Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex

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Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex. / Sapianik, A. A.; Semenenko, E. E.; Samsonenko, D. G. et al.

In: Journal of Structural Chemistry, Vol. 59, No. 2, 01.03.2018, p. 487-493.

Research output: Contribution to journal › Article › peer-review

Author

Sapianik, A. A. ; Semenenko, E. E. ; Samsonenko, D. G. et al. / Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 2. pp. 487-493.

BibTeX

@article{b1e3ecce2ed4412a9e87147267ffc990,

title = "Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex",

abstract = "Three new metal-organic frameworks [Zn(Hibdc)2]·DMF (1), (H2NMe2)[Li2Zn3(H2O)(dmf)(Hbtc)3(btc)]·6DMF·H2O (2), and [Li2Zn2(H2O)2(bpp)(bpdc)3]·7DMF (3) are obtained in the interaction of heterometallic carboxylate complex [Li2Zn2(piv)6(py)2] with isophthalic (H2ibdc) and trimesic (H3btc) acids and in the presence of both 4,4′-biphenyldicarboxylic acid (H2bpdc) and 4,4′-bispyridylpropane (bpp). The structure of the obtained compounds is determined by the single crystal X-ray diffraction analysis. In the reactions studied the structure of the initial {Li2Zn2} fragment is not retained. A complicated fragmentation of this four-nuclear block occurs, including the formation of binuclear heterometallic dimers {LiZn}.",

keywords = "carboxylate complexes, coordination polymers, lithium, metal-organic frameworks, polynuclear complexes, single crystal X-ray diffraction analysis, zinc, METAL-ORGANIC FRAMEWORKS",

author = "Sapianik, {A. A.} and Semenenko, {E. E.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",

year = "2018",

month = mar,

day = "1",

doi = "10.1134/S0022476618020336",

language = "English",

volume = "59",

pages = "487--493",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "2",

}

RIS

TY - JOUR

T1 - Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex

AU - Sapianik, A. A.

AU - Semenenko, E. E.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - Three new metal-organic frameworks [Zn(Hibdc)2]·DMF (1), (H2NMe2)[Li2Zn3(H2O)(dmf)(Hbtc)3(btc)]·6DMF·H2O (2), and [Li2Zn2(H2O)2(bpp)(bpdc)3]·7DMF (3) are obtained in the interaction of heterometallic carboxylate complex [Li2Zn2(piv)6(py)2] with isophthalic (H2ibdc) and trimesic (H3btc) acids and in the presence of both 4,4′-biphenyldicarboxylic acid (H2bpdc) and 4,4′-bispyridylpropane (bpp). The structure of the obtained compounds is determined by the single crystal X-ray diffraction analysis. In the reactions studied the structure of the initial {Li2Zn2} fragment is not retained. A complicated fragmentation of this four-nuclear block occurs, including the formation of binuclear heterometallic dimers {LiZn}.

AB - Three new metal-organic frameworks [Zn(Hibdc)2]·DMF (1), (H2NMe2)[Li2Zn3(H2O)(dmf)(Hbtc)3(btc)]·6DMF·H2O (2), and [Li2Zn2(H2O)2(bpp)(bpdc)3]·7DMF (3) are obtained in the interaction of heterometallic carboxylate complex [Li2Zn2(piv)6(py)2] with isophthalic (H2ibdc) and trimesic (H3btc) acids and in the presence of both 4,4′-biphenyldicarboxylic acid (H2bpdc) and 4,4′-bispyridylpropane (bpp). The structure of the obtained compounds is determined by the single crystal X-ray diffraction analysis. In the reactions studied the structure of the initial {Li2Zn2} fragment is not retained. A complicated fragmentation of this four-nuclear block occurs, including the formation of binuclear heterometallic dimers {LiZn}.

KW - carboxylate complexes

KW - coordination polymers

KW - lithium

KW - metal-organic frameworks

KW - polynuclear complexes

KW - single crystal X-ray diffraction analysis

KW - zinc

KW - METAL-ORGANIC FRAMEWORKS

UR - http://www.scopus.com/inward/record.url?scp=85048225332&partnerID=8YFLogxK

U2 - 10.1134/S0022476618020336

DO - 10.1134/S0022476618020336

M3 - Article

AN - SCOPUS:85048225332

VL - 59

SP - 487

EP - 493

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 13845467