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Crystal structure of a new magnesium paratungstate salt (CH3NH3)4[(Mg(H2O)5)2H6W12O42]Br2·8H2O. / Anyushin, A. V.; Smolentsev, A. I.; Sokolov, M. N.

In: Journal of Structural Chemistry, Vol. 58, No. 3, 01.05.2017, p. 597-599.

Research output: Contribution to journal › Article › peer-review

Harvard

Anyushin, AV, Smolentsev, AI & Sokolov, MN 2017, 'Crystal structure of a new magnesium paratungstate salt (CH3NH3)4[(Mg(H2O)5)2H6W12O42]Br2·8H2O', Journal of Structural Chemistry, vol. 58, no. 3, pp. 597-599. https://doi.org/10.1134/S0022476617030222

APA

Anyushin, A. V., Smolentsev, A. I., & Sokolov, M. N. (2017). Crystal structure of a new magnesium paratungstate salt (CH3NH3)4[(Mg(H2O)5)2H6W12O42]Br2·8H2O. Journal of Structural Chemistry, 58(3), 597-599. https://doi.org/10.1134/S0022476617030222

Vancouver

Anyushin AV, Smolentsev AI, Sokolov MN. Crystal structure of a new magnesium paratungstate salt (CH3NH3)4[(Mg(H2O)5)2H6W12O42]Br2·8H2O. Journal of Structural Chemistry. 2017 May 1;58(3):597-599. doi: 10.1134/S0022476617030222

Author

Anyushin, A. V. ; Smolentsev, A. I. ; Sokolov, M. N. / Crystal structure of a new magnesium paratungstate salt (CH3NH3)4[(Mg(H2O)5)2H6W12O42]Br2·8H2O. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 3. pp. 597-599.

BibTeX

@article{ce81e2fce8d7467b9300720ebfe15458,
title = "Crystal structure of a new magnesium paratungstate salt (CH3NH3)4[(Mg(H2O)5)2H6W12O42]Br2·8H2O",
abstract = "The X-ray crystal structure of (CH3NH3)4[(Mg(H2O)5)2(H6W12O42)]Br2·8H2O (1) obtained by a reaction of Li2WO4·H2O and Mg(NO3)2·6H2O in the presence of MeNH3Br is reported. Crystallographic parameters are: triclinic, space group P-1, a = 10.8280(4) {\AA}, b = 12.4866(5) {\AA}, c = 12.6201(5) {\AA}, α = 108.501(1)°, β = 111.542(1)°, γ = 91.139(1)°, V = 1486.98(10) {\AA}3, Z = 1, C4H66Br2Mg2N4O60W12, dx = 3.959 g/cm3, T = 150 K, R1 = 0.030 for 9914 Fo > 4δ(F) until 2θmax = 66.6° The structure contains tetraprotonated [H2W12O42]10– anions coordinated with {Mg(H2O)5}2+ cations as ditopic ligands via terminal oxygen atoms. The crystal structure also incorporates outer-sphere CH3NH3 + and Br– ions. The Mg2+ cations are in the octahedral environment, Mg–O(H2O) and Mg–O(W) bond lengths being 2.102(5)÷2.044(5) {\AA} and 2.071(5) {\AA}, respectively.",
keywords = "crystal structure, magnesium, paratungstate B, polyoxometalates, CLUSTERS, COMPLEXES, IONS, PARADODECATUNGSTATE",
author = "Anyushin, {A. V.} and Smolentsev, {A. I.} and Sokolov, {M. N.}",
year = "2017",
month = may,
day = "1",
doi = "10.1134/S0022476617030222",
language = "English",
volume = "58",
pages = "597--599",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

RIS

TY - JOUR

T1 - Crystal structure of a new magnesium paratungstate salt (CH3NH3)4[(Mg(H2O)5)2H6W12O42]Br2·8H2O

AU - Anyushin, A. V.

AU - Smolentsev, A. I.

AU - Sokolov, M. N.

PY - 2017/5/1

Y1 - 2017/5/1

N2 - The X-ray crystal structure of (CH3NH3)4[(Mg(H2O)5)2(H6W12O42)]Br2·8H2O (1) obtained by a reaction of Li2WO4·H2O and Mg(NO3)2·6H2O in the presence of MeNH3Br is reported. Crystallographic parameters are: triclinic, space group P-1, a = 10.8280(4) Å, b = 12.4866(5) Å, c = 12.6201(5) Å, α = 108.501(1)°, β = 111.542(1)°, γ = 91.139(1)°, V = 1486.98(10) Å3, Z = 1, C4H66Br2Mg2N4O60W12, dx = 3.959 g/cm3, T = 150 K, R1 = 0.030 for 9914 Fo > 4δ(F) until 2θmax = 66.6° The structure contains tetraprotonated [H2W12O42]10– anions coordinated with {Mg(H2O)5}2+ cations as ditopic ligands via terminal oxygen atoms. The crystal structure also incorporates outer-sphere CH3NH3 + and Br– ions. The Mg2+ cations are in the octahedral environment, Mg–O(H2O) and Mg–O(W) bond lengths being 2.102(5)÷2.044(5) Å and 2.071(5) Å, respectively.

AB - The X-ray crystal structure of (CH3NH3)4[(Mg(H2O)5)2(H6W12O42)]Br2·8H2O (1) obtained by a reaction of Li2WO4·H2O and Mg(NO3)2·6H2O in the presence of MeNH3Br is reported. Crystallographic parameters are: triclinic, space group P-1, a = 10.8280(4) Å, b = 12.4866(5) Å, c = 12.6201(5) Å, α = 108.501(1)°, β = 111.542(1)°, γ = 91.139(1)°, V = 1486.98(10) Å3, Z = 1, C4H66Br2Mg2N4O60W12, dx = 3.959 g/cm3, T = 150 K, R1 = 0.030 for 9914 Fo > 4δ(F) until 2θmax = 66.6° The structure contains tetraprotonated [H2W12O42]10– anions coordinated with {Mg(H2O)5}2+ cations as ditopic ligands via terminal oxygen atoms. The crystal structure also incorporates outer-sphere CH3NH3 + and Br– ions. The Mg2+ cations are in the octahedral environment, Mg–O(H2O) and Mg–O(W) bond lengths being 2.102(5)÷2.044(5) Å and 2.071(5) Å, respectively.

KW - crystal structure

KW - magnesium

KW - paratungstate B

KW - polyoxometalates

KW - CLUSTERS

KW - COMPLEXES

KW - IONS

KW - PARADODECATUNGSTATE

UR - http://www.scopus.com/inward/record.url?scp=85021202085&partnerID=8YFLogxK

U2 - 10.1134/S0022476617030222

DO - 10.1134/S0022476617030222

M3 - Article

AN - SCOPUS:85021202085

VL - 58

SP - 597

EP - 599

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -

ID: 8967782