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Crystal Structure and Properties of [Rh2(H2O)8(μ-OH)2](NO3)4·4H2O. / Berdyugin, S. N.; Vasilchenko, D. B.; Baidina, I. A. et al.

In: Journal of Structural Chemistry, Vol. 59, No. 3, 01.05.2018, p. 664-668.

Research output: Contribution to journal › Article › peer-review

Harvard

Berdyugin, SN, Vasilchenko, DB, Baidina, IA, Korenev, SV & Korolkov, IV 2018, 'Crystal Structure and Properties of [Rh2(H2O)8(μ-OH)2](NO3)4·4H2O', Journal of Structural Chemistry, vol. 59, no. 3, pp. 664-668. https://doi.org/10.1134/S002247661803023X

APA

Berdyugin, S. N., Vasilchenko, D. B., Baidina, I. A., Korenev, S. V., & Korolkov, I. V. (2018). Crystal Structure and Properties of [Rh2(H2O)8(μ-OH)2](NO3)4·4H2O. Journal of Structural Chemistry, 59(3), 664-668. https://doi.org/10.1134/S002247661803023X

Vancouver

Berdyugin SN, Vasilchenko DB, Baidina IA, Korenev SV, Korolkov IV. Crystal Structure and Properties of [Rh2(H2O)8(μ-OH)2](NO3)4·4H2O. Journal of Structural Chemistry. 2018 May 1;59(3):664-668. doi: 10.1134/S002247661803023X

Author

Berdyugin, S. N. ; Vasilchenko, D. B. ; Baidina, I. A. et al. / Crystal Structure and Properties of [Rh2(H2O)8(μ-OH)2](NO3)4·4H2O. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 3. pp. 664-668.

BibTeX

@article{6627e14def7948ba8efc996abf73e6fd,
title = "Crystal Structure and Properties of [Rh2(H2O)8(μ-OH)2](NO3)4·4H2O",
abstract = "A procedure to synthesize (μ-hydroxo)bis-pentaaquarhodium(III) nitrate tetrahydrate [Rh2(H2O)8(μ-OH)2](NO3)4·4H2O from potassium hexachlororhodiate(III) is elaborated. The compound is isolated into the solid phase and structurally characterized. The crystallographic data are as follows: a = 5.8763(2) {\AA}, b = 9.4749(4) {\AA}, c = 9.6249(3) {\AA}, α = 79.905(1)°, β = 84.324(1)°, γ = 82.922(1)°, space group P-1, Z = 1, ρcalc = 2.240 g/cm3. The compound is soluble in water, ethanol, and acetone. Hydrolysis takes place in concentrated nitric acid with the formation of mononuclear aqua- and aquanitrate complexes. Thermal decomposition of the salt at a temperature above 580 °C leads to the formation of a single product–rhodium(III) oxide.",
keywords = "bridging OH ligand, polycondensation of hydroxo complexes, polynuclear complexes, rhodium complexes, rhodium(III) nitrate, single crystal X-ray diffraction analysis, synthesis, RHODIUM(III), IONS",
author = "Berdyugin, {S. N.} and Vasilchenko, {D. B.} and Baidina, {I. A.} and Korenev, {S. V.} and Korolkov, {I. V.}",
year = "2018",
month = may,
day = "1",
doi = "10.1134/S002247661803023X",
language = "English",
volume = "59",
pages = "664--668",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

RIS

TY - JOUR

T1 - Crystal Structure and Properties of [Rh2(H2O)8(μ-OH)2](NO3)4·4H2O

AU - Berdyugin, S. N.

AU - Vasilchenko, D. B.

AU - Baidina, I. A.

AU - Korenev, S. V.

AU - Korolkov, I. V.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - A procedure to synthesize (μ-hydroxo)bis-pentaaquarhodium(III) nitrate tetrahydrate [Rh2(H2O)8(μ-OH)2](NO3)4·4H2O from potassium hexachlororhodiate(III) is elaborated. The compound is isolated into the solid phase and structurally characterized. The crystallographic data are as follows: a = 5.8763(2) Å, b = 9.4749(4) Å, c = 9.6249(3) Å, α = 79.905(1)°, β = 84.324(1)°, γ = 82.922(1)°, space group P-1, Z = 1, ρcalc = 2.240 g/cm3. The compound is soluble in water, ethanol, and acetone. Hydrolysis takes place in concentrated nitric acid with the formation of mononuclear aqua- and aquanitrate complexes. Thermal decomposition of the salt at a temperature above 580 °C leads to the formation of a single product–rhodium(III) oxide.

AB - A procedure to synthesize (μ-hydroxo)bis-pentaaquarhodium(III) nitrate tetrahydrate [Rh2(H2O)8(μ-OH)2](NO3)4·4H2O from potassium hexachlororhodiate(III) is elaborated. The compound is isolated into the solid phase and structurally characterized. The crystallographic data are as follows: a = 5.8763(2) Å, b = 9.4749(4) Å, c = 9.6249(3) Å, α = 79.905(1)°, β = 84.324(1)°, γ = 82.922(1)°, space group P-1, Z = 1, ρcalc = 2.240 g/cm3. The compound is soluble in water, ethanol, and acetone. Hydrolysis takes place in concentrated nitric acid with the formation of mononuclear aqua- and aquanitrate complexes. Thermal decomposition of the salt at a temperature above 580 °C leads to the formation of a single product–rhodium(III) oxide.

KW - bridging OH ligand

KW - polycondensation of hydroxo complexes

KW - polynuclear complexes

KW - rhodium complexes

KW - rhodium(III) nitrate

KW - single crystal X-ray diffraction analysis

KW - synthesis

KW - RHODIUM(III)

KW - IONS

UR - http://www.scopus.com/inward/record.url?scp=85049651048&partnerID=8YFLogxK

U2 - 10.1134/S002247661803023X

DO - 10.1134/S002247661803023X

M3 - Article

AN - SCOPUS:85049651048

VL - 59

SP - 664

EP - 668

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -

ID: 14446842