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Crystal Structures of [Dy(dpm)3]2 and Dy(dpm)3, Luminescent and X-Ray Fluorescent Study of Lanthanide(III) Tris-Dipivaloylmethanates. / Shen, Huang; Berezin, A. S.; Antonova, O. V. et al.

In: Journal of Structural Chemistry, Vol. 59, No. 3, 01.05.2018, p. 676-683.

Research output: Contribution to journal › Article › peer-review

Harvard

Shen, H, Berezin, AS, Antonova, OV, Zvereva, VV, Korolkov, IV, Pervukhina, NV, Prokhorova, SA & Stabnikov, PA 2018, 'Crystal Structures of [Dy(dpm)3]2 and Dy(dpm)3, Luminescent and X-Ray Fluorescent Study of Lanthanide(III) Tris-Dipivaloylmethanates', Journal of Structural Chemistry, vol. 59, no. 3, pp. 676-683. https://doi.org/10.1134/S0022476618030265

APA

Shen, H., Berezin, A. S., Antonova, O. V., Zvereva, V. V., Korolkov, I. V., Pervukhina, N. V., Prokhorova, S. A., & Stabnikov, P. A. (2018). Crystal Structures of [Dy(dpm)3]2 and Dy(dpm)3, Luminescent and X-Ray Fluorescent Study of Lanthanide(III) Tris-Dipivaloylmethanates. Journal of Structural Chemistry, 59(3), 676-683. https://doi.org/10.1134/S0022476618030265

Vancouver

Shen H, Berezin AS, Antonova OV, Zvereva VV, Korolkov IV, Pervukhina NV et al. Crystal Structures of [Dy(dpm)3]2 and Dy(dpm)3, Luminescent and X-Ray Fluorescent Study of Lanthanide(III) Tris-Dipivaloylmethanates. Journal of Structural Chemistry. 2018 May 1;59(3):676-683. doi: 10.1134/S0022476618030265

Author

Shen, Huang ; Berezin, A. S. ; Antonova, O. V. et al. / Crystal Structures of [Dy(dpm)3]2 and Dy(dpm)3, Luminescent and X-Ray Fluorescent Study of Lanthanide(III) Tris-Dipivaloylmethanates. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 3. pp. 676-683.

BibTeX

@article{8e00202218b843fdadd16bc8dec00956,
title = "Crystal Structures of [Dy(dpm)3]2 and Dy(dpm)3, Luminescent and X-Ray Fluorescent Study of Lanthanide(III) Tris-Dipivaloylmethanates",
abstract = "Crystal structures of [Dy(dpm)3]2 (1) at 155(2) K (space group P21/n, a = 12.2191(3) {\AA}, b = 27.6044(6) {\AA}, с = 21.8615(5) {\AA}, β = 105.172(1)°, V = 7116.9(3) {\AA}3, Z = 4) and Dy(dpm)3 (2) at 200(2) K (space group Pmn21, a = 17.8741(7) {\AA}, b = 10.5639(4) {\AA}, с = 9.8336(4) {\AA}, V = 1856.78(13) {\AA}3, Z = 2) are determined. The structure of complex 1 is similar to the previously known dimeric packings [Ln(dpm)3]2 (Ln = La, Pr, Nd, Eu, Gd, Tb). Complex 2 is isostructural to the previously studied molecular complexes Er(dpm)3 and Lu(dpm)3. At room temperature the luminescence quantum yield (QY) of Tb(dpm)3 is found to reach 77% and that of Dy(dpm)3 is 5%, while for the other Lu(dpm)3 complexes, where Ln = Pr, Nd, Sm, Eu, Gd, Ho, Er, Tm, Yb, QY is below 1%. A series of [Tb(dpm)3]2 and Dy(dpm)3 solid solutions is obtained by evaporating mixtures from solutions. Molecular films of these complexes on Si, Cu, Ni, Ti, KBr substrates are obtained by vacuum deposition.",
keywords = "crystal structure, Ln(III) dipivaloylmethanates, luminescence, molecular films, luminescence., COMPLEXES, BETA-DIKETONATE",
author = "Huang Shen and Berezin, {A. S.} and Antonova, {O. V.} and Zvereva, {V. V.} and Korolkov, {I. V.} and Pervukhina, {N. V.} and Prokhorova, {S. A.} and Stabnikov, {P. A.}",
year = "2018",
month = may,
day = "1",
doi = "10.1134/S0022476618030265",
language = "English",
volume = "59",
pages = "676--683",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

RIS

TY - JOUR

T1 - Crystal Structures of [Dy(dpm)3]2 and Dy(dpm)3, Luminescent and X-Ray Fluorescent Study of Lanthanide(III) Tris-Dipivaloylmethanates

AU - Shen, Huang

AU - Berezin, A. S.

AU - Antonova, O. V.

AU - Zvereva, V. V.

AU - Korolkov, I. V.

AU - Pervukhina, N. V.

AU - Prokhorova, S. A.

AU - Stabnikov, P. A.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - Crystal structures of [Dy(dpm)3]2 (1) at 155(2) K (space group P21/n, a = 12.2191(3) Å, b = 27.6044(6) Å, с = 21.8615(5) Å, β = 105.172(1)°, V = 7116.9(3) Å3, Z = 4) and Dy(dpm)3 (2) at 200(2) K (space group Pmn21, a = 17.8741(7) Å, b = 10.5639(4) Å, с = 9.8336(4) Å, V = 1856.78(13) Å3, Z = 2) are determined. The structure of complex 1 is similar to the previously known dimeric packings [Ln(dpm)3]2 (Ln = La, Pr, Nd, Eu, Gd, Tb). Complex 2 is isostructural to the previously studied molecular complexes Er(dpm)3 and Lu(dpm)3. At room temperature the luminescence quantum yield (QY) of Tb(dpm)3 is found to reach 77% and that of Dy(dpm)3 is 5%, while for the other Lu(dpm)3 complexes, where Ln = Pr, Nd, Sm, Eu, Gd, Ho, Er, Tm, Yb, QY is below 1%. A series of [Tb(dpm)3]2 and Dy(dpm)3 solid solutions is obtained by evaporating mixtures from solutions. Molecular films of these complexes on Si, Cu, Ni, Ti, KBr substrates are obtained by vacuum deposition.

AB - Crystal structures of [Dy(dpm)3]2 (1) at 155(2) K (space group P21/n, a = 12.2191(3) Å, b = 27.6044(6) Å, с = 21.8615(5) Å, β = 105.172(1)°, V = 7116.9(3) Å3, Z = 4) and Dy(dpm)3 (2) at 200(2) K (space group Pmn21, a = 17.8741(7) Å, b = 10.5639(4) Å, с = 9.8336(4) Å, V = 1856.78(13) Å3, Z = 2) are determined. The structure of complex 1 is similar to the previously known dimeric packings [Ln(dpm)3]2 (Ln = La, Pr, Nd, Eu, Gd, Tb). Complex 2 is isostructural to the previously studied molecular complexes Er(dpm)3 and Lu(dpm)3. At room temperature the luminescence quantum yield (QY) of Tb(dpm)3 is found to reach 77% and that of Dy(dpm)3 is 5%, while for the other Lu(dpm)3 complexes, where Ln = Pr, Nd, Sm, Eu, Gd, Ho, Er, Tm, Yb, QY is below 1%. A series of [Tb(dpm)3]2 and Dy(dpm)3 solid solutions is obtained by evaporating mixtures from solutions. Molecular films of these complexes on Si, Cu, Ni, Ti, KBr substrates are obtained by vacuum deposition.

KW - crystal structure

KW - Ln(III) dipivaloylmethanates

KW - luminescence

KW - molecular films

KW - luminescence.

KW - COMPLEXES

KW - BETA-DIKETONATE

UR - http://www.scopus.com/inward/record.url?scp=85049613552&partnerID=8YFLogxK

U2 - 10.1134/S0022476618030265

DO - 10.1134/S0022476618030265

M3 - Article

AN - SCOPUS:85049613552

VL - 59

SP - 676

EP - 683

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -

ID: 14446740