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DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks. / Kozlova, S. G.; Mirzaeva, I. V.; Ryzhikov, M. R.

In: Coordination Chemistry Reviews, Vol. 376, 01.12.2018, p. 62-74.

Research output: Contribution to journal › Review article › peer-review

Harvard

Kozlova, SG, Mirzaeva, IV & Ryzhikov, MR 2018, 'DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks', Coordination Chemistry Reviews, vol. 376, pp. 62-74. https://doi.org/10.1016/j.ccr.2018.07.008

APA

Kozlova, S. G., Mirzaeva, I. V., & Ryzhikov, M. R. (2018). DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks. Coordination Chemistry Reviews, 376, 62-74. https://doi.org/10.1016/j.ccr.2018.07.008

Vancouver

Kozlova SG, Mirzaeva IV, Ryzhikov MR. DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks. Coordination Chemistry Reviews. 2018 Dec 1;376:62-74. doi: 10.1016/j.ccr.2018.07.008

Author

Kozlova, S. G. ; Mirzaeva, I. V. ; Ryzhikov, M. R. / DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks. In: Coordination Chemistry Reviews. 2018 ; Vol. 376. pp. 62-74.

BibTeX

@article{2ed6d9e113554b5b8cd18566b2a011a4,
title = "DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks",
abstract = "The review reports recent progress in experimental and theoretical studies of structure and properties of the C6H12N2 molecule (DABCO) in metal-organic frameworks M2(C8H4O4)2 C6H12N2, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D3 symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.",
keywords = "DABCO, M-DMOF, Mobility, Parity violation, Phase transition, Quantum tunneling, THERMODYNAMIC PROPERTIES, PHASE-TRANSITIONS, CRYSTAL-STRUCTURE, VIBRATIONAL-SPECTRA, BOSE-EINSTEIN CONDENSATION, CATALYZED SUZUKI-MIYAURA, HEAT-CAPACITIES, PARITY-SYMMETRY-BREAKING, NUCLEAR-QUADRUPOLE-RESONANCE, D-ALANINE",
author = "Kozlova, {S. G.} and Mirzaeva, {I. V.} and Ryzhikov, {M. R.}",
year = "2018",
month = dec,
day = "1",
doi = "10.1016/j.ccr.2018.07.008",
language = "English",
volume = "376",
pages = "62--74",
journal = "Coordination Chemistry Reviews",
issn = "0010-8545",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks

AU - Kozlova, S. G.

AU - Mirzaeva, I. V.

AU - Ryzhikov, M. R.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - The review reports recent progress in experimental and theoretical studies of structure and properties of the C6H12N2 molecule (DABCO) in metal-organic frameworks M2(C8H4O4)2 C6H12N2, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D3 symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.

AB - The review reports recent progress in experimental and theoretical studies of structure and properties of the C6H12N2 molecule (DABCO) in metal-organic frameworks M2(C8H4O4)2 C6H12N2, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D3 symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.

KW - DABCO

KW - M-DMOF

KW - Mobility

KW - Parity violation

KW - Phase transition

KW - Quantum tunneling

KW - THERMODYNAMIC PROPERTIES

KW - PHASE-TRANSITIONS

KW - CRYSTAL-STRUCTURE

KW - VIBRATIONAL-SPECTRA

KW - BOSE-EINSTEIN CONDENSATION

KW - CATALYZED SUZUKI-MIYAURA

KW - HEAT-CAPACITIES

KW - PARITY-SYMMETRY-BREAKING

KW - NUCLEAR-QUADRUPOLE-RESONANCE

KW - D-ALANINE

UR - http://www.scopus.com/inward/record.url?scp=85051390598&partnerID=8YFLogxK

U2 - 10.1016/j.ccr.2018.07.008

DO - 10.1016/j.ccr.2018.07.008

M3 - Review article

AN - SCOPUS:85051390598

VL - 376

SP - 62

EP - 74

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

SN - 0010-8545

ER -

ID: 16081601