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Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4 [{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni). / Muravieva, V. K.; Lemoine, P.; Cordier, S. et al.

In: Journal of Structural Chemistry, Vol. 60, No. 1, 01.01.2019, p. 99-105.

Research output: Contribution to journal › Article › peer-review

Harvard

Muravieva, VK, Lemoine, P, Cordier, S & Naumov, NG 2019, 'Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4 [{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni)', Journal of Structural Chemistry, vol. 60, no. 1, pp. 99-105. https://doi.org/10.1134/S002247661901013X

APA

Muravieva, V. K., Lemoine, P., Cordier, S., & Naumov, N. G. (2019). Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4 [{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni). Journal of Structural Chemistry, 60(1), 99-105. https://doi.org/10.1134/S002247661901013X

Vancouver

Muravieva VK, Lemoine P, Cordier S, Naumov NG. Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4 [{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni). Journal of Structural Chemistry. 2019 Jan 1;60(1):99-105. doi: 10.1134/S002247661901013X

Author

Muravieva, V. K. ; Lemoine, P. ; Cordier, S. et al. / Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4 [{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni). In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 1. pp. 99-105.

BibTeX

@article{6e4868d97c9b467f93decea26091943c,
title = "Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4 [{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni)",
abstract = " Two isostructural compounds of the composition [M(NH 3 ) 6 ] 4 [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 } 2 ]·15H 2 O (M = Co, Ni) are obtained by a reaction of a salt of heterometal cluster [Re 3 Mo 3 Se 8 (CN) 6 ] 5− anion with cobalt or nickel salts in an aqueous ammonia solution. The obtained compounds are structurally characterized. They correspond to the class of cyano-bridged coordination polymers. Two cyano groups of the octahedral cluster in the trans position form bridging bonds with Co(II) and Ni(II) cations. The obtained compounds are composed of highly charged polymeric [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 }2] ∞∞ 8− 88 layers formed by cluster anions and metal cations. The negative charge of the layers is compensated by [M(NH 3 ) 6 ] 2+ cationic complexes inside the polymeric layer and in the interstitial space of the structure. ",
keywords = "coordination polymers, crystal structure, heterometal cluster, molybdenum, rhenium, ANIONS, FRAMEWORK MATERIALS, SE, CLUSTERS, COMPLEXES, TOOL",
author = "Muravieva, {V. K.} and P. Lemoine and S. Cordier and Naumov, {N. G.}",
year = "2019",
month = jan,
day = "1",
doi = "10.1134/S002247661901013X",
language = "English",
volume = "60",
pages = "99--105",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "1",

}

RIS

TY - JOUR

T1 - Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4 [{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni)

AU - Muravieva, V. K.

AU - Lemoine, P.

AU - Cordier, S.

AU - Naumov, N. G.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Two isostructural compounds of the composition [M(NH 3 ) 6 ] 4 [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 } 2 ]·15H 2 O (M = Co, Ni) are obtained by a reaction of a salt of heterometal cluster [Re 3 Mo 3 Se 8 (CN) 6 ] 5− anion with cobalt or nickel salts in an aqueous ammonia solution. The obtained compounds are structurally characterized. They correspond to the class of cyano-bridged coordination polymers. Two cyano groups of the octahedral cluster in the trans position form bridging bonds with Co(II) and Ni(II) cations. The obtained compounds are composed of highly charged polymeric [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 }2] ∞∞ 8− 88 layers formed by cluster anions and metal cations. The negative charge of the layers is compensated by [M(NH 3 ) 6 ] 2+ cationic complexes inside the polymeric layer and in the interstitial space of the structure.

AB - Two isostructural compounds of the composition [M(NH 3 ) 6 ] 4 [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 } 2 ]·15H 2 O (M = Co, Ni) are obtained by a reaction of a salt of heterometal cluster [Re 3 Mo 3 Se 8 (CN) 6 ] 5− anion with cobalt or nickel salts in an aqueous ammonia solution. The obtained compounds are structurally characterized. They correspond to the class of cyano-bridged coordination polymers. Two cyano groups of the octahedral cluster in the trans position form bridging bonds with Co(II) and Ni(II) cations. The obtained compounds are composed of highly charged polymeric [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 }2] ∞∞ 8− 88 layers formed by cluster anions and metal cations. The negative charge of the layers is compensated by [M(NH 3 ) 6 ] 2+ cationic complexes inside the polymeric layer and in the interstitial space of the structure.

KW - coordination polymers

KW - crystal structure

KW - heterometal cluster

KW - molybdenum

KW - rhenium

KW - ANIONS

KW - FRAMEWORK MATERIALS

KW - SE

KW - CLUSTERS

KW - COMPLEXES

KW - TOOL

UR - http://www.scopus.com/inward/record.url?scp=85064833461&partnerID=8YFLogxK

U2 - 10.1134/S002247661901013X

DO - 10.1134/S002247661901013X

M3 - Article

AN - SCOPUS:85064833461

VL - 60

SP - 99

EP - 105

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -

ID: 19647969