Research output: Contribution to journal › Article › peer-review
Effect of Hot Pressing on the Electrochemical Performance of Multilayer Holey Graphene Materials in Li-ion Batteries. / Stolyarova, Svetlana G.; Okotrub, Alexander V.; Shubin, Yury V. et al.
In: Physica Status Solidi (B) Basic Research, Vol. 255, No. 12, 1800202, 01.12.2018.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Effect of Hot Pressing on the Electrochemical Performance of Multilayer Holey Graphene Materials in Li-ion Batteries
AU - Stolyarova, Svetlana G.
AU - Okotrub, Alexander V.
AU - Shubin, Yury V.
AU - Asanov, Igor P.
AU - Galitsky, Alexander A.
AU - Bulusheva, Lyubov G.
PY - 2018/12/1
Y1 - 2018/12/1
N2 - Annealing and pressing are useful for improvement of the structural ordering of graphitic materials. Depending on the processing conditions, this may cause a gain or deteriorate the performances of graphitic anodes in batteries. In the present work, we study the effect of hot pressing on the interaction of multilayer holey graphene (HG) material with lithium ions. The initial HG sample with the holes of about 0.6–2 nm was pressured at 100 bar and room temperature, 600 °C, and 800 °C or at 500 bar and 800 °C. The analysis of the samples using X-ray diffraction detected an increase in the thickness of graphene stacks after pressing. Electrochemical tests revealed the best performance for the HG sample produced at 100 bar and 600 °C. A rise of the temperature and pressure reduces the contribution from cross-plane diffusion of lithium ions in the HG capacity.
AB - Annealing and pressing are useful for improvement of the structural ordering of graphitic materials. Depending on the processing conditions, this may cause a gain or deteriorate the performances of graphitic anodes in batteries. In the present work, we study the effect of hot pressing on the interaction of multilayer holey graphene (HG) material with lithium ions. The initial HG sample with the holes of about 0.6–2 nm was pressured at 100 bar and room temperature, 600 °C, and 800 °C or at 500 bar and 800 °C. The analysis of the samples using X-ray diffraction detected an increase in the thickness of graphene stacks after pressing. Electrochemical tests revealed the best performance for the HG sample produced at 100 bar and 600 °C. A rise of the temperature and pressure reduces the contribution from cross-plane diffusion of lithium ions in the HG capacity.
KW - cross-plane lithium diffusion
KW - hot pressing
KW - Li-ion battery
KW - multilayer holey graphene
KW - OXIDE-FILMS
KW - GRAPHITIZATION
KW - RATE CAPABILITY
KW - GRAPHITE
KW - POROUS GRAPHENE
KW - LITHIUM-ION
UR - http://www.scopus.com/inward/record.url?scp=85054192514&partnerID=8YFLogxK
U2 - 10.1002/pssb.201800202
DO - 10.1002/pssb.201800202
M3 - Article
AN - SCOPUS:85054192514
VL - 255
JO - Physica Status Solidi (B): Basic Research
JF - Physica Status Solidi (B): Basic Research
SN - 0370-1972
IS - 12
M1 - 1800202
ER -
ID: 16953485