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Effect of the composition of zeolite paranatrolite on the configuration of its water-cation subsystem. / Seryotkin, Yu V.; Bakakin, V. V.; Pekov, I. V.

In: Journal of Structural Chemistry, Vol. 57, No. 2, 01.03.2016, p. 406-412.

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Seryotkin YV, Bakakin VV, Pekov IV. Effect of the composition of zeolite paranatrolite on the configuration of its water-cation subsystem. Journal of Structural Chemistry. 2016 Mar 1;57(2):406-412. doi: 10.1134/S0022476616020232

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Seryotkin, Yu V. ; Bakakin, V. V. ; Pekov, I. V. / Effect of the composition of zeolite paranatrolite on the configuration of its water-cation subsystem. In: Journal of Structural Chemistry. 2016 ; Vol. 57, No. 2. pp. 406-412.

BibTeX

@article{ced61fa3e64a4728b23cc699fefc396e,
title = "Effect of the composition of zeolite paranatrolite on the configuration of its water-cation subsystem",
abstract = "The Rietveld method is used to determine the structure of two samples of high-hydrated zeolite paranatrolite: {Na1.15Ca0.38Sr0.04(H2O)3.1}[Al2.19Si2.81O10] (Vishnevye Mountains, Urals) and {Na2.01K0.04H0.04(H2O)3.8}[Al2.10Si2.90O10] (Kirov Mine, Khibiny Massif). Paranatrolite from the Vishnevye Mountains is characterized by the presence of split water positions and a relatively low total H2O content. Local water-cation assemblages (WCAs) of three configurations are identified in the statistical “mixture”. The extraframework subsystem in the structure of Khibiny paranatrolite is made of WCAs of one configuration. The H2O content of this mineral is close to the maximum possible amount and is a recordbreaker for natrolite-type minerals.",
keywords = "crystal structure, paranatrolite, water–cation assemblages, zeolites",
author = "Seryotkin, {Yu V.} and Bakakin, {V. V.} and Pekov, {I. V.}",
year = "2016",
month = mar,
day = "1",
doi = "10.1134/S0022476616020232",
language = "English",
volume = "57",
pages = "406--412",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - Effect of the composition of zeolite paranatrolite on the configuration of its water-cation subsystem

AU - Seryotkin, Yu V.

AU - Bakakin, V. V.

AU - Pekov, I. V.

PY - 2016/3/1

Y1 - 2016/3/1

N2 - The Rietveld method is used to determine the structure of two samples of high-hydrated zeolite paranatrolite: {Na1.15Ca0.38Sr0.04(H2O)3.1}[Al2.19Si2.81O10] (Vishnevye Mountains, Urals) and {Na2.01K0.04H0.04(H2O)3.8}[Al2.10Si2.90O10] (Kirov Mine, Khibiny Massif). Paranatrolite from the Vishnevye Mountains is characterized by the presence of split water positions and a relatively low total H2O content. Local water-cation assemblages (WCAs) of three configurations are identified in the statistical “mixture”. The extraframework subsystem in the structure of Khibiny paranatrolite is made of WCAs of one configuration. The H2O content of this mineral is close to the maximum possible amount and is a recordbreaker for natrolite-type minerals.

AB - The Rietveld method is used to determine the structure of two samples of high-hydrated zeolite paranatrolite: {Na1.15Ca0.38Sr0.04(H2O)3.1}[Al2.19Si2.81O10] (Vishnevye Mountains, Urals) and {Na2.01K0.04H0.04(H2O)3.8}[Al2.10Si2.90O10] (Kirov Mine, Khibiny Massif). Paranatrolite from the Vishnevye Mountains is characterized by the presence of split water positions and a relatively low total H2O content. Local water-cation assemblages (WCAs) of three configurations are identified in the statistical “mixture”. The extraframework subsystem in the structure of Khibiny paranatrolite is made of WCAs of one configuration. The H2O content of this mineral is close to the maximum possible amount and is a recordbreaker for natrolite-type minerals.

KW - crystal structure

KW - paranatrolite

KW - water–cation assemblages

KW - zeolites

UR - http://www.scopus.com/inward/record.url?scp=84971613928&partnerID=8YFLogxK

U2 - 10.1134/S0022476616020232

DO - 10.1134/S0022476616020232

M3 - Article

AN - SCOPUS:84971613928

VL - 57

SP - 406

EP - 412

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 25760858