Research output: Contribution to journal › Article › peer-review
Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]. / Cheplakova, A. M.; Fedoseev, I. S.; Dorovatovskii, P. V. et al.
In: Journal of Structural Chemistry, Vol. 59, No. 2, 01.03.2018, p. 494-496.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]
AU - Cheplakova, A. M.
AU - Fedoseev, I. S.
AU - Dorovatovskii, P. V.
AU - Lazarenko, V. A.
AU - Zubavichus, Ya V.
AU - Khrustalev, V. N.
AU - Fedin, V. P.
PY - 2018/3/1
Y1 - 2018/3/1
N2 - The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by interactions between the phenyl rings.
AB - The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by interactions between the phenyl rings.
KW - coordination polymer
KW - crystal structure
KW - scandium complexes
KW - tetrafluorobenzoic acid
KW - tetrafluoroterephthalic acid
KW - METAL-ORGANIC FRAMEWORKS
KW - BRIDGING LIGAND
KW - TETRAFLUOROTEREPHTHALIC ACID
KW - MOFS
KW - COORDINATION POLYMERS
UR - http://www.scopus.com/inward/record.url?scp=85048144014&partnerID=8YFLogxK
U2 - 10.1134/S0022476618020348
DO - 10.1134/S0022476618020348
M3 - Article
AN - SCOPUS:85048144014
VL - 59
SP - 494
EP - 496
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 2
ER -
ID: 13792649