional exchange-coupled chains with strong intra- and weak inter-diradical ferromagnetic coupling.

AB - Thermally stable organic diradicals with a triplet ground state along with large singlet-triplet energy gap have significant potential for advanced technological applications. A series of phenylene-bridged diradicals with oxoverdazyl and nitronyl nitroxide units were synthesized via a palladiumcatalyzed cross-coupling reaction of iodoverdazyls with a nitronyl nitroxide-2-ide gold(I) complex with high yields. The diradicals exhibit high stability and do not decompose in an inert atmosphere up to 180°C. For the diradicals, both substantial AF (∆EST≈-64 cm-1) and FM (∆EST≥ 25 and 100 cm-1) intramolecular exchange interactions were observed. The sign of the exchange interaction is determined both by the bridging moiety (para- or meta-phenylene) and by the type of oxoverdazyl block (C-linked or N-linked). Upon crystallization, diradicals with the triplet ground state form unique onedimensional exchange-coupled chains with strong intra- and weak inter-diradical ferromagnetic coupling.

KW - ferromagnetically coupled chain

KW - high-spin molecules

KW - nitroxides

KW - triplet diradicals

KW - verdazyl radicals

UR - http://www.scopus.com/inward/record.url?scp=85136211221&partnerID=8YFLogxK

U2 - 10.1002/ANGE.202010041

DO - 10.1002/ANGE.202010041

M3 - Article

AN - SCOPUS:85136211221

VL - 132

SP - 20885

EP - 20891

JO - Advanced Materials

JF - Advanced Materials

SN - 0935-9648

IS - 46

ER -

ID: 37000366