Research output: Contribution to journal › Article › peer-review
Crystal structures of [M(Еn)3](ReO4)2 (M = Ni, Zn). / Khranenko, S. P.; Bykova, E. A.; Zadesenets, A. V. et al.
In: Journal of Structural Chemistry, Vol. 58, No. 1, 01.01.2017, p. 90-96.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Crystal structures of [M(Еn)3](ReO4)2 (M = Ni, Zn)
AU - Khranenko, S. P.
AU - Bykova, E. A.
AU - Zadesenets, A. V.
AU - Gromilov, S. A.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - The structures of two isostructural phases of [M(Еn)3](ReO4)2 (M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)3](ReO4)2 (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.
AB - The structures of two isostructural phases of [M(Еn)3](ReO4)2 (M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)3](ReO4)2 (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.
KW - crystal chemistry
KW - ethylenediamine
KW - nickel
KW - rhenium
KW - single crystal X-ray diffraction study
KW - zinc
KW - THERMOLYSIS
KW - THERMAL-PROPERTIES
KW - SOLID-SOLUTIONS
KW - SALTS
UR - http://www.scopus.com/inward/record.url?scp=85016007138&partnerID=8YFLogxK
U2 - 10.1134/S0022476617010139
DO - 10.1134/S0022476617010139
M3 - Article
AN - SCOPUS:85016007138
VL - 58
SP - 90
EP - 96
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 1
ER -
ID: 10270317