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Dual-initiator alkoxyamines with an : N-tert -butyl- N -(1-diethylphosphono-2,2-dimethylpropyl) nitroxide moiety for preparation of block co-polymers. / Audran, Gérard; Bagryanskaya, Elena; Edeleva, Mariya et al.

In: RSC Advances, Vol. 7, No. 9, 01.01.2017, p. 4993-5001.

Research output: Contribution to journal › Article › peer-review

Harvard

Audran, G, Bagryanskaya, E, Edeleva, M, Marque, SRA & Yamasaki, T 2017, 'Dual-initiator alkoxyamines with an: N-tert -butyl- N -(1-diethylphosphono-2,2-dimethylpropyl) nitroxide moiety for preparation of block co-polymers', RSC Advances, vol. 7, no. 9, pp. 4993-5001. https://doi.org/10.1039/c6ra27231b

APA

Audran, G., Bagryanskaya, E., Edeleva, M., Marque, S. R. A., & Yamasaki, T. (2017). Dual-initiator alkoxyamines with an: N-tert -butyl- N -(1-diethylphosphono-2,2-dimethylpropyl) nitroxide moiety for preparation of block co-polymers. RSC Advances, 7(9), 4993-5001. https://doi.org/10.1039/c6ra27231b

Vancouver

Audran G, Bagryanskaya E, Edeleva M, Marque SRA, Yamasaki T. Dual-initiator alkoxyamines with an: N-tert -butyl- N -(1-diethylphosphono-2,2-dimethylpropyl) nitroxide moiety for preparation of block co-polymers. RSC Advances. 2017 Jan 1;7(9):4993-5001. doi: 10.1039/c6ra27231b

Author

Audran, Gérard ; Bagryanskaya, Elena ; Edeleva, Mariya et al. / Dual-initiator alkoxyamines with an : N-tert -butyl- N -(1-diethylphosphono-2,2-dimethylpropyl) nitroxide moiety for preparation of block co-polymers. In: RSC Advances. 2017 ; Vol. 7, No. 9. pp. 4993-5001.

BibTeX

@article{d67eaffb3670493eaffc20199a954861,
title = "Dual-initiator alkoxyamines with an: N-tert -butyl- N -(1-diethylphosphono-2,2-dimethylpropyl) nitroxide moiety for preparation of block co-polymers",
abstract = "Dual initiators for controlled radical/ionic polymerization reactions attract much attention in terms of preparation of new materials. We studied the potential of dual-initiator alkoxyamines 3 [based both on para-substituted aromatic ring for external triggering or initiation of orthogonal polymerization and on N-tert-butyl-N-(1-diethylphosphono-2,2-dimethylpropyl) nitroxide (SG1)] for nitroxide-mediated polymerization (NMP) with various monomers such as styrene, styrene sulphonate, 2-vinyl pyridine or methylmethacrylate. Alkoxyamines 3 were found to be as efficient in the NMP process as N-(2-methylpropyl)-N-(1-diethylphosphono-2,2-dimethylpropyl)-O-(2-carboxylprop-2-yl)hydroxylamine (1). Furthermore, in sharp contrast to 1, alkoxyamines 3 were easier to functionalize.",
author = "G{\'e}rard Audran and Elena Bagryanskaya and Mariya Edeleva and Marque, {Sylvain R.A.} and Toshihide Yamasaki",
note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",
year = "2017",
month = jan,
day = "1",
doi = "10.1039/c6ra27231b",
language = "English",
volume = "7",
pages = "4993--5001",
journal = "RSC Advances",
issn = "2046-2069",
publisher = "ROYAL SOC CHEMISTRY",
number = "9",

}

RIS

TY - JOUR

T1 - Dual-initiator alkoxyamines with an

T2 - N-tert -butyl- N -(1-diethylphosphono-2,2-dimethylpropyl) nitroxide moiety for preparation of block co-polymers

AU - Audran, Gérard

AU - Bagryanskaya, Elena

AU - Edeleva, Mariya

AU - Marque, Sylvain R.A.

AU - Yamasaki, Toshihide

N1 - Publisher Copyright: © 2017 The Royal Society of Chemistry.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Dual initiators for controlled radical/ionic polymerization reactions attract much attention in terms of preparation of new materials. We studied the potential of dual-initiator alkoxyamines 3 [based both on para-substituted aromatic ring for external triggering or initiation of orthogonal polymerization and on N-tert-butyl-N-(1-diethylphosphono-2,2-dimethylpropyl) nitroxide (SG1)] for nitroxide-mediated polymerization (NMP) with various monomers such as styrene, styrene sulphonate, 2-vinyl pyridine or methylmethacrylate. Alkoxyamines 3 were found to be as efficient in the NMP process as N-(2-methylpropyl)-N-(1-diethylphosphono-2,2-dimethylpropyl)-O-(2-carboxylprop-2-yl)hydroxylamine (1). Furthermore, in sharp contrast to 1, alkoxyamines 3 were easier to functionalize.

AB - Dual initiators for controlled radical/ionic polymerization reactions attract much attention in terms of preparation of new materials. We studied the potential of dual-initiator alkoxyamines 3 [based both on para-substituted aromatic ring for external triggering or initiation of orthogonal polymerization and on N-tert-butyl-N-(1-diethylphosphono-2,2-dimethylpropyl) nitroxide (SG1)] for nitroxide-mediated polymerization (NMP) with various monomers such as styrene, styrene sulphonate, 2-vinyl pyridine or methylmethacrylate. Alkoxyamines 3 were found to be as efficient in the NMP process as N-(2-methylpropyl)-N-(1-diethylphosphono-2,2-dimethylpropyl)-O-(2-carboxylprop-2-yl)hydroxylamine (1). Furthermore, in sharp contrast to 1, alkoxyamines 3 were easier to functionalize.

UR - http://www.scopus.com/inward/record.url?scp=85010303435&partnerID=8YFLogxK

U2 - 10.1039/c6ra27231b

DO - 10.1039/c6ra27231b

M3 - Article

AN - SCOPUS:85010303435

VL - 7

SP - 4993

EP - 5001

JO - RSC Advances

JF - RSC Advances

SN - 2046-2069

IS - 9

ER -

ID: 10314860