Standard

Crystallographic Analysis of TiO2 Polymorphism (Brookite, Anatase, Rutile). / Borisov, S. V.; Magarill, S. A.; Pervukhina, N. V.

In: Journal of Structural Chemistry, Vol. 60, No. 11, 01.11.2019, p. 1783-1789.

Research output: Contribution to journal › Article › peer-review

Harvard

Borisov, SV, Magarill, SA & Pervukhina, NV 2019, 'Crystallographic Analysis of TiO2 Polymorphism (Brookite, Anatase, Rutile)', Journal of Structural Chemistry, vol. 60, no. 11, pp. 1783-1789. https://doi.org/10.1134/S0022476619110118

APA

Borisov, S. V., Magarill, S. A., & Pervukhina, N. V. (2019). Crystallographic Analysis of TiO2 Polymorphism (Brookite, Anatase, Rutile). Journal of Structural Chemistry, 60(11), 1783-1789. https://doi.org/10.1134/S0022476619110118

Vancouver

Borisov SV, Magarill SA, Pervukhina NV. Crystallographic Analysis of TiO2 Polymorphism (Brookite, Anatase, Rutile). Journal of Structural Chemistry. 2019 Nov 1;60(11):1783-1789. doi: 10.1134/S0022476619110118

Author

Borisov, S. V. ; Magarill, S. A. ; Pervukhina, N. V. / Crystallographic Analysis of TiO2 Polymorphism (Brookite, Anatase, Rutile). In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 11. pp. 1783-1789.

BibTeX

@article{2b2fbb0defbf4aa78d800d27749c6a7b,
title = "Crystallographic Analysis of TiO2 Polymorphism (Brookite, Anatase, Rutile)",
abstract = "Crystallographic analysis of three TiO2 structures shows that all of them have a rhombohedral anion sublattice close to their cubic closest packing. In brookite it competes with the hexagonal packing, and the packing of TiO6 octahedra is less regular. High symmetry of anatase and rutile is initiated by the local (cubic) symmetry of TiO6 octahedra. Cations occupy most symmetrical special positions and provide a coherent assembly of these “building units” by spreading the local symmetry over the entire structure.",
keywords = "anatase, brookite, cation and anion sublattices, coherent assembly, crystallographic analysis, rutile, symmetry–stability, TiO polymorphism",
author = "Borisov, {S. V.} and Magarill, {S. A.} and Pervukhina, {N. V.}",
year = "2019",
month = nov,
day = "1",
doi = "10.1134/S0022476619110118",
language = "English",
volume = "60",
pages = "1783--1789",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "11",

}

RIS

TY - JOUR

T1 - Crystallographic Analysis of TiO2 Polymorphism (Brookite, Anatase, Rutile)

AU - Borisov, S. V.

AU - Magarill, S. A.

AU - Pervukhina, N. V.

PY - 2019/11/1

Y1 - 2019/11/1

N2 - Crystallographic analysis of three TiO2 structures shows that all of them have a rhombohedral anion sublattice close to their cubic closest packing. In brookite it competes with the hexagonal packing, and the packing of TiO6 octahedra is less regular. High symmetry of anatase and rutile is initiated by the local (cubic) symmetry of TiO6 octahedra. Cations occupy most symmetrical special positions and provide a coherent assembly of these “building units” by spreading the local symmetry over the entire structure.

AB - Crystallographic analysis of three TiO2 structures shows that all of them have a rhombohedral anion sublattice close to their cubic closest packing. In brookite it competes with the hexagonal packing, and the packing of TiO6 octahedra is less regular. High symmetry of anatase and rutile is initiated by the local (cubic) symmetry of TiO6 octahedra. Cations occupy most symmetrical special positions and provide a coherent assembly of these “building units” by spreading the local symmetry over the entire structure.

KW - anatase

KW - brookite

KW - cation and anion sublattices

KW - coherent assembly

KW - crystallographic analysis

KW - rutile

KW - symmetry–stability

KW - TiO polymorphism

UR - http://www.scopus.com/inward/record.url?scp=85076546222&partnerID=8YFLogxK

U2 - 10.1134/S0022476619110118

DO - 10.1134/S0022476619110118

M3 - Article

AN - SCOPUS:85076546222

VL - 60

SP - 1783

EP - 1789

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 11

ER -

ID: 23003216