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Crystal structure of a Zn complex with terephthalate and 1,6-bis(1,2,4-triazol-1-yl)hexane. / Sukhikh, Taisiya S.; Semitut, Evgeny Yu; Potapov, Andrei S.

In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 74, No. Pt 1, 01.01.2018, p. 6-9.

Research output: Contribution to journal › Article › peer-review

Harvard

Sukhikh, TS, Semitut, EY & Potapov, AS 2018, 'Crystal structure of a Zn complex with terephthalate and 1,6-bis(1,2,4-triazol-1-yl)hexane', Acta Crystallographica Section E: Crystallographic Communications, vol. 74, no. Pt 1, pp. 6-9. https://doi.org/10.1107/S2056989017017224

APA

Sukhikh, T. S., Semitut, E. Y., & Potapov, A. S. (2018). Crystal structure of a Zn complex with terephthalate and 1,6-bis(1,2,4-triazol-1-yl)hexane. Acta Crystallographica Section E: Crystallographic Communications, 74(Pt 1), 6-9. https://doi.org/10.1107/S2056989017017224

Vancouver

Sukhikh TS, Semitut EY, Potapov AS. Crystal structure of a Zn complex with terephthalate and 1,6-bis(1,2,4-triazol-1-yl)hexane. Acta Crystallographica Section E: Crystallographic Communications. 2018 Jan 1;74(Pt 1):6-9. doi: 10.1107/S2056989017017224

Author

Sukhikh, Taisiya S. ; Semitut, Evgeny Yu ; Potapov, Andrei S. / Crystal structure of a Zn complex with terephthalate and 1,6-bis(1,2,4-triazol-1-yl)hexane. In: Acta Crystallographica Section E: Crystallographic Communications. 2018 ; Vol. 74, No. Pt 1. pp. 6-9.

BibTeX

@article{cbaba62cdf274771ad5c12bb9c29c36d,
title = "Crystal structure of a Zn complex with terephthalate and 1,6-bis(1,2,4-triazol-1-yl)hexane",
abstract = "A new zinc coordination polymer with rigid benzene-1,4-dicarboxylate (bdc) and flexible 1,6-bis(1,2,4-triazol-1-yl)hexane (btrh), namely poly[[(μ2-benzene-1,4-dicarboxylato)[μ2-1,6-bis(1,2,4-triazol-1-yl)hexane]zinc] dimethylformamide monosolvate], [Zn(C8H4O4)(C10H16N6)]·C3H7NO, was synthesized. According to the single-crystal XRD analysis, the product crystallizes in the P1 space group and has a layered structure. Analysis of the layered structure reveals {Zn(bdc)} chains which are connected by pairs of btrh ligands. The layers are packed tightly perpendicular to the [122] direction, separated by one non-disordered dimethylformamide solvent molecule per formula unit. According to thermogravimetric analysis, the product completely loses this solvent at 453 K; the desolvated compound is stable up to 503 K. As a result of the lack of hydrogen-donor groups, hydrogen bonds are not observed in the structure of the complex; however, an intermolecular C - H⋯π contact of 3.07 {\AA} occurs.",
keywords = "coordination polymer, crystal structure, flexible ligand, terephthalate, LUMINESCENT PROPERTIES, LIGAND, COORDINATION POLYMERS",
author = "Sukhikh, {Taisiya S.} and Semitut, {Evgeny Yu} and Potapov, {Andrei S.}",
year = "2018",
month = jan,
day = "1",
doi = "10.1107/S2056989017017224",
language = "English",
volume = "74",
pages = "6--9",
journal = "Acta Crystallographica Section E: Crystallographic Communications",
issn = "2056-9890",
publisher = "International Union of Crystallography",
number = "Pt 1",

}

RIS

TY - JOUR

T1 - Crystal structure of a Zn complex with terephthalate and 1,6-bis(1,2,4-triazol-1-yl)hexane

AU - Sukhikh, Taisiya S.

AU - Semitut, Evgeny Yu

AU - Potapov, Andrei S.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - A new zinc coordination polymer with rigid benzene-1,4-dicarboxylate (bdc) and flexible 1,6-bis(1,2,4-triazol-1-yl)hexane (btrh), namely poly[[(μ2-benzene-1,4-dicarboxylato)[μ2-1,6-bis(1,2,4-triazol-1-yl)hexane]zinc] dimethylformamide monosolvate], [Zn(C8H4O4)(C10H16N6)]·C3H7NO, was synthesized. According to the single-crystal XRD analysis, the product crystallizes in the P1 space group and has a layered structure. Analysis of the layered structure reveals {Zn(bdc)} chains which are connected by pairs of btrh ligands. The layers are packed tightly perpendicular to the [122] direction, separated by one non-disordered dimethylformamide solvent molecule per formula unit. According to thermogravimetric analysis, the product completely loses this solvent at 453 K; the desolvated compound is stable up to 503 K. As a result of the lack of hydrogen-donor groups, hydrogen bonds are not observed in the structure of the complex; however, an intermolecular C - H⋯π contact of 3.07 Å occurs.

AB - A new zinc coordination polymer with rigid benzene-1,4-dicarboxylate (bdc) and flexible 1,6-bis(1,2,4-triazol-1-yl)hexane (btrh), namely poly[[(μ2-benzene-1,4-dicarboxylato)[μ2-1,6-bis(1,2,4-triazol-1-yl)hexane]zinc] dimethylformamide monosolvate], [Zn(C8H4O4)(C10H16N6)]·C3H7NO, was synthesized. According to the single-crystal XRD analysis, the product crystallizes in the P1 space group and has a layered structure. Analysis of the layered structure reveals {Zn(bdc)} chains which are connected by pairs of btrh ligands. The layers are packed tightly perpendicular to the [122] direction, separated by one non-disordered dimethylformamide solvent molecule per formula unit. According to thermogravimetric analysis, the product completely loses this solvent at 453 K; the desolvated compound is stable up to 503 K. As a result of the lack of hydrogen-donor groups, hydrogen bonds are not observed in the structure of the complex; however, an intermolecular C - H⋯π contact of 3.07 Å occurs.

KW - coordination polymer

KW - crystal structure

KW - flexible ligand

KW - terephthalate

KW - LUMINESCENT PROPERTIES

KW - LIGAND

KW - COORDINATION POLYMERS

UR - http://www.scopus.com/inward/record.url?scp=85040187026&partnerID=8YFLogxK

U2 - 10.1107/S2056989017017224

DO - 10.1107/S2056989017017224

M3 - Article

C2 - 29416881

AN - SCOPUS:85040187026

VL - 74

SP - 6

EP - 9

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

SN - 2056-9890

IS - Pt 1

ER -

ID: 12100948