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Decomposition of Ag2C2O4 in a spark plasma sintering apparatus : Morphological study and application for materials joining. / Dudina, D. V.; Matvienko, A. A.; Sidelnikov, A. A. et al.

In: Materials Today: Proceedings, Vol. 16, 2019, p. 187-190.

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Dudina DV, Matvienko AA, Sidelnikov AA, Legan MA, Mali VI, Esikov MA et al. Decomposition of Ag2C2O4 in a spark plasma sintering apparatus: Morphological study and application for materials joining. Materials Today: Proceedings. 2019;16:187-190. doi: 10.1016/j.matpr.2019.05.242

Author

Dudina, D. V. ; Matvienko, A. A. ; Sidelnikov, A. A. et al. / Decomposition of Ag2C2O4 in a spark plasma sintering apparatus : Morphological study and application for materials joining. In: Materials Today: Proceedings. 2019 ; Vol. 16. pp. 187-190.

BibTeX

@article{34d31ceb5a39413cbd74e11bf26b884f,
title = "Decomposition of Ag2C2O4 in a spark plasma sintering apparatus: Morphological study and application for materials joining",
abstract = "Silver oxalate Ag2C2O4 is an interesting compound from both fundamental and practical viewpoints. Decomposition of Ag2C2O4 results in the formation of metallic silver, whose size and morphology can be tailored for different applications. In this work, we focused on the morphological features of silver that forms upon decomposition of Ag2C2O4 in a spark plasma sintering (SPS) apparatus. While crystals heated in a conventional furnace decompose to produce silver in the form of a pseudomorph, decomposition induced by heating in a SPS chamber at a rate of 30 ºC·min-1 via a pressureless process results in the formation of foam-like porous silver. Decomposition of Ag2C2O4 was also carried out under pressure by placing the powder between copper plates and heating the assembly in a SPS die. A feasibility study has shown that Ag2C2O4 powders can be used for joining copper plates in a fast process enabled by the SPS method. Joints formed by the SPS method at 300ºC and 13 MPa were formed by silver with 500-nm crystallites; the shear strength of the joints was 45 MPa.",
keywords = "Brazing, Decomposition, Morphology, Silver oxalate, Spark Plasma Sintering, brazing, morphology, decomposition, silver oxalate",
author = "Dudina, {D. V.} and Matvienko, {A. A.} and Sidelnikov, {A. A.} and Legan, {M. A.} and Mali, {V. I.} and Esikov, {M. A.} and Gribov, {P. A.} and Boldyrev, {V. V.}",
year = "2019",
doi = "10.1016/j.matpr.2019.05.242",
language = "English",
volume = "16",
pages = "187--190",
journal = "Materials Today: Proceedings",
issn = "2214-7853",
publisher = "Elsevier Science B.V.",
note = "6th International Symposium on Advanced Ceramics, ISAC 2018 ; Conference date: 10-03-2018 Through 12-03-2018",

}

RIS

TY - JOUR

T1 - Decomposition of Ag2C2O4 in a spark plasma sintering apparatus

T2 - 6th International Symposium on Advanced Ceramics, ISAC 2018

AU - Dudina, D. V.

AU - Matvienko, A. A.

AU - Sidelnikov, A. A.

AU - Legan, M. A.

AU - Mali, V. I.

AU - Esikov, M. A.

AU - Gribov, P. A.

AU - Boldyrev, V. V.

PY - 2019

Y1 - 2019

N2 - Silver oxalate Ag2C2O4 is an interesting compound from both fundamental and practical viewpoints. Decomposition of Ag2C2O4 results in the formation of metallic silver, whose size and morphology can be tailored for different applications. In this work, we focused on the morphological features of silver that forms upon decomposition of Ag2C2O4 in a spark plasma sintering (SPS) apparatus. While crystals heated in a conventional furnace decompose to produce silver in the form of a pseudomorph, decomposition induced by heating in a SPS chamber at a rate of 30 ºC·min-1 via a pressureless process results in the formation of foam-like porous silver. Decomposition of Ag2C2O4 was also carried out under pressure by placing the powder between copper plates and heating the assembly in a SPS die. A feasibility study has shown that Ag2C2O4 powders can be used for joining copper plates in a fast process enabled by the SPS method. Joints formed by the SPS method at 300ºC and 13 MPa were formed by silver with 500-nm crystallites; the shear strength of the joints was 45 MPa.

AB - Silver oxalate Ag2C2O4 is an interesting compound from both fundamental and practical viewpoints. Decomposition of Ag2C2O4 results in the formation of metallic silver, whose size and morphology can be tailored for different applications. In this work, we focused on the morphological features of silver that forms upon decomposition of Ag2C2O4 in a spark plasma sintering (SPS) apparatus. While crystals heated in a conventional furnace decompose to produce silver in the form of a pseudomorph, decomposition induced by heating in a SPS chamber at a rate of 30 ºC·min-1 via a pressureless process results in the formation of foam-like porous silver. Decomposition of Ag2C2O4 was also carried out under pressure by placing the powder between copper plates and heating the assembly in a SPS die. A feasibility study has shown that Ag2C2O4 powders can be used for joining copper plates in a fast process enabled by the SPS method. Joints formed by the SPS method at 300ºC and 13 MPa were formed by silver with 500-nm crystallites; the shear strength of the joints was 45 MPa.

KW - Brazing

KW - Decomposition

KW - Morphology

KW - Silver oxalate

KW - Spark Plasma Sintering

KW - brazing

KW - morphology

KW - decomposition

KW - silver oxalate

UR - http://www.scopus.com/inward/record.url?scp=85086914277&partnerID=8YFLogxK

U2 - 10.1016/j.matpr.2019.05.242

DO - 10.1016/j.matpr.2019.05.242

M3 - Conference article

AN - SCOPUS:85086914277

VL - 16

SP - 187

EP - 190

JO - Materials Today: Proceedings

JF - Materials Today: Proceedings

SN - 2214-7853

Y2 - 10 March 2018 through 12 March 2018

ER -

ID: 25862147