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Dye-modified carbon nanotubes for the optical detection of amines vapours. / Banimuslem, Hikmat; Hassan, Aseel; Basova, Tamara et al.
In: Sensors and Actuators, B: Chemical, Vol. 207, No. Part A, 02.2015, p. 224-234.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Dye-modified carbon nanotubes for the optical detection of amines vapours
AU - Banimuslem, Hikmat
AU - Hassan, Aseel
AU - Basova, Tamara
AU - Esenpinar, Aliye Asli
AU - Tuncel, Sinem
AU - Durmuş, Mahmut
AU - Gürek, Ayşe Gül
AU - Ahsen, Vefa
PY - 2015/2
Y1 - 2015/2
N2 - Thin films of peripheral and non-peripheral tetra-substituted copper phthalocyanines [CuPcR4, R = O(CH2CH2O)3CH3 or S(CH2CH2O)3CH3] and their hybrids with single walled carbon nanotubes (SWCNT) have been investigated as optical active layers for amines vapours detection. Adsorption of amines onto the films' surfaces has been realized by monitoring changes in the phase shift (Δ(λ)) of total internal reflection ellipsometry spectra. Methylamine has shown higher sensitivity and lower response time among the studied three amines. The steric hindrance provided by the shapes of the secondary and tertiary amine molecules is thought to decrease the interaction with films' surfaces as compared to methylamine. For all active layers used in this study, the sensitivity of SWCNT/CuPcR4 hybrid films was higher than the sensitivity of pristine CuPcR4 films with clear recovery in the Δ(λ) spectra after flushing the cell with air. The lower response time at 40 ppm is found to be 66 s and the highest sensitivity is 0.000325/ppm towards methylamine vapour.
AB - Thin films of peripheral and non-peripheral tetra-substituted copper phthalocyanines [CuPcR4, R = O(CH2CH2O)3CH3 or S(CH2CH2O)3CH3] and their hybrids with single walled carbon nanotubes (SWCNT) have been investigated as optical active layers for amines vapours detection. Adsorption of amines onto the films' surfaces has been realized by monitoring changes in the phase shift (Δ(λ)) of total internal reflection ellipsometry spectra. Methylamine has shown higher sensitivity and lower response time among the studied three amines. The steric hindrance provided by the shapes of the secondary and tertiary amine molecules is thought to decrease the interaction with films' surfaces as compared to methylamine. For all active layers used in this study, the sensitivity of SWCNT/CuPcR4 hybrid films was higher than the sensitivity of pristine CuPcR4 films with clear recovery in the Δ(λ) spectra after flushing the cell with air. The lower response time at 40 ppm is found to be 66 s and the highest sensitivity is 0.000325/ppm towards methylamine vapour.
KW - Amines detection
KW - Metal phtalocyanine
KW - Single-Walled Carbon Nanotubes
KW - TIRE
UR - http://www.scopus.com/inward/record.url?scp=84910070483&partnerID=8YFLogxK
U2 - 10.1016/j.snb.2014.10.046
DO - 10.1016/j.snb.2014.10.046
M3 - Article
AN - SCOPUS:84910070483
VL - 207
SP - 224
EP - 234
JO - Sensors and Actuators, B: Chemical
JF - Sensors and Actuators, B: Chemical
SN - 0925-4005
IS - Part A
ER -
ID: 25435557