Research output: Contribution to journal › Article › peer-review
Electrochemical Properties of the Ultrasonically Activated Thermally Expanded Graphite–Polyaniline Hybrid Material. / Fedorovskaya, Ekaterina O.; Bulusheva, Lyubov G.; Smirnov, Dmitry A. et al.
In: Physica Status Solidi (B) Basic Research, Vol. 255, No. 1, 1700516, 01.01.2018.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Electrochemical Properties of the Ultrasonically Activated Thermally Expanded Graphite–Polyaniline Hybrid Material
AU - Fedorovskaya, Ekaterina O.
AU - Bulusheva, Lyubov G.
AU - Smirnov, Dmitry A.
AU - Okotrub, Alexander V.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - Thermally expanded graphite (TEG) is used as a template for precipitation of polyaniline from an aqueous solution of aniline hydrochloride and sodium persulfate used as an oxidant. In the first case, the TEG sample is used without treatment, in the second case the TEG sample is activated by ultrasonication before the polyaniline precipitation. Raman spectroscopy shows the formation of polymer layers on the surface of graphene layers. Near-edge X-ray absorption fine structure and X-ray photoelectron spectroscopy reveal the influence of the TEG ultrasonication on the chemical state of polyaniline in the hybrid. This material shows a large specific capacitance in a 1 M H2SO4 electrolyte due to the Faradaic processes in the polyaniline and high stability during the cycling.
AB - Thermally expanded graphite (TEG) is used as a template for precipitation of polyaniline from an aqueous solution of aniline hydrochloride and sodium persulfate used as an oxidant. In the first case, the TEG sample is used without treatment, in the second case the TEG sample is activated by ultrasonication before the polyaniline precipitation. Raman spectroscopy shows the formation of polymer layers on the surface of graphene layers. Near-edge X-ray absorption fine structure and X-ray photoelectron spectroscopy reveal the influence of the TEG ultrasonication on the chemical state of polyaniline in the hybrid. This material shows a large specific capacitance in a 1 M H2SO4 electrolyte due to the Faradaic processes in the polyaniline and high stability during the cycling.
KW - cyclic voltammetry
KW - NEXAFS
KW - polyaniline
KW - thermally expanded graphite
KW - X-ray photoelectron spectroscopy
KW - STORAGE
KW - GRAPHENE OXIDE
KW - ENERGY
KW - CARBON NANOTUBE
KW - ELECTRODES
KW - SUPERCAPACITOR PERFORMANCE
KW - REDUCTION
KW - FABRICATION
UR - http://www.scopus.com/inward/record.url?scp=85037666016&partnerID=8YFLogxK
U2 - 10.1002/pssb.201700516
DO - 10.1002/pssb.201700516
M3 - Article
AN - SCOPUS:85037666016
VL - 255
JO - Physica Status Solidi (B): Basic Research
JF - Physica Status Solidi (B): Basic Research
SN - 0370-1972
IS - 1
M1 - 1700516
ER -
ID: 9444617