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Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3). / Adonin, S. A.; Sokolov, M. N.; Fedin, V. P.

In: Journal of Structural Chemistry, Vol. 60, No. 10, 01.10.2019, p. 1655-1659.

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Adonin SA, Sokolov MN, Fedin VP. Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3). Journal of Structural Chemistry. 2019 Oct 1;60(10):1655-1659. doi: 10.1134/S0022476619100111

Author

Adonin, S. A. ; Sokolov, M. N. ; Fedin, V. P. / Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3). In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 10. pp. 1655-1659.

BibTeX

@article{dea2c49bfcf64a49b287bd2875c6193a,
title = "Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)",
abstract = "By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.",
keywords = "bismuth, halide complexes, polyhalides, polynuclear complexes",
author = "Adonin, {S. A.} and Sokolov, {M. N.} and Fedin, {V. P.}",
note = "Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2019",
month = oct,
day = "1",
doi = "10.1134/S0022476619100111",
language = "English",
volume = "60",
pages = "1655--1659",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "10",

}

RIS

TY - JOUR

T1 - Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)

AU - Adonin, S. A.

AU - Sokolov, M. N.

AU - Fedin, V. P.

N1 - Publisher Copyright: © 2019, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2019/10/1

Y1 - 2019/10/1

N2 - By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.

AB - By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.

KW - bismuth

KW - halide complexes

KW - polyhalides

KW - polynuclear complexes

UR - http://www.scopus.com/inward/record.url?scp=85074612164&partnerID=8YFLogxK

U2 - 10.1134/S0022476619100111

DO - 10.1134/S0022476619100111

M3 - Article

AN - SCOPUS:85074612164

VL - 60

SP - 1655

EP - 1659

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 10

ER -

ID: 22316146