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Facile Substitution of Bridging SO2 2- Ligands in Re12 Bioctahedral Cluster Complexes. / Gayfulin, Yakov M.; Smolentsev, Anton I.; Kozlova, Svetlana G. et al.

In: Inorganic Chemistry, Vol. 56, No. 20, 16.10.2017, p. 12389-12400.

Research output: Contribution to journal › Article › peer-review

Harvard

Gayfulin, YM, Smolentsev, AI, Kozlova, SG, Novozhilov, IN, Plyusnin, PE, Kompankov, NB & Mironov, YV 2017, 'Facile Substitution of Bridging SO2 2- Ligands in Re12 Bioctahedral Cluster Complexes', Inorganic Chemistry, vol. 56, no. 20, pp. 12389-12400. https://doi.org/10.1021/acs.inorgchem.7b01889

APA

Gayfulin, Y. M., Smolentsev, A. I., Kozlova, S. G., Novozhilov, I. N., Plyusnin, P. E., Kompankov, N. B., & Mironov, Y. V. (2017). Facile Substitution of Bridging SO2 2- Ligands in Re12 Bioctahedral Cluster Complexes. Inorganic Chemistry, 56(20), 12389-12400. https://doi.org/10.1021/acs.inorgchem.7b01889

Vancouver

Gayfulin YM, Smolentsev AI, Kozlova SG, Novozhilov IN, Plyusnin PE, Kompankov NB et al. Facile Substitution of Bridging SO2 2- Ligands in Re12 Bioctahedral Cluster Complexes. Inorganic Chemistry. 2017 Oct 16;56(20):12389-12400. doi: 10.1021/acs.inorgchem.7b01889

Author

Gayfulin, Yakov M. ; Smolentsev, Anton I. ; Kozlova, Svetlana G. et al. / Facile Substitution of Bridging SO2 2- Ligands in Re12 Bioctahedral Cluster Complexes. In: Inorganic Chemistry. 2017 ; Vol. 56, No. 20. pp. 12389-12400.

BibTeX

@article{2376082a109940a599e7f14d0fb95a2f,
title = "Facile Substitution of Bridging SO2 2- Ligands in Re12 Bioctahedral Cluster Complexes",
abstract = "Selective substitution of μ-SO2 2- groups by either O2- or Se2- ions occurs upon heating the bioctahedral rhenium cluster complex K6[Re12CS14(μ-SO2)3(CN)6] in air atmosphere or in the presence of a Se source, respectively, manifesting the remarkable lability of SO2 2- ligands bound to a transition-metal cluster. A series of compounds based on the new mixed-ligand anions, [Re12CS14(μ-O)3(CN)6]6-, [Re12CS14(μ-Se)3(CN)6]6-, and [Re12CS14(μ-O)3(OH)6]6-, were isolated and their solid-state structures were elucidated by single-crystal X-ray diffraction analysis. Along with the previously reported μ-sulfide clusters, the new species constitute a series of rhenium anionic complexes with the common formula [Re12CS14(μ-Q)3L6]6- (Q = O, S, Se, L = CN- Q = O, S, L = OH-), within which the total charge and number of cluster valence electrons (CVEs) are constant. The article presents insights into the mechanistic and synthetic aspects of the substitution process, and it comprehensively discusses the influence of inner ligand environment on the structure, spectroscopic characteristics, and electrochemical behavior of the novel compounds.",
keywords = "ORDER REGULAR APPROXIMATION, RHENIUM CLUSTER, STRUCTURAL-CHARACTERIZATION, SOLUTION CHEMISTRY, SCREENING MODEL, SULFUR-DIOXIDE, CORE, SOLVATION, EXCHANGE, ENVIRONMENT",
author = "Gayfulin, {Yakov M.} and Smolentsev, {Anton I.} and Kozlova, {Svetlana G.} and Novozhilov, {Igor N.} and Plyusnin, {Pavel E.} and Kompankov, {Nikolay B.} and Mironov, {Yuri V.}",
year = "2017",
month = oct,
day = "16",
doi = "10.1021/acs.inorgchem.7b01889",
language = "English",
volume = "56",
pages = "12389--12400",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "20",

}

RIS

TY - JOUR

T1 - Facile Substitution of Bridging SO2 2- Ligands in Re12 Bioctahedral Cluster Complexes

AU - Gayfulin, Yakov M.

AU - Smolentsev, Anton I.

AU - Kozlova, Svetlana G.

AU - Novozhilov, Igor N.

AU - Plyusnin, Pavel E.

AU - Kompankov, Nikolay B.

AU - Mironov, Yuri V.

PY - 2017/10/16

Y1 - 2017/10/16

N2 - Selective substitution of μ-SO2 2- groups by either O2- or Se2- ions occurs upon heating the bioctahedral rhenium cluster complex K6[Re12CS14(μ-SO2)3(CN)6] in air atmosphere or in the presence of a Se source, respectively, manifesting the remarkable lability of SO2 2- ligands bound to a transition-metal cluster. A series of compounds based on the new mixed-ligand anions, [Re12CS14(μ-O)3(CN)6]6-, [Re12CS14(μ-Se)3(CN)6]6-, and [Re12CS14(μ-O)3(OH)6]6-, were isolated and their solid-state structures were elucidated by single-crystal X-ray diffraction analysis. Along with the previously reported μ-sulfide clusters, the new species constitute a series of rhenium anionic complexes with the common formula [Re12CS14(μ-Q)3L6]6- (Q = O, S, Se, L = CN- Q = O, S, L = OH-), within which the total charge and number of cluster valence electrons (CVEs) are constant. The article presents insights into the mechanistic and synthetic aspects of the substitution process, and it comprehensively discusses the influence of inner ligand environment on the structure, spectroscopic characteristics, and electrochemical behavior of the novel compounds.

AB - Selective substitution of μ-SO2 2- groups by either O2- or Se2- ions occurs upon heating the bioctahedral rhenium cluster complex K6[Re12CS14(μ-SO2)3(CN)6] in air atmosphere or in the presence of a Se source, respectively, manifesting the remarkable lability of SO2 2- ligands bound to a transition-metal cluster. A series of compounds based on the new mixed-ligand anions, [Re12CS14(μ-O)3(CN)6]6-, [Re12CS14(μ-Se)3(CN)6]6-, and [Re12CS14(μ-O)3(OH)6]6-, were isolated and their solid-state structures were elucidated by single-crystal X-ray diffraction analysis. Along with the previously reported μ-sulfide clusters, the new species constitute a series of rhenium anionic complexes with the common formula [Re12CS14(μ-Q)3L6]6- (Q = O, S, Se, L = CN- Q = O, S, L = OH-), within which the total charge and number of cluster valence electrons (CVEs) are constant. The article presents insights into the mechanistic and synthetic aspects of the substitution process, and it comprehensively discusses the influence of inner ligand environment on the structure, spectroscopic characteristics, and electrochemical behavior of the novel compounds.

KW - ORDER REGULAR APPROXIMATION

KW - RHENIUM CLUSTER

KW - STRUCTURAL-CHARACTERIZATION

KW - SOLUTION CHEMISTRY

KW - SCREENING MODEL

KW - SULFUR-DIOXIDE

KW - CORE

KW - SOLVATION

KW - EXCHANGE

KW - ENVIRONMENT

UR - http://www.scopus.com/inward/record.url?scp=85031729965&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.7b01889

DO - 10.1021/acs.inorgchem.7b01889

M3 - Article

AN - SCOPUS:85031729965

VL - 56

SP - 12389

EP - 12400

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 20

ER -

ID: 9875938