Standard

Di-tert-butylcatecholate derivatives of titanocene. / Petrov, Pavel A.; Sukhikh, Taisiya S.; Nadolinny, Vladimir A. et al.

In: New Journal of Chemistry, Vol. 43, No. 17, 07.05.2019, p. 6636-6642.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Sukhikh, TS, Nadolinny, VA, Bogomyakov, AS, Laricheva, YA & Piskunov, AV 2019, 'Di-tert-butylcatecholate derivatives of titanocene', New Journal of Chemistry, vol. 43, no. 17, pp. 6636-6642. https://doi.org/10.1039/c9nj00771g

APA

Petrov, P. A., Sukhikh, T. S., Nadolinny, V. A., Bogomyakov, A. S., Laricheva, Y. A., & Piskunov, A. V. (2019). Di-tert-butylcatecholate derivatives of titanocene. New Journal of Chemistry, 43(17), 6636-6642. https://doi.org/10.1039/c9nj00771g

Vancouver

Petrov PA, Sukhikh TS, Nadolinny VA, Bogomyakov AS, Laricheva YA, Piskunov AV. Di-tert-butylcatecholate derivatives of titanocene. New Journal of Chemistry. 2019 May 7;43(17):6636-6642. doi: 10.1039/c9nj00771g

Author

Petrov, Pavel A. ; Sukhikh, Taisiya S. ; Nadolinny, Vladimir A. et al. / Di-tert-butylcatecholate derivatives of titanocene. In: New Journal of Chemistry. 2019 ; Vol. 43, No. 17. pp. 6636-6642.

BibTeX

@article{02c0a158d07241ddbf51062720eaf8f3,
title = "Di-tert-butylcatecholate derivatives of titanocene",
abstract = " Reaction of Cp 2 TiCl 2 (Cp = η 5 -C 5 H 5 ) with sodium 3,6-di-tert-butylcatecholate (Na 2 Cat 36 ) leads to mononuclear complex [Cp 2 TiCat 36 ], while the isomeric sodium 3,5-di-tert-butylcatecholate (Na 2 Cat 35 ) gives the mixed-valence binuclear complex [Cp 2 Ti(μ-Cat 35 ) 2 TiCp]. The latter was characterized by EPR spectroscopy and magnetic susceptibility measurements, and shown to be a Ti-centred radical. DFT calculations confirm that the unpaired electron is located on the Ti atom from the TiCp 2 fragment. ",
keywords = "REDOX-ACTIVE LIGANDS, VALENCE TAUTOMERISM, METAL-COMPLEXES, MAGNETIC-PROPERTIES, OXIDATIVE-ADDITION, CRYSTAL-STRUCTURES, ELECTRON-TRANSFER, CHEMISTRY, CATECHOLATE, APPROXIMATION",
author = "Petrov, {Pavel A.} and Sukhikh, {Taisiya S.} and Nadolinny, {Vladimir A.} and Bogomyakov, {Artem S.} and Laricheva, {Yuliya A.} and Piskunov, {Alexandr V.}",
year = "2019",
month = may,
day = "7",
doi = "10.1039/c9nj00771g",
language = "English",
volume = "43",
pages = "6636--6642",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "ROYAL SOC CHEMISTRY",
number = "17",

}

RIS

TY - JOUR

T1 - Di-tert-butylcatecholate derivatives of titanocene

AU - Petrov, Pavel A.

AU - Sukhikh, Taisiya S.

AU - Nadolinny, Vladimir A.

AU - Bogomyakov, Artem S.

AU - Laricheva, Yuliya A.

AU - Piskunov, Alexandr V.

PY - 2019/5/7

Y1 - 2019/5/7

N2 - Reaction of Cp 2 TiCl 2 (Cp = η 5 -C 5 H 5 ) with sodium 3,6-di-tert-butylcatecholate (Na 2 Cat 36 ) leads to mononuclear complex [Cp 2 TiCat 36 ], while the isomeric sodium 3,5-di-tert-butylcatecholate (Na 2 Cat 35 ) gives the mixed-valence binuclear complex [Cp 2 Ti(μ-Cat 35 ) 2 TiCp]. The latter was characterized by EPR spectroscopy and magnetic susceptibility measurements, and shown to be a Ti-centred radical. DFT calculations confirm that the unpaired electron is located on the Ti atom from the TiCp 2 fragment.

AB - Reaction of Cp 2 TiCl 2 (Cp = η 5 -C 5 H 5 ) with sodium 3,6-di-tert-butylcatecholate (Na 2 Cat 36 ) leads to mononuclear complex [Cp 2 TiCat 36 ], while the isomeric sodium 3,5-di-tert-butylcatecholate (Na 2 Cat 35 ) gives the mixed-valence binuclear complex [Cp 2 Ti(μ-Cat 35 ) 2 TiCp]. The latter was characterized by EPR spectroscopy and magnetic susceptibility measurements, and shown to be a Ti-centred radical. DFT calculations confirm that the unpaired electron is located on the Ti atom from the TiCp 2 fragment.

KW - REDOX-ACTIVE LIGANDS

KW - VALENCE TAUTOMERISM

KW - METAL-COMPLEXES

KW - MAGNETIC-PROPERTIES

KW - OXIDATIVE-ADDITION

KW - CRYSTAL-STRUCTURES

KW - ELECTRON-TRANSFER

KW - CHEMISTRY

KW - CATECHOLATE

KW - APPROXIMATION

UR - http://www.scopus.com/inward/record.url?scp=85064927253&partnerID=8YFLogxK

U2 - 10.1039/c9nj00771g

DO - 10.1039/c9nj00771g

M3 - Article

AN - SCOPUS:85064927253

VL - 43

SP - 6636

EP - 6642

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 17

ER -

ID: 20049449