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Dichloroacetonitrile hydrogenation by osmium cluster : Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2). / Savkov, Boris Yu; Virovets, Alexander V.; Maksakov, Vladimir A.

In: Journal of Molecular Structure, Vol. 1141, 05.08.2017, p. 115-118.

Research output: Contribution to journal › Article › peer-review

Harvard

Savkov, BY, Virovets, AV & Maksakov, VA 2017, 'Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2)', Journal of Molecular Structure, vol. 1141, pp. 115-118. https://doi.org/10.1016/j.molstruc.2017.03.093

APA

Savkov, B. Y., Virovets, A. V., & Maksakov, V. A. (2017). Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2). Journal of Molecular Structure, 1141, 115-118. https://doi.org/10.1016/j.molstruc.2017.03.093

Vancouver

Savkov BY, Virovets AV, Maksakov VA. Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2). Journal of Molecular Structure. 2017 Aug 5;1141:115-118. doi: 10.1016/j.molstruc.2017.03.093

Author

Savkov, Boris Yu ; Virovets, Alexander V. ; Maksakov, Vladimir A. / Dichloroacetonitrile hydrogenation by osmium cluster : Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2). In: Journal of Molecular Structure. 2017 ; Vol. 1141. pp. 115-118.

BibTeX

@article{30e9128108804c33a86ac87cd4be8c6d,
title = "Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2)",
abstract = "Dichloroacetonitrile undergoes hydrogenation by triosmium dihydride cluster under mild conditions. The reaction of cluster complex (μ-H)2Os3(CO)10 (1) with CHCl2CN in the presence of morpholine as a base results in two novel compounds (μ-Cl)Os3(CO)10(μ-N=CHCHCl2) (2) and (μ-H)Os3(CO)10(μ,η2-HN=CHCHCl2) (3). Both compounds were characterized using FTIR, 13C, 1H NMR spectra, and CHN analysis, molecular structure of 2 was determined by X-Ray diffraction study.",
keywords = "Hydrogenation, Osmium clusters, Transition metal cluster hydrides, MU-HYDRIDO-DECACARBONYLTRIOSMIUM, TRIOSMIUM CLUSTERS, CARBONYL HYDRIDES, H2OS3(CO)10, COMPLEXES, ISOMERIZATION, IRON, LIGANDS, NITRILE, MOLECULAR-GEOMETRY",
author = "Savkov, {Boris Yu} and Virovets, {Alexander V.} and Maksakov, {Vladimir A.}",
year = "2017",
month = aug,
day = "5",
doi = "10.1016/j.molstruc.2017.03.093",
language = "English",
volume = "1141",
pages = "115--118",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Dichloroacetonitrile hydrogenation by osmium cluster

T2 - Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2)

AU - Savkov, Boris Yu

AU - Virovets, Alexander V.

AU - Maksakov, Vladimir A.

PY - 2017/8/5

Y1 - 2017/8/5

N2 - Dichloroacetonitrile undergoes hydrogenation by triosmium dihydride cluster under mild conditions. The reaction of cluster complex (μ-H)2Os3(CO)10 (1) with CHCl2CN in the presence of morpholine as a base results in two novel compounds (μ-Cl)Os3(CO)10(μ-N=CHCHCl2) (2) and (μ-H)Os3(CO)10(μ,η2-HN=CHCHCl2) (3). Both compounds were characterized using FTIR, 13C, 1H NMR spectra, and CHN analysis, molecular structure of 2 was determined by X-Ray diffraction study.

AB - Dichloroacetonitrile undergoes hydrogenation by triosmium dihydride cluster under mild conditions. The reaction of cluster complex (μ-H)2Os3(CO)10 (1) with CHCl2CN in the presence of morpholine as a base results in two novel compounds (μ-Cl)Os3(CO)10(μ-N=CHCHCl2) (2) and (μ-H)Os3(CO)10(μ,η2-HN=CHCHCl2) (3). Both compounds were characterized using FTIR, 13C, 1H NMR spectra, and CHN analysis, molecular structure of 2 was determined by X-Ray diffraction study.

KW - Hydrogenation

KW - Osmium clusters

KW - Transition metal cluster hydrides

KW - MU-HYDRIDO-DECACARBONYLTRIOSMIUM

KW - TRIOSMIUM CLUSTERS

KW - CARBONYL HYDRIDES

KW - H2OS3(CO)10

KW - COMPLEXES

KW - ISOMERIZATION

KW - IRON

KW - LIGANDS

KW - NITRILE

KW - MOLECULAR-GEOMETRY

UR - http://www.scopus.com/inward/record.url?scp=85016311271&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2017.03.093

DO - 10.1016/j.molstruc.2017.03.093

M3 - Article

AN - SCOPUS:85016311271

VL - 1141

SP - 115

EP - 118

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -

ID: 9980628