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Decay of Hexaniobate Complexes of Mn(IV) and Pt(IV) in Alkaline Solutions : Some New Hexaniobate Salts. / Shmakova, Alexandra A.; Shiriyazdanov, Rishat R.; Karimova, Albina R. et al.

In: Journal of Cluster Science, Vol. 29, No. 6, 01.11.2018, p. 1201-1207.

Research output: Contribution to journal › Article › peer-review

Harvard

Shmakova, AA, Shiriyazdanov, RR, Karimova, AR, Kompankov, NB, Abramov, PA & Sokolov, MN 2018, 'Decay of Hexaniobate Complexes of Mn(IV) and Pt(IV) in Alkaline Solutions: Some New Hexaniobate Salts', Journal of Cluster Science, vol. 29, no. 6, pp. 1201-1207. https://doi.org/10.1007/s10876-018-1439-6

APA

Shmakova, A. A., Shiriyazdanov, R. R., Karimova, A. R., Kompankov, N. B., Abramov, P. A., & Sokolov, M. N. (2018). Decay of Hexaniobate Complexes of Mn(IV) and Pt(IV) in Alkaline Solutions: Some New Hexaniobate Salts. Journal of Cluster Science, 29(6), 1201-1207. https://doi.org/10.1007/s10876-018-1439-6

Vancouver

Shmakova AA, Shiriyazdanov RR, Karimova AR, Kompankov NB, Abramov PA, Sokolov MN. Decay of Hexaniobate Complexes of Mn(IV) and Pt(IV) in Alkaline Solutions: Some New Hexaniobate Salts. Journal of Cluster Science. 2018 Nov 1;29(6):1201-1207. doi: 10.1007/s10876-018-1439-6

Author

Shmakova, Alexandra A. ; Shiriyazdanov, Rishat R. ; Karimova, Albina R. et al. / Decay of Hexaniobate Complexes of Mn(IV) and Pt(IV) in Alkaline Solutions : Some New Hexaniobate Salts. In: Journal of Cluster Science. 2018 ; Vol. 29, No. 6. pp. 1201-1207.

BibTeX

@article{65ca3d064d3047deb7ddb23daaa8ba23,
title = "Decay of Hexaniobate Complexes of Mn(IV) and Pt(IV) in Alkaline Solutions: Some New Hexaniobate Salts",
abstract = "This research summarizes the behavior [Mn(Nb6O19)2]12− and [(Nb6O19)2(Pt(OH)2)2]12− in basic solutions at pH 12. After heating of [Mn(Nb6O19)2]12− for 20 min at 60° in the presence of NaOH new very unstable phase Na8[Nb6O19]·25H2O (1) was obtained. Gentle (60 °C) heating of a solution of [(Nb6O19)2(Pt(OH)2)2]12− for 10 min in the presence of NaOH causes rearrangement into [Pt(Nb6O19)2]12−, which was isolated as Na12[Pt(Nb6O19)2]·52H2O (2). Longer heating yields white insoluble amorphous precipitate and crystals of a new hexaniobate phase K5Na3[Nb6O19]·9H2O (3). Crystal structures of the products and their structural relationship with known analogs are discussed.",
keywords = "Alkaline solutions, Manganese, Platinum, Polyoxoniobates, ROUTE, NIOBIUM, CRYSTAL-STRUCTURE, PLATINUM(IV), PT-195, NIOBATES, IV, SOLID-STATE",
author = "Shmakova, {Alexandra A.} and Shiriyazdanov, {Rishat R.} and Karimova, {Albina R.} and Kompankov, {Nikolay B.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
note = "Publisher Copyright: {\textcopyright} 2018, Springer Science+Business Media, LLC, part of Springer Nature.",
year = "2018",
month = nov,
day = "1",
doi = "10.1007/s10876-018-1439-6",
language = "English",
volume = "29",
pages = "1201--1207",
journal = "Journal of Cluster Science",
issn = "1040-7278",
publisher = "Springer New York",
number = "6",

}

RIS

TY - JOUR

T1 - Decay of Hexaniobate Complexes of Mn(IV) and Pt(IV) in Alkaline Solutions

T2 - Some New Hexaniobate Salts

AU - Shmakova, Alexandra A.

AU - Shiriyazdanov, Rishat R.

AU - Karimova, Albina R.

AU - Kompankov, Nikolay B.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

N1 - Publisher Copyright: © 2018, Springer Science+Business Media, LLC, part of Springer Nature.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - This research summarizes the behavior [Mn(Nb6O19)2]12− and [(Nb6O19)2(Pt(OH)2)2]12− in basic solutions at pH 12. After heating of [Mn(Nb6O19)2]12− for 20 min at 60° in the presence of NaOH new very unstable phase Na8[Nb6O19]·25H2O (1) was obtained. Gentle (60 °C) heating of a solution of [(Nb6O19)2(Pt(OH)2)2]12− for 10 min in the presence of NaOH causes rearrangement into [Pt(Nb6O19)2]12−, which was isolated as Na12[Pt(Nb6O19)2]·52H2O (2). Longer heating yields white insoluble amorphous precipitate and crystals of a new hexaniobate phase K5Na3[Nb6O19]·9H2O (3). Crystal structures of the products and their structural relationship with known analogs are discussed.

AB - This research summarizes the behavior [Mn(Nb6O19)2]12− and [(Nb6O19)2(Pt(OH)2)2]12− in basic solutions at pH 12. After heating of [Mn(Nb6O19)2]12− for 20 min at 60° in the presence of NaOH new very unstable phase Na8[Nb6O19]·25H2O (1) was obtained. Gentle (60 °C) heating of a solution of [(Nb6O19)2(Pt(OH)2)2]12− for 10 min in the presence of NaOH causes rearrangement into [Pt(Nb6O19)2]12−, which was isolated as Na12[Pt(Nb6O19)2]·52H2O (2). Longer heating yields white insoluble amorphous precipitate and crystals of a new hexaniobate phase K5Na3[Nb6O19]·9H2O (3). Crystal structures of the products and their structural relationship with known analogs are discussed.

KW - Alkaline solutions

KW - Manganese

KW - Platinum

KW - Polyoxoniobates

KW - ROUTE

KW - NIOBIUM

KW - CRYSTAL-STRUCTURE

KW - PLATINUM(IV)

KW - PT-195

KW - NIOBATES

KW - IV

KW - SOLID-STATE

UR - http://www.scopus.com/inward/record.url?scp=85052145785&partnerID=8YFLogxK

U2 - 10.1007/s10876-018-1439-6

DO - 10.1007/s10876-018-1439-6

M3 - Article

AN - SCOPUS:85052145785

VL - 29

SP - 1201

EP - 1207

JO - Journal of Cluster Science

JF - Journal of Cluster Science

SN - 1040-7278

IS - 6

ER -

ID: 16226101