Standard

Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil. / Cholach, A. R.; Asanov, I. P.; Bryliakova, A. A. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 4, 01.04.2020, p. 523-532.

Research output: Contribution to journal › Article › peer-review

Harvard

Cholach, AR, Asanov, IP, Bryliakova, AA, Kalinkin, AV & Smirnov, MY 2020, 'Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil', Journal of Structural Chemistry, vol. 61, no. 4, pp. 523-532. https://doi.org/10.1134/S0022476620040046

APA

Cholach, A. R., Asanov, I. P., Bryliakova, A. A., Kalinkin, A. V., & Smirnov, M. Y. (2020). Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil. Journal of Structural Chemistry, 61(4), 523-532. https://doi.org/10.1134/S0022476620040046

Vancouver

Cholach AR, Asanov IP, Bryliakova AA, Kalinkin AV, Smirnov MY. Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil. Journal of Structural Chemistry. 2020 Apr 1;61(4):523-532. doi: 10.1134/S0022476620040046

Author

Cholach, A. R. ; Asanov, I. P. ; Bryliakova, A. A. et al. / Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 4. pp. 523-532.

BibTeX

@article{c0f60c99194f45dcb43dcd0978459b6c,
title = "Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil",
abstract = "The possibility to obtain novel data by standard electron spectroscopy and quantum chemical techniques is exemplified by C2FBr0.15 intercalate and silver foil. The features of extended X-ray photoelectron spectra are interpreted by electronic transitions in the valence band of similar unit cells. The analysis of experimental and calculated spectra reveals two states of intercalated Br2: molecular and chain-like. The interaction of Ag with NO2 at 300–520 K is limited by the formation of an oxidized state in the near-surface layer with a thickness of ∼6 A, with the metallic state of silver dominating in the Ag3d И Ag MNN spectra. Geometric parameters, states of atoms, and the character of bonds between them are consistent with the previously obtained results.",
keywords = "conjugate electron transitions, energy losses, valence band, XPS, OXIDATION, BROMINE, AG, GRAPHITE, ADSORPTION, ELECTRONIC-STRUCTURE, MOLECULES",
author = "Cholach, {A. R.} and Asanov, {I. P.} and Bryliakova, {A. A.} and Kalinkin, {A. V.} and Smirnov, {M. Yu}",
year = "2020",
month = apr,
day = "1",
doi = "10.1134/S0022476620040046",
language = "English",
volume = "61",
pages = "523--532",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "4",

}

RIS

TY - JOUR

T1 - Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil

AU - Cholach, A. R.

AU - Asanov, I. P.

AU - Bryliakova, A. A.

AU - Kalinkin, A. V.

AU - Smirnov, M. Yu

PY - 2020/4/1

Y1 - 2020/4/1

N2 - The possibility to obtain novel data by standard electron spectroscopy and quantum chemical techniques is exemplified by C2FBr0.15 intercalate and silver foil. The features of extended X-ray photoelectron spectra are interpreted by electronic transitions in the valence band of similar unit cells. The analysis of experimental and calculated spectra reveals two states of intercalated Br2: molecular and chain-like. The interaction of Ag with NO2 at 300–520 K is limited by the formation of an oxidized state in the near-surface layer with a thickness of ∼6 A, with the metallic state of silver dominating in the Ag3d И Ag MNN spectra. Geometric parameters, states of atoms, and the character of bonds between them are consistent with the previously obtained results.

AB - The possibility to obtain novel data by standard electron spectroscopy and quantum chemical techniques is exemplified by C2FBr0.15 intercalate and silver foil. The features of extended X-ray photoelectron spectra are interpreted by electronic transitions in the valence band of similar unit cells. The analysis of experimental and calculated spectra reveals two states of intercalated Br2: molecular and chain-like. The interaction of Ag with NO2 at 300–520 K is limited by the formation of an oxidized state in the near-surface layer with a thickness of ∼6 A, with the metallic state of silver dominating in the Ag3d И Ag MNN spectra. Geometric parameters, states of atoms, and the character of bonds between them are consistent with the previously obtained results.

KW - conjugate electron transitions

KW - energy losses

KW - valence band

KW - XPS

KW - OXIDATION

KW - BROMINE

KW - AG

KW - GRAPHITE

KW - ADSORPTION

KW - ELECTRONIC-STRUCTURE

KW - MOLECULES

UR - http://www.scopus.com/inward/record.url?scp=85088653980&partnerID=8YFLogxK

U2 - 10.1134/S0022476620040046

DO - 10.1134/S0022476620040046

M3 - Article

AN - SCOPUS:85088653980

VL - 61

SP - 523

EP - 532

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 24868608