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Crystal structures of antimony(III) chloride complexes with pyridine. / Davydova, Elena I.; Virovets, Alexander; Peresypkina, Eugenia et al.

In: Polyhedron, Vol. 158, 15.01.2019, p. 97-101.

Research output: Contribution to journal › Article › peer-review

Harvard

Davydova, EI, Virovets, A, Peresypkina, E, Pomogaeva, AV & Timoshkin, AY 2019, 'Crystal structures of antimony(III) chloride complexes with pyridine', Polyhedron, vol. 158, pp. 97-101. https://doi.org/10.1016/j.poly.2018.10.056

APA

Davydova, E. I., Virovets, A., Peresypkina, E., Pomogaeva, A. V., & Timoshkin, A. Y. (2019). Crystal structures of antimony(III) chloride complexes with pyridine. Polyhedron, 158, 97-101. https://doi.org/10.1016/j.poly.2018.10.056

Vancouver

Davydova EI, Virovets A, Peresypkina E, Pomogaeva AV, Timoshkin AY. Crystal structures of antimony(III) chloride complexes with pyridine. Polyhedron. 2019 Jan 15;158:97-101. doi: 10.1016/j.poly.2018.10.056

Author

Davydova, Elena I. ; Virovets, Alexander ; Peresypkina, Eugenia et al. / Crystal structures of antimony(III) chloride complexes with pyridine. In: Polyhedron. 2019 ; Vol. 158. pp. 97-101.

BibTeX

@article{61ea1a8105bb4f5c94ef38933cc1c7c3,
title = "Crystal structures of antimony(III) chloride complexes with pyridine",
abstract = "Molecular structures of two new SbCl3–Py complexes, (SbCl3)4Py4 and (SbCl3)3Py5, in the solid state have been determined by single crystal X-ray diffraction. In both complexes all Sb atoms adopt a pseudo-octahedral coordination geometry which is completed by additional Sb⋯Cl contacts shorter than sum of van der Waals radii, with Cl–Sb⋯Cl angles close to 180°. These contacts indicate the presence of Sb⋯Cl pnictogen bonding. To reveal its nature, the DFT calculations were performed followed by the analyses of the electrostatic potentials, the orbital interactions and topological analysis.",
keywords = "Antimony trichloride, Complexes, Crystal structure, Pnictogen bonds, Pyridine, HALIDES, COORDINATION CHEMISTRY, STIBINE, STABILITY, STATE, THERMAL-DECOMPOSITION, TRANSITION, ELEMENTS, BROMIDE, VALENCE",
author = "Davydova, {Elena I.} and Alexander Virovets and Eugenia Peresypkina and Pomogaeva, {Anna V.} and Timoshkin, {Alexey Y.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd",
year = "2019",
month = jan,
day = "15",
doi = "10.1016/j.poly.2018.10.056",
language = "English",
volume = "158",
pages = "97--101",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Crystal structures of antimony(III) chloride complexes with pyridine

AU - Davydova, Elena I.

AU - Virovets, Alexander

AU - Peresypkina, Eugenia

AU - Pomogaeva, Anna V.

AU - Timoshkin, Alexey Y.

N1 - Publisher Copyright: © 2018 Elsevier Ltd

PY - 2019/1/15

Y1 - 2019/1/15

N2 - Molecular structures of two new SbCl3–Py complexes, (SbCl3)4Py4 and (SbCl3)3Py5, in the solid state have been determined by single crystal X-ray diffraction. In both complexes all Sb atoms adopt a pseudo-octahedral coordination geometry which is completed by additional Sb⋯Cl contacts shorter than sum of van der Waals radii, with Cl–Sb⋯Cl angles close to 180°. These contacts indicate the presence of Sb⋯Cl pnictogen bonding. To reveal its nature, the DFT calculations were performed followed by the analyses of the electrostatic potentials, the orbital interactions and topological analysis.

AB - Molecular structures of two new SbCl3–Py complexes, (SbCl3)4Py4 and (SbCl3)3Py5, in the solid state have been determined by single crystal X-ray diffraction. In both complexes all Sb atoms adopt a pseudo-octahedral coordination geometry which is completed by additional Sb⋯Cl contacts shorter than sum of van der Waals radii, with Cl–Sb⋯Cl angles close to 180°. These contacts indicate the presence of Sb⋯Cl pnictogen bonding. To reveal its nature, the DFT calculations were performed followed by the analyses of the electrostatic potentials, the orbital interactions and topological analysis.

KW - Antimony trichloride

KW - Complexes

KW - Crystal structure

KW - Pnictogen bonds

KW - Pyridine

KW - HALIDES

KW - COORDINATION CHEMISTRY

KW - STIBINE

KW - STABILITY

KW - STATE

KW - THERMAL-DECOMPOSITION

KW - TRANSITION

KW - ELEMENTS

KW - BROMIDE

KW - VALENCE

UR - http://www.scopus.com/inward/record.url?scp=85056488250&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2018.10.056

DO - 10.1016/j.poly.2018.10.056

M3 - Article

AN - SCOPUS:85056488250

VL - 158

SP - 97

EP - 101

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 17473304