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Features of the Thermolysis of Fe(II), Co(II), Ni(II), and Cu(II) Salts of Maleic and Phthalic Acids with the Formation of Metal Nanoparticles. / Yudanova, L. I.; Logvinenko, V. A.; Sheludyakova, L. A. et al.

In: Russian Journal of Physical Chemistry A, Vol. 93, No. 7, 01.07.2019, p. 1327-1332.

Research output: Contribution to journal › Article › peer-review

Harvard

Yudanova, LI, Logvinenko, VA, Sheludyakova, LA, Korolkov, IV, Rudina, NA, Ishchenko, AV & Alferova, NI 2019, 'Features of the Thermolysis of Fe(II), Co(II), Ni(II), and Cu(II) Salts of Maleic and Phthalic Acids with the Formation of Metal Nanoparticles', Russian Journal of Physical Chemistry A, vol. 93, no. 7, pp. 1327-1332. https://doi.org/10.1134/S003602441907032X

APA

Yudanova, L. I., Logvinenko, V. A., Sheludyakova, L. A., Korolkov, I. V., Rudina, N. A., Ishchenko, A. V., & Alferova, N. I. (2019). Features of the Thermolysis of Fe(II), Co(II), Ni(II), and Cu(II) Salts of Maleic and Phthalic Acids with the Formation of Metal Nanoparticles. Russian Journal of Physical Chemistry A, 93(7), 1327-1332. https://doi.org/10.1134/S003602441907032X

Vancouver

Yudanova LI, Logvinenko VA, Sheludyakova LA, Korolkov IV, Rudina NA, Ishchenko AV et al. Features of the Thermolysis of Fe(II), Co(II), Ni(II), and Cu(II) Salts of Maleic and Phthalic Acids with the Formation of Metal Nanoparticles. Russian Journal of Physical Chemistry A. 2019 Jul 1;93(7):1327-1332. doi: 10.1134/S003602441907032X

Author

Yudanova, L. I. ; Logvinenko, V. A. ; Sheludyakova, L. A. et al. / Features of the Thermolysis of Fe(II), Co(II), Ni(II), and Cu(II) Salts of Maleic and Phthalic Acids with the Formation of Metal Nanoparticles. In: Russian Journal of Physical Chemistry A. 2019 ; Vol. 93, No. 7. pp. 1327-1332.

BibTeX

@article{5b47448e40ac48b399a54e4e75242c9b,
title = "Features of the Thermolysis of Fe(II), Co(II), Ni(II), and Cu(II) Salts of Maleic and Phthalic Acids with the Formation of Metal Nanoparticles",
abstract = "Abstract: A relationship is established between the structural and thermoanalytical characteristics of the decomposition of hydrogen maleates and phthalates of Fe(II), Co(II), Ni(II), Cu(II). The temperatures of the onset of the first and second stages of decomposition grow in the series of both hydrogen maleates Cu ≤ Fe < Co < Ni and phthalates Fe ≤ Co < Ni < Cu, while the lengths of (Formula Presented.) and M–Oanion bonds shrink in these structures. At the third stage, the temperature of the onset of the decarboxylation of hydrogen maleates and phthalates falls in the order Fe > Co > Ni > Cu. The size of metal nanoparticles additionally contained in a polymer or graphene shell grows from 3.5 to 5 nm (Co) and from 4.5 to 7 nm (Ni) upon moving from composites obtained through the decomposition of hydrogen maleates to hydrogen phthalates. Polymeric conglomerates containing shell-less copper nanoparticles, the average size of which ranges from 7.5 to 50 nm, are incorporated into a polymer matrix of composites obtained via the thermolysis of Cu(II) hydrogen maleate and phthalate.",
keywords = "catalysts, maleates, metal/polymer composites, nanoparticles, ortho-phthalates, quantum size effect, thermal decomposition, transition metals, COPPER(II) MALEATE, metal, CRYSTAL, CO, THERMAL-DECOMPOSITION, polymer composites, NI",
author = "Yudanova, {L. I.} and Logvinenko, {V. A.} and Sheludyakova, {L. A.} and Korolkov, {I. V.} and Rudina, {N. A.} and Ishchenko, {A. V.} and Alferova, {N. I.}",
year = "2019",
month = jul,
day = "1",
doi = "10.1134/S003602441907032X",
language = "English",
volume = "93",
pages = "1327--1332",
journal = "Russian Journal of Physical Chemistry A",
issn = "0036-0244",
publisher = "PLEIADES PUBLISHING INC",
number = "7",

}

RIS

TY - JOUR

T1 - Features of the Thermolysis of Fe(II), Co(II), Ni(II), and Cu(II) Salts of Maleic and Phthalic Acids with the Formation of Metal Nanoparticles

AU - Yudanova, L. I.

AU - Logvinenko, V. A.

AU - Sheludyakova, L. A.

AU - Korolkov, I. V.

AU - Rudina, N. A.

AU - Ishchenko, A. V.

AU - Alferova, N. I.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Abstract: A relationship is established between the structural and thermoanalytical characteristics of the decomposition of hydrogen maleates and phthalates of Fe(II), Co(II), Ni(II), Cu(II). The temperatures of the onset of the first and second stages of decomposition grow in the series of both hydrogen maleates Cu ≤ Fe < Co < Ni and phthalates Fe ≤ Co < Ni < Cu, while the lengths of (Formula Presented.) and M–Oanion bonds shrink in these structures. At the third stage, the temperature of the onset of the decarboxylation of hydrogen maleates and phthalates falls in the order Fe > Co > Ni > Cu. The size of metal nanoparticles additionally contained in a polymer or graphene shell grows from 3.5 to 5 nm (Co) and from 4.5 to 7 nm (Ni) upon moving from composites obtained through the decomposition of hydrogen maleates to hydrogen phthalates. Polymeric conglomerates containing shell-less copper nanoparticles, the average size of which ranges from 7.5 to 50 nm, are incorporated into a polymer matrix of composites obtained via the thermolysis of Cu(II) hydrogen maleate and phthalate.

AB - Abstract: A relationship is established between the structural and thermoanalytical characteristics of the decomposition of hydrogen maleates and phthalates of Fe(II), Co(II), Ni(II), Cu(II). The temperatures of the onset of the first and second stages of decomposition grow in the series of both hydrogen maleates Cu ≤ Fe < Co < Ni and phthalates Fe ≤ Co < Ni < Cu, while the lengths of (Formula Presented.) and M–Oanion bonds shrink in these structures. At the third stage, the temperature of the onset of the decarboxylation of hydrogen maleates and phthalates falls in the order Fe > Co > Ni > Cu. The size of metal nanoparticles additionally contained in a polymer or graphene shell grows from 3.5 to 5 nm (Co) and from 4.5 to 7 nm (Ni) upon moving from composites obtained through the decomposition of hydrogen maleates to hydrogen phthalates. Polymeric conglomerates containing shell-less copper nanoparticles, the average size of which ranges from 7.5 to 50 nm, are incorporated into a polymer matrix of composites obtained via the thermolysis of Cu(II) hydrogen maleate and phthalate.

KW - catalysts

KW - maleates

KW - metal/polymer composites

KW - nanoparticles

KW - ortho-phthalates

KW - quantum size effect

KW - thermal decomposition

KW - transition metals

KW - COPPER(II) MALEATE

KW - metal

KW - CRYSTAL

KW - CO

KW - THERMAL-DECOMPOSITION

KW - polymer composites

KW - NI

UR - http://www.scopus.com/inward/record.url?scp=85068748092&partnerID=8YFLogxK

U2 - 10.1134/S003602441907032X

DO - 10.1134/S003602441907032X

M3 - Article

AN - SCOPUS:85068748092

VL - 93

SP - 1327

EP - 1332

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

SN - 0036-0244

IS - 7

ER -

ID: 20837854