Research output: Contribution to journal › Article › peer-review
Effect of dispersion of gold nanoparticles on the properties and alignment of liquid crystalline copper phthalocyanine films. / Basova, Tamara V.; Parkhomenko, Roman G.; Polyakov, Maxim et al.
In: Dyes and Pigments, Vol. 125, 01.02.2016, p. 266-273.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Effect of dispersion of gold nanoparticles on the properties and alignment of liquid crystalline copper phthalocyanine films
AU - Basova, Tamara V.
AU - Parkhomenko, Roman G.
AU - Polyakov, Maxim
AU - Gürek, Ayşe Gül
AU - Atilla, Devrim
AU - Yuksel, Fatma
AU - Ryabchikova, Elena I.
AU - Kadem, Burak Y.
AU - Hassan, Aseel K.
PY - 2016/2/1
Y1 - 2016/2/1
N2 - The inclusion of hexadecylamine capped gold nanoparticles (AuNPs) into the ordered matrix of hexagonal columnar mesophase of copper phthalocyanine (CuPc) has been investigated. The effects of AuNPs on the liquid crystalline behaviour, optical and electrical properties of CuPc films is investigated by different physical methods. The molecules orientation in the films of CuPc and its composites with AuNPs, deposited on the surface of one substrate and between two electrodes, is studied by polarized Raman spectroscopy and polarized microscopy. It has been shown that thin films of the composites confined between ITO and Al electrodes are characterized by homeotropic alignment while no homeotropic alignment was observed in films deposited on ITO substrate with air constituting the upper interface. The I(V) dependences for the films confined between ITO and Al electrodes were measured. Appreciable enhancement of the DC conductivity is observed in the case of composites containing gold nanoparticles.
AB - The inclusion of hexadecylamine capped gold nanoparticles (AuNPs) into the ordered matrix of hexagonal columnar mesophase of copper phthalocyanine (CuPc) has been investigated. The effects of AuNPs on the liquid crystalline behaviour, optical and electrical properties of CuPc films is investigated by different physical methods. The molecules orientation in the films of CuPc and its composites with AuNPs, deposited on the surface of one substrate and between two electrodes, is studied by polarized Raman spectroscopy and polarized microscopy. It has been shown that thin films of the composites confined between ITO and Al electrodes are characterized by homeotropic alignment while no homeotropic alignment was observed in films deposited on ITO substrate with air constituting the upper interface. The I(V) dependences for the films confined between ITO and Al electrodes were measured. Appreciable enhancement of the DC conductivity is observed in the case of composites containing gold nanoparticles.
KW - Composite materials
KW - Films alignment
KW - Gold nanoparticles
KW - Liquid crystals
KW - Metal phthalocyanines
KW - Plasmon resonance
UR - http://www.scopus.com/inward/record.url?scp=84946887652&partnerID=8YFLogxK
U2 - 10.1016/j.dyepig.2015.10.005
DO - 10.1016/j.dyepig.2015.10.005
M3 - Article
AN - SCOPUS:84946887652
VL - 125
SP - 266
EP - 273
JO - Dyes and Pigments
JF - Dyes and Pigments
SN - 0143-7208
ER -
ID: 25436786