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Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures. / Shundrin, Leonid A.; Irtegova, Irina G.; Vasilieva, Nadezhda V. et al.

In: Mendeleev Communications, Vol. 28, No. 3, 01.05.2018, p. 257-260.

Research output: Contribution to journal › Article › peer-review

Harvard

Shundrin, LA, Irtegova, IG, Vasilieva, NV & Loskutov, VA 2018, 'Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures', Mendeleev Communications, vol. 28, no. 3, pp. 257-260. https://doi.org/10.1016/j.mencom.2018.05.009

APA

Shundrin, L. A., Irtegova, I. G., Vasilieva, N. V., & Loskutov, V. A. (2018). Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures. Mendeleev Communications, 28(3), 257-260. https://doi.org/10.1016/j.mencom.2018.05.009

Vancouver

Shundrin LA, Irtegova IG, Vasilieva NV, Loskutov VA. Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures. Mendeleev Communications. 2018 May 1;28(3):257-260. doi: 10.1016/j.mencom.2018.05.009

Author

Shundrin, Leonid A. ; Irtegova, Irina G. ; Vasilieva, Nadezhda V. et al. / Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures. In: Mendeleev Communications. 2018 ; Vol. 28, No. 3. pp. 257-260.

BibTeX

@article{aa55d8bc508941189a6a8801d2124a03,
title = "Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures",
abstract = "The electrochemical reduction of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its 2-(N-piperidyl) derivative in DMF and DMF–H2O mixtures represents an EE-process, whereas that for 1-(N-piperidyl) and 1,4-di(N-piperidyl) derivatives occurs as an EEC-process. Based on the linear dependences of the first reversible one-electron reductive half-wave potentials of these compounds on the water content of DMF–H2O mixtures, the corresponding changes in the free energies of solvation under electron transfer have been calculated. Radical anions of the above compounds were obtained in DMF and characterized by EPR spectroscopy and DFT calculations at the (U)B3LYP/6-31+G* level of theory.",
author = "Shundrin, {Leonid A.} and Irtegova, {Irina G.} and Vasilieva, {Nadezhda V.} and Loskutov, {Vladimir A.}",
year = "2018",
month = may,
day = "1",
doi = "10.1016/j.mencom.2018.05.009",
language = "English",
volume = "28",
pages = "257--260",
journal = "Mendeleev Communications",
issn = "0959-9436",
publisher = "Elsevier",
number = "3",

}

RIS

TY - JOUR

T1 - Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures

AU - Shundrin, Leonid A.

AU - Irtegova, Irina G.

AU - Vasilieva, Nadezhda V.

AU - Loskutov, Vladimir A.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - The electrochemical reduction of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its 2-(N-piperidyl) derivative in DMF and DMF–H2O mixtures represents an EE-process, whereas that for 1-(N-piperidyl) and 1,4-di(N-piperidyl) derivatives occurs as an EEC-process. Based on the linear dependences of the first reversible one-electron reductive half-wave potentials of these compounds on the water content of DMF–H2O mixtures, the corresponding changes in the free energies of solvation under electron transfer have been calculated. Radical anions of the above compounds were obtained in DMF and characterized by EPR spectroscopy and DFT calculations at the (U)B3LYP/6-31+G* level of theory.

AB - The electrochemical reduction of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its 2-(N-piperidyl) derivative in DMF and DMF–H2O mixtures represents an EE-process, whereas that for 1-(N-piperidyl) and 1,4-di(N-piperidyl) derivatives occurs as an EEC-process. Based on the linear dependences of the first reversible one-electron reductive half-wave potentials of these compounds on the water content of DMF–H2O mixtures, the corresponding changes in the free energies of solvation under electron transfer have been calculated. Radical anions of the above compounds were obtained in DMF and characterized by EPR spectroscopy and DFT calculations at the (U)B3LYP/6-31+G* level of theory.

UR - http://www.scopus.com/inward/record.url?scp=85047614984&partnerID=8YFLogxK

U2 - 10.1016/j.mencom.2018.05.009

DO - 10.1016/j.mencom.2018.05.009

M3 - Article

AN - SCOPUS:85047614984

VL - 28

SP - 257

EP - 260

JO - Mendeleev Communications

JF - Mendeleev Communications

SN - 0959-9436

IS - 3

ER -

ID: 13632995