Standard

Cu2ZnSnS4crystal growth using an SnCl2based flux. / Kokh, K. A.; Atuchin, V. V.; Adichtchev, S. V. et al.

In: CrystEngComm, Vol. 23, No. 4, 28.01.2021, p. 1025-1032.

Research output: Contribution to journal › Article › peer-review

Harvard

Kokh, KA, Atuchin, VV, Adichtchev, SV, Gavrilova, TA, Bakhadur, AM, Klimov, AO, Korolkov, IV, Kuratieva, NV, Mukherjee, S, Pervukhina, NV & Surovtsev, NV 2021, 'Cu2ZnSnS4crystal growth using an SnCl2based flux', CrystEngComm, vol. 23, no. 4, pp. 1025-1032. https://doi.org/10.1039/d0ce01264e

APA

Kokh, K. A., Atuchin, V. V., Adichtchev, S. V., Gavrilova, T. A., Bakhadur, A. M., Klimov, A. O., Korolkov, I. V., Kuratieva, N. V., Mukherjee, S., Pervukhina, N. V., & Surovtsev, N. V. (2021). Cu2ZnSnS4crystal growth using an SnCl2based flux. CrystEngComm, 23(4), 1025-1032. https://doi.org/10.1039/d0ce01264e

Vancouver

Kokh KA, Atuchin VV, Adichtchev SV, Gavrilova TA, Bakhadur AM, Klimov AO et al. Cu2ZnSnS4crystal growth using an SnCl2based flux. CrystEngComm. 2021 Jan 28;23(4):1025-1032. doi: 10.1039/d0ce01264e

Author

Kokh, K. A. ; Atuchin, V. V. ; Adichtchev, S. V. et al. / Cu2ZnSnS4crystal growth using an SnCl2based flux. In: CrystEngComm. 2021 ; Vol. 23, No. 4. pp. 1025-1032.

BibTeX

@article{c4df960071a2428c9b09603630f4c1f4,
title = "Cu2ZnSnS4crystal growth using an SnCl2based flux",
abstract = "The stoichiometry and phase homogeneity of the kesterite type compound Cu2ZnSnS4play a key role in its efficiency in solar cells. In this work, CuCl2, ZnCl2and SnCl2were applied as solvents in the Cu2ZnSnS4crystal growth for the first time. The multiphase ingot was obtained by direct fusion of the stoichiometric batch composed of constituent elements. Compared to that, the material recrystallized in SnCl2presented a single-phase Zn-rich kesterite with composition Cu1.94Zn1.06SnS4and unit cell parameters ofa= 5.4324(3) andc= 10.8383(2) {\AA}. The crystal structure of Cu1.94Zn1.06SnS4was determined by single crystal X-ray diffraction analysis. The integral phase purity of the crystals grown with the use of the SnCl2solvent was verified by powder X-ray diffraction analysis and Raman measurements. In the Raman spectrum, the FWHM value of the 337 cm−1line was as low as 9.6 cm−1that indicates the minimal lattice disorder.",
author = "Kokh, {K. A.} and Atuchin, {V. V.} and Adichtchev, {S. V.} and Gavrilova, {T. A.} and Bakhadur, {A. M.} and Klimov, {A. O.} and Korolkov, {I. V.} and Kuratieva, {N. V.} and S. Mukherjee and Pervukhina, {N. V.} and Surovtsev, {N. V.}",
note = "Funding Information: This work was supported by the Russian Science Foundation (project 19-42-02003), the Ministry of Science and Higher Education of Russia (projects 075-15-2020-797 (13.1902.21.0024) and AAAA-A17-117052410033-9), the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (Grant No. AP08052719), state assignment of IGM SB RAS, and the DST-RSF Bilateral Project (No. DST/INT/RUS/RSF/P-20 dated May 16, 2019). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = jan,
day = "28",
doi = "10.1039/d0ce01264e",
language = "English",
volume = "23",
pages = "1025--1032",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "4",

}

RIS

TY - JOUR

T1 - Cu2ZnSnS4crystal growth using an SnCl2based flux

AU - Kokh, K. A.

AU - Atuchin, V. V.

AU - Adichtchev, S. V.

AU - Gavrilova, T. A.

AU - Bakhadur, A. M.

AU - Klimov, A. O.

AU - Korolkov, I. V.

AU - Kuratieva, N. V.

AU - Mukherjee, S.

AU - Pervukhina, N. V.

AU - Surovtsev, N. V.

N1 - Funding Information: This work was supported by the Russian Science Foundation (project 19-42-02003), the Ministry of Science and Higher Education of Russia (projects 075-15-2020-797 (13.1902.21.0024) and AAAA-A17-117052410033-9), the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (Grant No. AP08052719), state assignment of IGM SB RAS, and the DST-RSF Bilateral Project (No. DST/INT/RUS/RSF/P-20 dated May 16, 2019). Publisher Copyright: © The Royal Society of Chemistry 2021. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/1/28

Y1 - 2021/1/28

N2 - The stoichiometry and phase homogeneity of the kesterite type compound Cu2ZnSnS4play a key role in its efficiency in solar cells. In this work, CuCl2, ZnCl2and SnCl2were applied as solvents in the Cu2ZnSnS4crystal growth for the first time. The multiphase ingot was obtained by direct fusion of the stoichiometric batch composed of constituent elements. Compared to that, the material recrystallized in SnCl2presented a single-phase Zn-rich kesterite with composition Cu1.94Zn1.06SnS4and unit cell parameters ofa= 5.4324(3) andc= 10.8383(2) Å. The crystal structure of Cu1.94Zn1.06SnS4was determined by single crystal X-ray diffraction analysis. The integral phase purity of the crystals grown with the use of the SnCl2solvent was verified by powder X-ray diffraction analysis and Raman measurements. In the Raman spectrum, the FWHM value of the 337 cm−1line was as low as 9.6 cm−1that indicates the minimal lattice disorder.

AB - The stoichiometry and phase homogeneity of the kesterite type compound Cu2ZnSnS4play a key role in its efficiency in solar cells. In this work, CuCl2, ZnCl2and SnCl2were applied as solvents in the Cu2ZnSnS4crystal growth for the first time. The multiphase ingot was obtained by direct fusion of the stoichiometric batch composed of constituent elements. Compared to that, the material recrystallized in SnCl2presented a single-phase Zn-rich kesterite with composition Cu1.94Zn1.06SnS4and unit cell parameters ofa= 5.4324(3) andc= 10.8383(2) Å. The crystal structure of Cu1.94Zn1.06SnS4was determined by single crystal X-ray diffraction analysis. The integral phase purity of the crystals grown with the use of the SnCl2solvent was verified by powder X-ray diffraction analysis and Raman measurements. In the Raman spectrum, the FWHM value of the 337 cm−1line was as low as 9.6 cm−1that indicates the minimal lattice disorder.

UR - http://www.scopus.com/inward/record.url?scp=85100278135&partnerID=8YFLogxK

U2 - 10.1039/d0ce01264e

DO - 10.1039/d0ce01264e

M3 - Article

AN - SCOPUS:85100278135

VL - 23

SP - 1025

EP - 1032

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 4

ER -

ID: 27707118