Standard

Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; Dppe = 1,2-bis(diphenylphosphino)ethane). / Afonin, Mikhail Yu; Smolentsev, Anton I.; Konchenko, Sergey N. et al.

In: Journal of Coordination Chemistry, Vol. 68, No. 3, 01.02.2015, p. 422-431.

Research output: Contribution to journal › Article › peer-review

Harvard

Afonin, MY, Smolentsev, AI, Konchenko, SN & Petrov, PA 2015, 'Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; Dppe = 1,2-bis(diphenylphosphino)ethane)', Journal of Coordination Chemistry, vol. 68, no. 3, pp. 422-431. https://doi.org/10.1080/00958972.2014.992888

APA

Afonin, M. Y., Smolentsev, A. I., Konchenko, S. N., & Petrov, P. A. (2015). Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; Dppe = 1,2-bis(diphenylphosphino)ethane). Journal of Coordination Chemistry, 68(3), 422-431. https://doi.org/10.1080/00958972.2014.992888

Vancouver

Afonin MY, Smolentsev AI, Konchenko SN, Petrov PA. Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; Dppe = 1,2-bis(diphenylphosphino)ethane). Journal of Coordination Chemistry. 2015 Feb 1;68(3):422-431. doi: 10.1080/00958972.2014.992888

Author

Afonin, Mikhail Yu ; Smolentsev, Anton I. ; Konchenko, Sergey N. et al. / Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; Dppe = 1,2-bis(diphenylphosphino)ethane). In: Journal of Coordination Chemistry. 2015 ; Vol. 68, No. 3. pp. 422-431.

BibTeX

@article{690dbc4db79548678aad7bf4da151d5e,
title = "Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; Dppe = 1,2-bis(diphenylphosphino)ethane)",
abstract = "Two pseudohalido-substituted cluster complexes, [Mo3S4(dppe)3(NCS)3]NCS (1) and [Mo3S4(dppe)3(NCO)3]Br (2) (dppe = 1,2-bis(diphenylphosphino)ethane), have been synthesized by substitution between [Mo3S4(dppe)3Br3]Br and potassium thiocyanate or sodium cyanate, respectively, in boiling acetonitrile. The compounds were characterized by IR-spectroscopy, elemental analysis, electrospray mass-spectrometry, and single-crystal X-ray diffraction analysis. Both compounds crystallize as toluene solvates (1·3C6H5CH3 and 2·2.5C6H5CH3) in space group with similar unit cell dimensions and adopt very similar molecular geometries. Both structures consist of discrete cluster cations [Mo3S4(dppe)3X3]+, NCS- or Br- anions, and solvate toluene molecules.",
keywords = "Chalcogenides, Crystal structure, Mass-spectrometry, Molybdenum, Pseudohalides, Triangular clusters",
author = "Afonin, {Mikhail Yu} and Smolentsev, {Anton I.} and Konchenko, {Sergey N.} and Petrov, {Pavel A.}",
year = "2015",
month = feb,
day = "1",
doi = "10.1080/00958972.2014.992888",
language = "English",
volume = "68",
pages = "422--431",
journal = "Journal of Coordination Chemistry",
issn = "0095-8972",
publisher = "Taylor and Francis Ltd.",
number = "3",

}

RIS

TY - JOUR

T1 - Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; Dppe = 1,2-bis(diphenylphosphino)ethane)

AU - Afonin, Mikhail Yu

AU - Smolentsev, Anton I.

AU - Konchenko, Sergey N.

AU - Petrov, Pavel A.

PY - 2015/2/1

Y1 - 2015/2/1

N2 - Two pseudohalido-substituted cluster complexes, [Mo3S4(dppe)3(NCS)3]NCS (1) and [Mo3S4(dppe)3(NCO)3]Br (2) (dppe = 1,2-bis(diphenylphosphino)ethane), have been synthesized by substitution between [Mo3S4(dppe)3Br3]Br and potassium thiocyanate or sodium cyanate, respectively, in boiling acetonitrile. The compounds were characterized by IR-spectroscopy, elemental analysis, electrospray mass-spectrometry, and single-crystal X-ray diffraction analysis. Both compounds crystallize as toluene solvates (1·3C6H5CH3 and 2·2.5C6H5CH3) in space group with similar unit cell dimensions and adopt very similar molecular geometries. Both structures consist of discrete cluster cations [Mo3S4(dppe)3X3]+, NCS- or Br- anions, and solvate toluene molecules.

AB - Two pseudohalido-substituted cluster complexes, [Mo3S4(dppe)3(NCS)3]NCS (1) and [Mo3S4(dppe)3(NCO)3]Br (2) (dppe = 1,2-bis(diphenylphosphino)ethane), have been synthesized by substitution between [Mo3S4(dppe)3Br3]Br and potassium thiocyanate or sodium cyanate, respectively, in boiling acetonitrile. The compounds were characterized by IR-spectroscopy, elemental analysis, electrospray mass-spectrometry, and single-crystal X-ray diffraction analysis. Both compounds crystallize as toluene solvates (1·3C6H5CH3 and 2·2.5C6H5CH3) in space group with similar unit cell dimensions and adopt very similar molecular geometries. Both structures consist of discrete cluster cations [Mo3S4(dppe)3X3]+, NCS- or Br- anions, and solvate toluene molecules.

KW - Chalcogenides

KW - Crystal structure

KW - Mass-spectrometry

KW - Molybdenum

KW - Pseudohalides

KW - Triangular clusters

UR - http://www.scopus.com/inward/record.url?scp=84943610058&partnerID=8YFLogxK

U2 - 10.1080/00958972.2014.992888

DO - 10.1080/00958972.2014.992888

M3 - Article

AN - SCOPUS:84943610058

VL - 68

SP - 422

EP - 431

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

SN - 0095-8972

IS - 3

ER -

ID: 25415084