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Different Reactivity of As4 towards Disilenes and Silylenes. / Seitz, Andreas E.; Eckhardt, Maria; Sen, Sakya S. et al.

In: Angewandte Chemie - International Edition, Vol. 56, No. 23, 01.06.2017, p. 6655-6659.

Research output: Contribution to journal › Article › peer-review

Harvard

Seitz, AE, Eckhardt, M, Sen, SS, Erlebach, A, Peresypkina, EV, Roesky, HW, Sierka, M & Scheer, M 2017, 'Different Reactivity of As4 towards Disilenes and Silylenes', Angewandte Chemie - International Edition, vol. 56, no. 23, pp. 6655-6659. https://doi.org/10.1002/anie.201701740

APA

Seitz, A. E., Eckhardt, M., Sen, S. S., Erlebach, A., Peresypkina, E. V., Roesky, H. W., Sierka, M., & Scheer, M. (2017). Different Reactivity of As4 towards Disilenes and Silylenes. Angewandte Chemie - International Edition, 56(23), 6655-6659. https://doi.org/10.1002/anie.201701740

Vancouver

Seitz AE, Eckhardt M, Sen SS, Erlebach A, Peresypkina EV, Roesky HW et al. Different Reactivity of As4 towards Disilenes and Silylenes. Angewandte Chemie - International Edition. 2017 Jun 1;56(23):6655-6659. doi: 10.1002/anie.201701740

Author

Seitz, Andreas E. ; Eckhardt, Maria ; Sen, Sakya S. et al. / Different Reactivity of As4 towards Disilenes and Silylenes. In: Angewandte Chemie - International Edition. 2017 ; Vol. 56, No. 23. pp. 6655-6659.

BibTeX

@article{5f32a9f6387e4f6baa3f1a8619d103e8,
title = "Different Reactivity of As4 towards Disilenes and Silylenes",
abstract = "The activation of yellow arsenic is possible with the silylene [PhC(NtBu)2SiN(SiMe3)2] (1) and the disilene [(Me3Si)2N(η1-Me5C5)Si=Si(η1-Me5C5)N(SiMe3)2] (3). The reaction of As4 with 1 leads to the unprecedented As10 cage compound [(LSiN(SiMe3)2)3As10] (2; L=PhC(NtBu)2) with an As7 nortricyclane core stabilized by arsasilene moieties containing silicon(II)bis(trimethylsilyl)amide substituents. In contrast, the compound [Cp*{(SiMe3)2N}SiAs]2 (4) containing a butterfly-like diarsadisilabicyclo[1.1.0]butane unit is formed by the reaction of As4 with the disilene 3. Both compounds were characterized by single-crystal X-ray diffraction analysis, NMR spectroscopy, and mass spectrometry. The reaction outcomes demonstrate the different reaction behavior of yellow arsenic (As4) compared to white phosphorus (P4) in the reactions with the corresponding silylenes and disilenes.",
keywords = "arsenic, density functional calculations, silicon, silylene, small-molecule activation, TRANSFORMATION, COMPLEXES, P-4 ACTIVATION, ELEMENTS, TETRAHEDRON, CAGE COMPOUNDS, DINITROGEN, WHITE PHOSPHORUS, BOND, AGGREGATION",
author = "Seitz, {Andreas E.} and Maria Eckhardt and Sen, {Sakya S.} and Andreas Erlebach and Peresypkina, {Eugenia V.} and Roesky, {Herbert W.} and Marek Sierka and Manfred Scheer",
year = "2017",
month = jun,
day = "1",
doi = "10.1002/anie.201701740",
language = "English",
volume = "56",
pages = "6655--6659",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "23",

}

RIS

TY - JOUR

T1 - Different Reactivity of As4 towards Disilenes and Silylenes

AU - Seitz, Andreas E.

AU - Eckhardt, Maria

AU - Sen, Sakya S.

AU - Erlebach, Andreas

AU - Peresypkina, Eugenia V.

AU - Roesky, Herbert W.

AU - Sierka, Marek

AU - Scheer, Manfred

PY - 2017/6/1

Y1 - 2017/6/1

N2 - The activation of yellow arsenic is possible with the silylene [PhC(NtBu)2SiN(SiMe3)2] (1) and the disilene [(Me3Si)2N(η1-Me5C5)Si=Si(η1-Me5C5)N(SiMe3)2] (3). The reaction of As4 with 1 leads to the unprecedented As10 cage compound [(LSiN(SiMe3)2)3As10] (2; L=PhC(NtBu)2) with an As7 nortricyclane core stabilized by arsasilene moieties containing silicon(II)bis(trimethylsilyl)amide substituents. In contrast, the compound [Cp*{(SiMe3)2N}SiAs]2 (4) containing a butterfly-like diarsadisilabicyclo[1.1.0]butane unit is formed by the reaction of As4 with the disilene 3. Both compounds were characterized by single-crystal X-ray diffraction analysis, NMR spectroscopy, and mass spectrometry. The reaction outcomes demonstrate the different reaction behavior of yellow arsenic (As4) compared to white phosphorus (P4) in the reactions with the corresponding silylenes and disilenes.

AB - The activation of yellow arsenic is possible with the silylene [PhC(NtBu)2SiN(SiMe3)2] (1) and the disilene [(Me3Si)2N(η1-Me5C5)Si=Si(η1-Me5C5)N(SiMe3)2] (3). The reaction of As4 with 1 leads to the unprecedented As10 cage compound [(LSiN(SiMe3)2)3As10] (2; L=PhC(NtBu)2) with an As7 nortricyclane core stabilized by arsasilene moieties containing silicon(II)bis(trimethylsilyl)amide substituents. In contrast, the compound [Cp*{(SiMe3)2N}SiAs]2 (4) containing a butterfly-like diarsadisilabicyclo[1.1.0]butane unit is formed by the reaction of As4 with the disilene 3. Both compounds were characterized by single-crystal X-ray diffraction analysis, NMR spectroscopy, and mass spectrometry. The reaction outcomes demonstrate the different reaction behavior of yellow arsenic (As4) compared to white phosphorus (P4) in the reactions with the corresponding silylenes and disilenes.

KW - arsenic

KW - density functional calculations

KW - silicon

KW - silylene

KW - small-molecule activation

KW - TRANSFORMATION

KW - COMPLEXES

KW - P-4 ACTIVATION

KW - ELEMENTS

KW - TETRAHEDRON

KW - CAGE COMPOUNDS

KW - DINITROGEN

KW - WHITE PHOSPHORUS

KW - BOND

KW - AGGREGATION

UR - http://www.scopus.com/inward/record.url?scp=85018447524&partnerID=8YFLogxK

U2 - 10.1002/anie.201701740

DO - 10.1002/anie.201701740

M3 - Article

AN - SCOPUS:85018447524

VL - 56

SP - 6655

EP - 6659

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 23

ER -

ID: 10262945