Research output: Contribution to journal › Article › peer-review
Crystal structure of Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O. / Abramov, P. A.; Sokolov, M. N.
In: Journal of Structural Chemistry, Vol. 58, No. 7, 01.12.2017, p. 1411-1417.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Crystal structure of Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O
AU - Abramov, P. A.
AU - Sokolov, M. N.
N1 - Publisher Copyright: © 2017, Pleiades Publishing, Ltd.
PY - 2017/12/1
Y1 - 2017/12/1
N2 - The diffusion of acetone vapor into a Na7H[Nb6O19] solution at pH 9.5 results in the crystallization of the Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O (1) complex characterized by X-ray diffraction. The sodium cation coordination to a triangular face of the anion enables the determination of anion protonation sites by blocking the disordering and the formation of strong hydrogen bonds between the anions.
AB - The diffusion of acetone vapor into a Na7H[Nb6O19] solution at pH 9.5 results in the crystallization of the Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O (1) complex characterized by X-ray diffraction. The sodium cation coordination to a triangular face of the anion enables the determination of anion protonation sites by blocking the disordering and the formation of strong hydrogen bonds between the anions.
KW - hexaniobate
KW - sodium
KW - X-ray diffraction analysis
KW - OXYGEN
KW - OXIDE
KW - BEHAVIOR
KW - POLYOXOMETALATE
KW - LINDQVIST ION
KW - SOLID-STATE
KW - WATER
UR - http://www.scopus.com/inward/record.url?scp=85039857822&partnerID=8YFLogxK
U2 - 10.1134/S0022476617070198
DO - 10.1134/S0022476617070198
M3 - Article
AN - SCOPUS:85039857822
VL - 58
SP - 1411
EP - 1417
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 7
ER -
ID: 9409434