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Dithionite and sulfinate complexes from the reaction of SO2 with decamethylsamarocene. / Klementyeva, Svetlana V.; Arleth, Nicholas; Meyer, Karsten et al.

In: New Journal of Chemistry, Vol. 39, No. 10, 31.03.2015, p. 7589-7594.

Research output: Contribution to journal › Article › peer-review

Harvard

Klementyeva, SV, Arleth, N, Meyer, K, Konchenko, SN & Roesky, PW 2015, 'Dithionite and sulfinate complexes from the reaction of SO2 with decamethylsamarocene', New Journal of Chemistry, vol. 39, no. 10, pp. 7589-7594. https://doi.org/10.1039/c5nj00318k

APA

Klementyeva, S. V., Arleth, N., Meyer, K., Konchenko, S. N., & Roesky, P. W. (2015). Dithionite and sulfinate complexes from the reaction of SO2 with decamethylsamarocene. New Journal of Chemistry, 39(10), 7589-7594. https://doi.org/10.1039/c5nj00318k

Vancouver

Klementyeva SV, Arleth N, Meyer K, Konchenko SN, Roesky PW. Dithionite and sulfinate complexes from the reaction of SO2 with decamethylsamarocene. New Journal of Chemistry. 2015 Mar 31;39(10):7589-7594. doi: 10.1039/c5nj00318k

Author

Klementyeva, Svetlana V. ; Arleth, Nicholas ; Meyer, Karsten et al. / Dithionite and sulfinate complexes from the reaction of SO2 with decamethylsamarocene. In: New Journal of Chemistry. 2015 ; Vol. 39, No. 10. pp. 7589-7594.

BibTeX

@article{460e35ac5ff14dd093b2aeaf8fc78a60,
title = "Dithionite and sulfinate complexes from the reaction of SO2 with decamethylsamarocene",
abstract = "The reaction of [(η5-C5Me5)2Sm(THF)2] with SO2 resulted in four different products. The dimeric samarium complex [{(η5-C5Me5)2Sm(C5Me5SO2)}2] (1) crystallized from the reaction mixture first. The dithionite-sulfinate complex [{(η5-C5Me5)2Sm(S2O4)}2{(η5-C5Me5)Sm(C5Me5SO2)}2] (2), was obtained as the second major product after workup of the filtrate. Additionally, the dithionite complex [{(η5-C5Me5)2Sm}2(S2O4)] (3) and the sulfinate complex [{(η5-C5Me5)Sm}2(C5Me5SO2)4] (4) were isolated as minor products. All compounds were characterized by single crystal X-ray diffraction. As major reaction pathways, the reductive coupling of two SO2 molecules to form the dithionite anion S2O42- and the nucleophilic attack of one samarocene C5Me5 ligand on the sulfur atom of SO2 were observed.",
author = "Klementyeva, {Svetlana V.} and Nicholas Arleth and Karsten Meyer and Konchenko, {Sergey N.} and Roesky, {Peter W.}",
year = "2015",
month = mar,
day = "31",
doi = "10.1039/c5nj00318k",
language = "English",
volume = "39",
pages = "7589--7594",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "ROYAL SOC CHEMISTRY",
number = "10",

}

RIS

TY - JOUR

T1 - Dithionite and sulfinate complexes from the reaction of SO2 with decamethylsamarocene

AU - Klementyeva, Svetlana V.

AU - Arleth, Nicholas

AU - Meyer, Karsten

AU - Konchenko, Sergey N.

AU - Roesky, Peter W.

PY - 2015/3/31

Y1 - 2015/3/31

N2 - The reaction of [(η5-C5Me5)2Sm(THF)2] with SO2 resulted in four different products. The dimeric samarium complex [{(η5-C5Me5)2Sm(C5Me5SO2)}2] (1) crystallized from the reaction mixture first. The dithionite-sulfinate complex [{(η5-C5Me5)2Sm(S2O4)}2{(η5-C5Me5)Sm(C5Me5SO2)}2] (2), was obtained as the second major product after workup of the filtrate. Additionally, the dithionite complex [{(η5-C5Me5)2Sm}2(S2O4)] (3) and the sulfinate complex [{(η5-C5Me5)Sm}2(C5Me5SO2)4] (4) were isolated as minor products. All compounds were characterized by single crystal X-ray diffraction. As major reaction pathways, the reductive coupling of two SO2 molecules to form the dithionite anion S2O42- and the nucleophilic attack of one samarocene C5Me5 ligand on the sulfur atom of SO2 were observed.

AB - The reaction of [(η5-C5Me5)2Sm(THF)2] with SO2 resulted in four different products. The dimeric samarium complex [{(η5-C5Me5)2Sm(C5Me5SO2)}2] (1) crystallized from the reaction mixture first. The dithionite-sulfinate complex [{(η5-C5Me5)2Sm(S2O4)}2{(η5-C5Me5)Sm(C5Me5SO2)}2] (2), was obtained as the second major product after workup of the filtrate. Additionally, the dithionite complex [{(η5-C5Me5)2Sm}2(S2O4)] (3) and the sulfinate complex [{(η5-C5Me5)Sm}2(C5Me5SO2)4] (4) were isolated as minor products. All compounds were characterized by single crystal X-ray diffraction. As major reaction pathways, the reductive coupling of two SO2 molecules to form the dithionite anion S2O42- and the nucleophilic attack of one samarocene C5Me5 ligand on the sulfur atom of SO2 were observed.

UR - http://www.scopus.com/inward/record.url?scp=84942872390&partnerID=8YFLogxK

U2 - 10.1039/c5nj00318k

DO - 10.1039/c5nj00318k

M3 - Article

AN - SCOPUS:84942872390

VL - 39

SP - 7589

EP - 7594

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 10

ER -

ID: 25415190