Crystal structure of metal-organic frameworks based on terbium and 1,4-naphthalenedicarboxylic acid

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Crystal structure of metal-organic frameworks based on terbium and 1,4-naphthalenedicarboxylic acid. / Barsukova, M. O.; Samsonenko, D. G.; Fedin, V. P.

In: Journal of Structural Chemistry, Vol. 61, No. 7, 01.07.2020, p. 1090-1096.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{abb74e92e3e8418f890f417b812949de,

title = "Crystal structure of metal-organic frameworks based on terbium and 1,4-naphthalenedicarboxylic acid",

abstract = "The interaction of terbium nitrate pentahydrate and 1,4-naphthalenedicarboxylic acid (H2ndc) in a solvent mixture under solvothermal conditions yields two new metal-organic frameworks: ((CH3)2NH2)2[Tb3(H2O)(HCOO)(ndc)5]∙3DMF (1) and [Tb4(DMF)(NMP)6(ndc)6] (2) (ndc2– is 1,4-naphthalenedicarboxylate, DMF is N,N-dimethylformamide, NMP is N-methyl-2-pyrrolidone). The crystal structures of compounds 1 and 2 are established by the single crystal X-ray diffraction analysis. Compound 1 is a negatively charged 3D framework in which dimethyl ammonium cations act as counterions. The remaining volume available for solvent molecules is filled with DMF. Compound 2 has a dense layered structure. The luminescence spectrum contains one emission band corresponding to π*– π transitions in the ligand.",

keywords = "1,4-naphthalenedicarboxylic acid, metal-organic frameworks, terbium, X-ray diffraction analysis, 1, 4-naphthalenedicarboxylic acid, LUMINESCENCE",

author = "Barsukova, {M. O.} and Samsonenko, {D. G.} and Fedin, {V. P.}",

year = "2020",

month = jul,

day = "1",

doi = "10.1134/S0022476620070112",

language = "English",

volume = "61",

pages = "1090--1096",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "7",

}

RIS

TY - JOUR

T1 - Crystal structure of metal-organic frameworks based on terbium and 1,4-naphthalenedicarboxylic acid

AU - Barsukova, M. O.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

PY - 2020/7/1

Y1 - 2020/7/1

N2 - The interaction of terbium nitrate pentahydrate and 1,4-naphthalenedicarboxylic acid (H2ndc) in a solvent mixture under solvothermal conditions yields two new metal-organic frameworks: ((CH3)2NH2)2[Tb3(H2O)(HCOO)(ndc)5]∙3DMF (1) and [Tb4(DMF)(NMP)6(ndc)6] (2) (ndc2– is 1,4-naphthalenedicarboxylate, DMF is N,N-dimethylformamide, NMP is N-methyl-2-pyrrolidone). The crystal structures of compounds 1 and 2 are established by the single crystal X-ray diffraction analysis. Compound 1 is a negatively charged 3D framework in which dimethyl ammonium cations act as counterions. The remaining volume available for solvent molecules is filled with DMF. Compound 2 has a dense layered structure. The luminescence spectrum contains one emission band corresponding to π*– π transitions in the ligand.

AB - The interaction of terbium nitrate pentahydrate and 1,4-naphthalenedicarboxylic acid (H2ndc) in a solvent mixture under solvothermal conditions yields two new metal-organic frameworks: ((CH3)2NH2)2[Tb3(H2O)(HCOO)(ndc)5]∙3DMF (1) and [Tb4(DMF)(NMP)6(ndc)6] (2) (ndc2– is 1,4-naphthalenedicarboxylate, DMF is N,N-dimethylformamide, NMP is N-methyl-2-pyrrolidone). The crystal structures of compounds 1 and 2 are established by the single crystal X-ray diffraction analysis. Compound 1 is a negatively charged 3D framework in which dimethyl ammonium cations act as counterions. The remaining volume available for solvent molecules is filled with DMF. Compound 2 has a dense layered structure. The luminescence spectrum contains one emission band corresponding to π*– π transitions in the ligand.

KW - 1,4-naphthalenedicarboxylic acid

KW - metal-organic frameworks

KW - terbium

KW - X-ray diffraction analysis

KW - 1

KW - 4-naphthalenedicarboxylic acid

KW - LUMINESCENCE

UR - http://www.scopus.com/inward/record.url?scp=85090208603&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/cc275c10-d6af-39e0-9a1a-2a0833752a6d/

U2 - 10.1134/S0022476620070112

DO - 10.1134/S0022476620070112

M3 - Article

AN - SCOPUS:85090208603

VL - 61

SP - 1090

EP - 1096

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 7

ER -

ID: 25285218