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Crystal structure, solid-state 13C and 15N NMR characterisation, chemisorption activity and thermal behaviour of new mercury(II) dipropyldithiocarbamate : Binuclear, pseudo-binuclear and heteronuclear complexes of [Hg2(PrDtc)4], [Hg(PrDtc)2]2 and [Au(PrDtc)2]2[Hg2Cl6]. / Rodina, Tatyana A.; Loseva, Olga V.; Smolentsev, Anton I. et al.

In: Inorganica Chimica Acta, Vol. 508, 119630, 01.08.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Rodina, TA, Loseva, OV, Smolentsev, AI, Antzutkin, ON & Ivanov, AV 2020, 'Crystal structure, solid-state 13C and 15N NMR characterisation, chemisorption activity and thermal behaviour of new mercury(II) dipropyldithiocarbamate: Binuclear, pseudo-binuclear and heteronuclear complexes of [Hg2(PrDtc)4], [Hg(PrDtc)2]2 and [Au(PrDtc)2]2[Hg2Cl6]', Inorganica Chimica Acta, vol. 508, 119630. https://doi.org/10.1016/j.ica.2020.119630

APA

Rodina, T. A., Loseva, O. V., Smolentsev, A. I., Antzutkin, O. N., & Ivanov, A. V. (2020). Crystal structure, solid-state 13C and 15N NMR characterisation, chemisorption activity and thermal behaviour of new mercury(II) dipropyldithiocarbamate: Binuclear, pseudo-binuclear and heteronuclear complexes of [Hg2(PrDtc)4], [Hg(PrDtc)2]2 and [Au(PrDtc)2]2[Hg2Cl6]. Inorganica Chimica Acta, 508, [119630]. https://doi.org/10.1016/j.ica.2020.119630

Vancouver

Rodina TA, Loseva OV, Smolentsev AI, Antzutkin ON, Ivanov AV. Crystal structure, solid-state 13C and 15N NMR characterisation, chemisorption activity and thermal behaviour of new mercury(II) dipropyldithiocarbamate: Binuclear, pseudo-binuclear and heteronuclear complexes of [Hg2(PrDtc)4], [Hg(PrDtc)2]2 and [Au(PrDtc)2]2[Hg2Cl6]. Inorganica Chimica Acta. 2020 Aug 1;508:119630. doi: 10.1016/j.ica.2020.119630

Author

Rodina, Tatyana A. ; Loseva, Olga V. ; Smolentsev, Anton I. et al. / Crystal structure, solid-state 13C and 15N NMR characterisation, chemisorption activity and thermal behaviour of new mercury(II) dipropyldithiocarbamate : Binuclear, pseudo-binuclear and heteronuclear complexes of [Hg2(PrDtc)4], [Hg(PrDtc)2]2 and [Au(PrDtc)2]2[Hg2Cl6]. In: Inorganica Chimica Acta. 2020 ; Vol. 508.

BibTeX

@article{c456bcab4c614553bf8caf48c1c7cea5,
title = "Crystal structure, solid-state 13C and 15N NMR characterisation, chemisorption activity and thermal behaviour of new mercury(II) dipropyldithiocarbamate: Binuclear, pseudo-binuclear and heteronuclear complexes of [Hg2(PrDtc)4], [Hg(PrDtc)2]2 and [Au(PrDtc)2]2[Hg2Cl6]",
abstract = "Two polymorphs of a new mercury(II) N,N-dipropyldithiocarbamate represented by centrosymmetric binuclear and pseudo-binuclear molecules, [Hg2(PrDtc)4] (1) and [Hg(PrDtc)2]2 (2), have been isolated, identified using heteronuclear (13C, 15N) CP-MAS NMR and structurally characterised by single-crystal X-ray diffraction analysis. There are two pairs of inequivalent PrDtc ligands playing either terminal chelating or tridentate bridging structural functions in the former compound; while the latter complex comprises two pairs of structurally inequivalent chelating PrDtc ligands. The reaction of freshly precipitated mercury(II) N,N-dipropyldithiocarbamate (HgPrDtc) with a [AuCl4]−/2 M HCl solution results in the formation of the ionic complex [Au(PrDtc)2]2[Hg2Cl6] (3). There are two inequivalent centrosymmetric cations, [Au(PrDtc)2]+ ({\textquoteleft}A{\textquoteright} and {\textquoteleft}B{\textquoteright}), and a binuclear centrosymmetric anion, [Hg2Cl6]2− in the structure of 3. In the cationic part of the complex, each of the gold(III) cations has two pairs of the relatively weak inequivalent secondary Au···S bonds with two neighbours, therefore forming linear supramolecular cationic chains (⋯{\textquoteleft}A{\textquoteright}⋯{\textquoteleft}B{\textquoteright}⋯{\textquoteleft}A{\textquoteright}⋯{\textquoteleft}B{\textquoteright}⋯)n. To study the thermal behaviour of the compounds, simultaneous thermal analysis was also performed. The formation of HgS and reduced elemental gold was established during the thermolysis of 1/2 and 3, respectively.",
keywords = "Chemisorption activity, Heteronuclear (C, N) CP-MAS NMR spectroscopy, Ionic double gold(III)-mercury(II) compound, Mercury(II) dipropyldithiocarbamate's binuclear and pseudo-binuclear polymorphs, Secondary (Hg⋯S, Au⋯S) interactions, Thermal behavior, CENTER-DOT-S, MOLECULAR-STRUCTURE, CHEMICAL-SHIFTS, X-RAY-DIFFRACTION, HG(II) COMPLEXES, SELF-ORGANIZATION, Secondary (Hg center dot center dot center dot S, Au center dot center dot center dot S) interactions, SUPRAMOLECULAR STRUCTURE, Heteronuclear (C-13, N-15) CP-MAS NMR spectroscopy, CP/MAS C-13, CYCLIC DITHIOCARBAMATE LIGANDS, MAS NMR",
author = "Rodina, {Tatyana A.} and Loseva, {Olga V.} and Smolentsev, {Anton I.} and Antzutkin, {Oleg N.} and Ivanov, {Alexander V.}",
note = "Publisher Copyright: {\textcopyright} 2020",
year = "2020",
month = aug,
day = "1",
doi = "10.1016/j.ica.2020.119630",
language = "English",
volume = "508",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Crystal structure, solid-state 13C and 15N NMR characterisation, chemisorption activity and thermal behaviour of new mercury(II) dipropyldithiocarbamate

T2 - Binuclear, pseudo-binuclear and heteronuclear complexes of [Hg2(PrDtc)4], [Hg(PrDtc)2]2 and [Au(PrDtc)2]2[Hg2Cl6]

AU - Rodina, Tatyana A.

AU - Loseva, Olga V.

AU - Smolentsev, Anton I.

AU - Antzutkin, Oleg N.

AU - Ivanov, Alexander V.

N1 - Publisher Copyright: © 2020

PY - 2020/8/1

Y1 - 2020/8/1

N2 - Two polymorphs of a new mercury(II) N,N-dipropyldithiocarbamate represented by centrosymmetric binuclear and pseudo-binuclear molecules, [Hg2(PrDtc)4] (1) and [Hg(PrDtc)2]2 (2), have been isolated, identified using heteronuclear (13C, 15N) CP-MAS NMR and structurally characterised by single-crystal X-ray diffraction analysis. There are two pairs of inequivalent PrDtc ligands playing either terminal chelating or tridentate bridging structural functions in the former compound; while the latter complex comprises two pairs of structurally inequivalent chelating PrDtc ligands. The reaction of freshly precipitated mercury(II) N,N-dipropyldithiocarbamate (HgPrDtc) with a [AuCl4]−/2 M HCl solution results in the formation of the ionic complex [Au(PrDtc)2]2[Hg2Cl6] (3). There are two inequivalent centrosymmetric cations, [Au(PrDtc)2]+ (‘A’ and ‘B’), and a binuclear centrosymmetric anion, [Hg2Cl6]2− in the structure of 3. In the cationic part of the complex, each of the gold(III) cations has two pairs of the relatively weak inequivalent secondary Au···S bonds with two neighbours, therefore forming linear supramolecular cationic chains (⋯‘A’⋯‘B’⋯‘A’⋯‘B’⋯)n. To study the thermal behaviour of the compounds, simultaneous thermal analysis was also performed. The formation of HgS and reduced elemental gold was established during the thermolysis of 1/2 and 3, respectively.

AB - Two polymorphs of a new mercury(II) N,N-dipropyldithiocarbamate represented by centrosymmetric binuclear and pseudo-binuclear molecules, [Hg2(PrDtc)4] (1) and [Hg(PrDtc)2]2 (2), have been isolated, identified using heteronuclear (13C, 15N) CP-MAS NMR and structurally characterised by single-crystal X-ray diffraction analysis. There are two pairs of inequivalent PrDtc ligands playing either terminal chelating or tridentate bridging structural functions in the former compound; while the latter complex comprises two pairs of structurally inequivalent chelating PrDtc ligands. The reaction of freshly precipitated mercury(II) N,N-dipropyldithiocarbamate (HgPrDtc) with a [AuCl4]−/2 M HCl solution results in the formation of the ionic complex [Au(PrDtc)2]2[Hg2Cl6] (3). There are two inequivalent centrosymmetric cations, [Au(PrDtc)2]+ (‘A’ and ‘B’), and a binuclear centrosymmetric anion, [Hg2Cl6]2− in the structure of 3. In the cationic part of the complex, each of the gold(III) cations has two pairs of the relatively weak inequivalent secondary Au···S bonds with two neighbours, therefore forming linear supramolecular cationic chains (⋯‘A’⋯‘B’⋯‘A’⋯‘B’⋯)n. To study the thermal behaviour of the compounds, simultaneous thermal analysis was also performed. The formation of HgS and reduced elemental gold was established during the thermolysis of 1/2 and 3, respectively.

KW - Chemisorption activity

KW - Heteronuclear (C, N) CP-MAS NMR spectroscopy

KW - Ionic double gold(III)-mercury(II) compound

KW - Mercury(II) dipropyldithiocarbamate's binuclear and pseudo-binuclear polymorphs

KW - Secondary (Hg⋯S, Au⋯S) interactions

KW - Thermal behavior

KW - CENTER-DOT-S

KW - MOLECULAR-STRUCTURE

KW - CHEMICAL-SHIFTS

KW - X-RAY-DIFFRACTION

KW - HG(II) COMPLEXES

KW - SELF-ORGANIZATION

KW - Secondary (Hg center dot center dot center dot S, Au center dot center dot center dot S) interactions

KW - SUPRAMOLECULAR STRUCTURE

KW - Heteronuclear (C-13, N-15) CP-MAS NMR spectroscopy

KW - CP/MAS C-13

KW - CYCLIC DITHIOCARBAMATE LIGANDS

KW - MAS NMR

UR - http://www.scopus.com/inward/record.url?scp=85082728300&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2020.119630

DO - 10.1016/j.ica.2020.119630

M3 - Article

AN - SCOPUS:85082728300

VL - 508

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 119630

ER -

ID: 23950102