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Crystal Structure of the Heteroligand Complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy) : Formation of Supramolecular Associates due to the Halogen Bond. / Adonin, S. A.; Novikov, A. S.; Fedin, V. P.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 46, No. 1, 01.2020, p. 37-41.

Research output: Contribution to journal › Article › peer-review

Harvard

Adonin, SA, Novikov, AS & Fedin, VP 2020, 'Crystal Structure of the Heteroligand Complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy): Formation of Supramolecular Associates due to the Halogen Bond', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 46, no. 1, pp. 37-41. https://doi.org/10.1134/S1070328420010017

APA

Adonin, S. A., Novikov, A. S., & Fedin, V. P. (2020). Crystal Structure of the Heteroligand Complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy): Formation of Supramolecular Associates due to the Halogen Bond. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 46(1), 37-41. https://doi.org/10.1134/S1070328420010017

Vancouver

Adonin SA, Novikov AS, Fedin VP. Crystal Structure of the Heteroligand Complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy): Formation of Supramolecular Associates due to the Halogen Bond. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020 Jan;46(1):37-41. doi: 10.1134/S1070328420010017

Author

Adonin, S. A. ; Novikov, A. S. ; Fedin, V. P. / Crystal Structure of the Heteroligand Complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy) : Formation of Supramolecular Associates due to the Halogen Bond. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020 ; Vol. 46, No. 1. pp. 37-41.

BibTeX

@article{ac318ed6e1964da692c7bd819c2fcb80,
title = "Crystal Structure of the Heteroligand Complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy): Formation of Supramolecular Associates due to the Halogen Bond",
abstract = "The reaction of CoCl2 with 2-bromo-5-methylpyridine (2-Br-5-MePy) in ethanol affords the het-eroligand complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy) (I), the structure of which is determined by X-ray diffraction analysis (СIF file ССDС no. 1921405). Specific noncovalent interactions Cl···Br (halogen bond) are observed in the crystal structure and lead to the formation of unidimensional supramolecular polymers. The energies of these contacts are determined using quantum-chemical methods.",
keywords = "cobalt, crystal structure, halogen bond, N-donor ligands, quantum-chemical calculations, HALIDES, FE CONTACTS, HYDROGEN-BOND, DONOR, COORDINATION, NONCOVALENT INTERACTIONS, BR, METALS, COMPETITION, M-X",
author = "Adonin, {S. A.} and Novikov, {A. S.} and Fedin, {V. P.}",
year = "2020",
month = jan,
doi = "10.1134/S1070328420010017",
language = "English",
volume = "46",
pages = "37--41",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "1",

}

RIS

TY - JOUR

T1 - Crystal Structure of the Heteroligand Complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy)

T2 - Formation of Supramolecular Associates due to the Halogen Bond

AU - Adonin, S. A.

AU - Novikov, A. S.

AU - Fedin, V. P.

PY - 2020/1

Y1 - 2020/1

N2 - The reaction of CoCl2 with 2-bromo-5-methylpyridine (2-Br-5-MePy) in ethanol affords the het-eroligand complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy) (I), the structure of which is determined by X-ray diffraction analysis (СIF file ССDС no. 1921405). Specific noncovalent interactions Cl···Br (halogen bond) are observed in the crystal structure and lead to the formation of unidimensional supramolecular polymers. The energies of these contacts are determined using quantum-chemical methods.

AB - The reaction of CoCl2 with 2-bromo-5-methylpyridine (2-Br-5-MePy) in ethanol affords the het-eroligand complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy) (I), the structure of which is determined by X-ray diffraction analysis (СIF file ССDС no. 1921405). Specific noncovalent interactions Cl···Br (halogen bond) are observed in the crystal structure and lead to the formation of unidimensional supramolecular polymers. The energies of these contacts are determined using quantum-chemical methods.

KW - cobalt

KW - crystal structure

KW - halogen bond

KW - N-donor ligands

KW - quantum-chemical calculations

KW - HALIDES

KW - FE CONTACTS

KW - HYDROGEN-BOND

KW - DONOR

KW - COORDINATION

KW - NONCOVALENT INTERACTIONS

KW - BR

KW - METALS

KW - COMPETITION

KW - M-X

UR - http://www.scopus.com/inward/record.url?scp=85081955650&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/b02ed9a2-6503-3d40-b239-0eefc384eec9/

U2 - 10.1134/S1070328420010017

DO - 10.1134/S1070328420010017

M3 - Article

AN - SCOPUS:85081955650

VL - 46

SP - 37

EP - 41

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 1

ER -

ID: 23875588