Research output: Contribution to journal › Article › peer-review
Direct Determination of Cadmium, Lead, and Zinc in Mussels by Two-Stage Probe Atomization (TPA) Graphite Furnace Atomic Absorption Spectrometry (GFAAS). / Volzhenin, Artyom V.; Petrova, Natalya I.; Romanova, Tamara E. et al.
In: Analytical Letters, Vol. 54, No. 14, 2021, p. 2293-2303.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Direct Determination of Cadmium, Lead, and Zinc in Mussels by Two-Stage Probe Atomization (TPA) Graphite Furnace Atomic Absorption Spectrometry (GFAAS)
AU - Volzhenin, Artyom V.
AU - Petrova, Natalya I.
AU - Romanova, Tamara E.
AU - Saprykin, Anatoly I.
N1 - Funding Information: This work was funded by the Russian Science Support Foundation (19-74-311). Publisher Copyright: © 2020 Taylor & Francis Group, LLC. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021
Y1 - 2021
N2 - Seafood consumption may induce health risks due to its contamination by pollutants. In this study, the two-stage probe atomization technique (TPA) was combined with graphite furnace atomic absorption spectrometry (GFAAS) to develop a novel procedure for determining Cd, Pb and Zn in mussels collected in the Sea of Japan (Russia). The application of TPA eliminated organic matrix interferences during GFAAS determination of heavy metals and allowed significant reduction of the sample pretreatment processes. The procedure involved the formation of a suspension of treated lyophilized mussels that were inserted into graphite furnace. The limits of detection using the optimized conditions were 0.8, 10, and 0.4 ng/g for Cd, Pb, and Zn, respectively. Inductively coupled plasma–optical emission spectrometry (ICP-OES) was employed to characterize the accuracy of the developed technique. The concentrations of heavy metals in Crenomytilus Grayanus mussel tissues from Peter the Great bay did not exceed 8.2, 31 and 475 μg/g for Cd, Pb, and Zn and are considered to have no negative effects upon human health.
AB - Seafood consumption may induce health risks due to its contamination by pollutants. In this study, the two-stage probe atomization technique (TPA) was combined with graphite furnace atomic absorption spectrometry (GFAAS) to develop a novel procedure for determining Cd, Pb and Zn in mussels collected in the Sea of Japan (Russia). The application of TPA eliminated organic matrix interferences during GFAAS determination of heavy metals and allowed significant reduction of the sample pretreatment processes. The procedure involved the formation of a suspension of treated lyophilized mussels that were inserted into graphite furnace. The limits of detection using the optimized conditions were 0.8, 10, and 0.4 ng/g for Cd, Pb, and Zn, respectively. Inductively coupled plasma–optical emission spectrometry (ICP-OES) was employed to characterize the accuracy of the developed technique. The concentrations of heavy metals in Crenomytilus Grayanus mussel tissues from Peter the Great bay did not exceed 8.2, 31 and 475 μg/g for Cd, Pb, and Zn and are considered to have no negative effects upon human health.
KW - Cadmium
KW - electrothermal atomization
KW - graphite furnace atomic absorption spectrometry (GFAAS)
KW - lead
KW - mussels
KW - two-stage probe atomization (TPA)
KW - zinc
UR - http://www.scopus.com/inward/record.url?scp=85106785377&partnerID=8YFLogxK
U2 - 10.1080/00032719.2020.1856862
DO - 10.1080/00032719.2020.1856862
M3 - Article
AN - SCOPUS:85106785377
VL - 54
SP - 2293
EP - 2303
JO - Analytical Letters
JF - Analytical Letters
SN - 0003-2719
IS - 14
ER -
ID: 29236723