Standard

Crystallographic Analysis of the Genesis of the Structure Symmetry of Acid Sulfates M 3 H(SO 4 ) 2 (M = K, NH 4 ). / Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A.

In: Journal of Structural Chemistry, Vol. 60, No. 4, 01.04.2019, p. 602-608.

Research output: Contribution to journal › Article › peer-review

Harvard

Borisov, SV, Pervukhina, NV & Magarill, SA 2019, 'Crystallographic Analysis of the Genesis of the Structure Symmetry of Acid Sulfates M 3 H(SO 4 ) 2 (M = K, NH 4 )', Journal of Structural Chemistry, vol. 60, no. 4, pp. 602-608. https://doi.org/10.1134/S0022476619040103

APA

Borisov, S. V., Pervukhina, N. V., & Magarill, S. A. (2019). Crystallographic Analysis of the Genesis of the Structure Symmetry of Acid Sulfates M 3 H(SO 4 ) 2 (M = K, NH 4 ). Journal of Structural Chemistry, 60(4), 602-608. https://doi.org/10.1134/S0022476619040103

Vancouver

Borisov SV, Pervukhina NV, Magarill SA. Crystallographic Analysis of the Genesis of the Structure Symmetry of Acid Sulfates M 3 H(SO 4 ) 2 (M = K, NH 4 ). Journal of Structural Chemistry. 2019 Apr 1;60(4):602-608. doi: 10.1134/S0022476619040103

Author

Borisov, S. V. ; Pervukhina, N. V. ; Magarill, S. A. / Crystallographic Analysis of the Genesis of the Structure Symmetry of Acid Sulfates M 3 H(SO 4 ) 2 (M = K, NH 4 ). In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 4. pp. 602-608.

BibTeX

@article{037f4107fe42455584123e9159a315ff,
title = "Crystallographic Analysis of the Genesis of the Structure Symmetry of Acid Sulfates M 3 H(SO 4 ) 2 (M = K, NH 4 )",
abstract = " The crystallographic analysis of five compositionally similar structures shows that the R3 ¯ -symmetrical trigonal structure and two monoclinic (C2/c) structures with the ratio M:S = 3:2 that is the same for all three have identical cation sublattices and similar real configurations of atomic positions. Two structures with M:S = 9:8, with the orthorhombic symmetry (Pcan) and with its monoclinic distortion (P2 1 /c), have identical cation sublattices. In the first group of the structures the symmetry and pseudosymmetry are determined by the SO 4 template symmetry, namely, axis 3. In the second group the symmetry of cation frameworks and structures in general is partially formed by three mutually perpendicular axes 4 ¯ of the SO 4 tetrahedra. ",
keywords = "cation sublattices, crystallographic analysis, M H(SO ) structures, SO template symmetry, symmetry-stability, STABILITY, SO4 template symmetry, M3H(SO4)(2) structures",
author = "Borisov, {S. V.} and Pervukhina, {N. V.} and Magarill, {S. A.}",
year = "2019",
month = apr,
day = "1",
doi = "10.1134/S0022476619040103",
language = "English",
volume = "60",
pages = "602--608",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "4",

}

RIS

TY - JOUR

T1 - Crystallographic Analysis of the Genesis of the Structure Symmetry of Acid Sulfates M 3 H(SO 4 ) 2 (M = K, NH 4 )

AU - Borisov, S. V.

AU - Pervukhina, N. V.

AU - Magarill, S. A.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - The crystallographic analysis of five compositionally similar structures shows that the R3 ¯ -symmetrical trigonal structure and two monoclinic (C2/c) structures with the ratio M:S = 3:2 that is the same for all three have identical cation sublattices and similar real configurations of atomic positions. Two structures with M:S = 9:8, with the orthorhombic symmetry (Pcan) and with its monoclinic distortion (P2 1 /c), have identical cation sublattices. In the first group of the structures the symmetry and pseudosymmetry are determined by the SO 4 template symmetry, namely, axis 3. In the second group the symmetry of cation frameworks and structures in general is partially formed by three mutually perpendicular axes 4 ¯ of the SO 4 tetrahedra.

AB - The crystallographic analysis of five compositionally similar structures shows that the R3 ¯ -symmetrical trigonal structure and two monoclinic (C2/c) structures with the ratio M:S = 3:2 that is the same for all three have identical cation sublattices and similar real configurations of atomic positions. Two structures with M:S = 9:8, with the orthorhombic symmetry (Pcan) and with its monoclinic distortion (P2 1 /c), have identical cation sublattices. In the first group of the structures the symmetry and pseudosymmetry are determined by the SO 4 template symmetry, namely, axis 3. In the second group the symmetry of cation frameworks and structures in general is partially formed by three mutually perpendicular axes 4 ¯ of the SO 4 tetrahedra.

KW - cation sublattices

KW - crystallographic analysis

KW - M H(SO ) structures

KW - SO template symmetry

KW - symmetry-stability

KW - STABILITY

KW - SO4 template symmetry

KW - M3H(SO4)(2) structures

UR - http://www.scopus.com/inward/record.url?scp=85065340781&partnerID=8YFLogxK

U2 - 10.1134/S0022476619040103

DO - 10.1134/S0022476619040103

M3 - Article

AN - SCOPUS:85065340781

VL - 60

SP - 602

EP - 608

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 20166395