Research output: Contribution to journal › Article › peer-review
Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3). / Adonin, S. A.; Sokolov, M. N.; Fedin, V. P.
In: Journal of Structural Chemistry, Vol. 60, No. 10, 01.10.2019, p. 1655-1659.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)
AU - Adonin, S. A.
AU - Sokolov, M. N.
AU - Fedin, V. P.
N1 - Publisher Copyright: © 2019, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2019/10/1
Y1 - 2019/10/1
N2 - By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.
AB - By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.
KW - bismuth
KW - halide complexes
KW - polyhalides
KW - polynuclear complexes
UR - http://www.scopus.com/inward/record.url?scp=85074612164&partnerID=8YFLogxK
U2 - 10.1134/S0022476619100111
DO - 10.1134/S0022476619100111
M3 - Article
AN - SCOPUS:85074612164
VL - 60
SP - 1655
EP - 1659
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 10
ER -
ID: 22316146