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Crystal structure and thermal properties of N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato)palladium(II). / Cherkasov, S. A.; Vikulova, E. S.; Nikolaeva, N. S. et al.

In: Journal of Structural Chemistry, Vol. 58, No. 7, 01.12.2017, p. 1453-1456.

Research output: Contribution to journal › Article › peer-review

Harvard

Cherkasov, SA, Vikulova, ES, Nikolaeva, NS, Smolentsev, AI & Morozova, NB 2017, 'Crystal structure and thermal properties of N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato)palladium(II)', Journal of Structural Chemistry, vol. 58, no. 7, pp. 1453-1456. https://doi.org/10.1134/S0022476617070277

APA

Cherkasov, S. A., Vikulova, E. S., Nikolaeva, N. S., Smolentsev, A. I., & Morozova, N. B. (2017). Crystal structure and thermal properties of N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato)palladium(II). Journal of Structural Chemistry, 58(7), 1453-1456. https://doi.org/10.1134/S0022476617070277

Vancouver

Cherkasov SA, Vikulova ES, Nikolaeva NS, Smolentsev AI, Morozova NB. Crystal structure and thermal properties of N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato)palladium(II). Journal of Structural Chemistry. 2017 Dec 1;58(7):1453-1456. doi: 10.1134/S0022476617070277

Author

Cherkasov, S. A. ; Vikulova, E. S. ; Nikolaeva, N. S. et al. / Crystal structure and thermal properties of N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato)palladium(II). In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 7. pp. 1453-1456.

BibTeX

@article{36a4b2443885486db97e759158300d5e,
title = "Crystal structure and thermal properties of N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato)palladium(II)",
abstract = "[Pd(acacdmpda)] complex (1) is obtained for the first time by the interaction of [Pd(CH3CN)2Cl2], NaOH, and H2acacdmpda (acacdmpda = N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato-)) in acetonitrile. The compound is characterized by elemental analysis and IR spectroscopy; its structure is determined by single crystal X-ray diffraction. Complex 1 has a molecular structure. The coordination environment of the Pd2+ cation is a distorted square formed by O and N atoms of the tetradentately coordinated acacdmpda2– ligand. The average Pd–O and Pd–N bond lengths are 1.998(4) {\AA} and 2.016(4) {\AA} respectively. The N–Pd–O chelate angles are 92.34(10)° and 91.73(9)°; the N–Pd–N angle is 95.52(10)°. The thermal properties of 1 are studied by thermogravimetry. The complex passes quantitatively into the gas phase in the temperature range 225-325 °С.",
keywords = "MOCVD precursor, palladium(II), Schiff bases, single crystal X-ray diffraction analysis, thermogravimetry, SCHIFF-BASE PRECURSOR, PALLADIUM(II) COMPLEXES, MOCVD APPLICATIONS, CHEMICAL-VAPOR-DEPOSITION, FILM",
author = "Cherkasov, {S. A.} and Vikulova, {E. S.} and Nikolaeva, {N. S.} and Smolentsev, {A. I.} and Morozova, {N. B.}",
year = "2017",
month = dec,
day = "1",
doi = "10.1134/S0022476617070277",
language = "English",
volume = "58",
pages = "1453--1456",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "7",

}

RIS

TY - JOUR

T1 - Crystal structure and thermal properties of N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato)palladium(II)

AU - Cherkasov, S. A.

AU - Vikulova, E. S.

AU - Nikolaeva, N. S.

AU - Smolentsev, A. I.

AU - Morozova, N. B.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - [Pd(acacdmpda)] complex (1) is obtained for the first time by the interaction of [Pd(CH3CN)2Cl2], NaOH, and H2acacdmpda (acacdmpda = N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato-)) in acetonitrile. The compound is characterized by elemental analysis and IR spectroscopy; its structure is determined by single crystal X-ray diffraction. Complex 1 has a molecular structure. The coordination environment of the Pd2+ cation is a distorted square formed by O and N atoms of the tetradentately coordinated acacdmpda2– ligand. The average Pd–O and Pd–N bond lengths are 1.998(4) Å and 2.016(4) Å respectively. The N–Pd–O chelate angles are 92.34(10)° and 91.73(9)°; the N–Pd–N angle is 95.52(10)°. The thermal properties of 1 are studied by thermogravimetry. The complex passes quantitatively into the gas phase in the temperature range 225-325 °С.

AB - [Pd(acacdmpda)] complex (1) is obtained for the first time by the interaction of [Pd(CH3CN)2Cl2], NaOH, and H2acacdmpda (acacdmpda = N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato-)) in acetonitrile. The compound is characterized by elemental analysis and IR spectroscopy; its structure is determined by single crystal X-ray diffraction. Complex 1 has a molecular structure. The coordination environment of the Pd2+ cation is a distorted square formed by O and N atoms of the tetradentately coordinated acacdmpda2– ligand. The average Pd–O and Pd–N bond lengths are 1.998(4) Å and 2.016(4) Å respectively. The N–Pd–O chelate angles are 92.34(10)° and 91.73(9)°; the N–Pd–N angle is 95.52(10)°. The thermal properties of 1 are studied by thermogravimetry. The complex passes quantitatively into the gas phase in the temperature range 225-325 °С.

KW - MOCVD precursor

KW - palladium(II)

KW - Schiff bases

KW - single crystal X-ray diffraction analysis

KW - thermogravimetry

KW - SCHIFF-BASE PRECURSOR

KW - PALLADIUM(II) COMPLEXES

KW - MOCVD APPLICATIONS

KW - CHEMICAL-VAPOR-DEPOSITION

KW - FILM

UR - http://www.scopus.com/inward/record.url?scp=85039849764&partnerID=8YFLogxK

U2 - 10.1134/S0022476617070277

DO - 10.1134/S0022476617070277

M3 - Article

AN - SCOPUS:85039849764

VL - 58

SP - 1453

EP - 1456

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 7

ER -

ID: 9409283