Standard

Crystal Structure and Properties of Iridium(I)(1,5-Cyclooctadiene) (η5-Tetramethylcyclopentadiene) [Ir(cod)CpMe4]. / Bonegardt, D. V.; Ilyin, I. Yu; Sukhikh, T. S. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 3, 01.03.2020, p. 456-465.

Research output: Contribution to journal › Article › peer-review

Harvard

Bonegardt, DV, Ilyin, IY, Sukhikh, TS, Ilyina, EV & Morozova, NB 2020, 'Crystal Structure and Properties of Iridium(I)(1,5-Cyclooctadiene) (η5-Tetramethylcyclopentadiene) [Ir(cod)CpMe4]', Journal of Structural Chemistry, vol. 61, no. 3, pp. 456-465. https://doi.org/10.1134/S0022476620030129

APA

Bonegardt, D. V., Ilyin, I. Y., Sukhikh, T. S., Ilyina, E. V., & Morozova, N. B. (2020). Crystal Structure and Properties of Iridium(I)(1,5-Cyclooctadiene) (η5-Tetramethylcyclopentadiene) [Ir(cod)CpMe4]. Journal of Structural Chemistry, 61(3), 456-465. https://doi.org/10.1134/S0022476620030129

Vancouver

Bonegardt DV, Ilyin IY, Sukhikh TS, Ilyina EV, Morozova NB. Crystal Structure and Properties of Iridium(I)(1,5-Cyclooctadiene) (η5-Tetramethylcyclopentadiene) [Ir(cod)CpMe4]. Journal of Structural Chemistry. 2020 Mar 1;61(3):456-465. doi: 10.1134/S0022476620030129

Author

Bonegardt, D. V. ; Ilyin, I. Yu ; Sukhikh, T. S. et al. / Crystal Structure and Properties of Iridium(I)(1,5-Cyclooctadiene) (η5-Tetramethylcyclopentadiene) [Ir(cod)CpMe4]. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 3. pp. 456-465.

BibTeX

@article{1ed3ae4bc1ae451e8fa2d9b4211994f7,
title = "Crystal Structure and Properties of Iridium(I)(1,5-Cyclooctadiene) (η5-Tetramethylcyclopentadiene) [Ir(cod)CpMe4]",
abstract = "Volatile iridium complex [Ir(cod)CpMe4] (CpMe4 is tetramettiylcyclopentadienyl, cod is 1,5-cyclooctadiene) is synthesized and characterized by IR and NMR spectroscopy methods. The complex is a solid phase under standard conditions and crystallizes in the form of colorless needle shaped crystals. The structure of [Ir(cod)CpMe4] is solved by X-ray diffraction: chemical formula IrC17H25, space group P-1, a = 6.4631(3) {\AA}, b = 8.4620(4) {\AA}, c = 13.5577(8) {\AA}, α = 85.770(2)°, β = 84.611(2)°, γ = 78.013(2)°, V = 720.99(6) {\AA}3, Z = 2, dcalc = 1.942 g/cm3, μ = 9.240 mm−1. Tetramethylcyclopentadienyl is a η5-coordinated ligand, 1,5-cyclooctadiene is a η4-coordinated ligand in the cis-cis conformation. According to the thermogravimetric data, the complex transfers to the gas phase congruently upon heating.",
keywords = "1,5-cyclooctadiene, iridium(I), MOCVD precursor, tetramethylcyclopentadiene, thermogravimetric analysis, X-ray diffraction analysis, 1, CHEMICAL-VAPOR-DEPOSITION, 5-cyclooctadiene, METAL, IRIDIUM OXIDE-FILMS",
author = "Bonegardt, {D. V.} and Ilyin, {I. Yu} and Sukhikh, {T. S.} and Ilyina, {E. V.} and Morozova, {N. B.}",
year = "2020",
month = mar,
day = "1",
doi = "10.1134/S0022476620030129",
language = "English",
volume = "61",
pages = "456--465",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

RIS

TY - JOUR

T1 - Crystal Structure and Properties of Iridium(I)(1,5-Cyclooctadiene) (η5-Tetramethylcyclopentadiene) [Ir(cod)CpMe4]

AU - Bonegardt, D. V.

AU - Ilyin, I. Yu

AU - Sukhikh, T. S.

AU - Ilyina, E. V.

AU - Morozova, N. B.

PY - 2020/3/1

Y1 - 2020/3/1

N2 - Volatile iridium complex [Ir(cod)CpMe4] (CpMe4 is tetramettiylcyclopentadienyl, cod is 1,5-cyclooctadiene) is synthesized and characterized by IR and NMR spectroscopy methods. The complex is a solid phase under standard conditions and crystallizes in the form of colorless needle shaped crystals. The structure of [Ir(cod)CpMe4] is solved by X-ray diffraction: chemical formula IrC17H25, space group P-1, a = 6.4631(3) Å, b = 8.4620(4) Å, c = 13.5577(8) Å, α = 85.770(2)°, β = 84.611(2)°, γ = 78.013(2)°, V = 720.99(6) Å3, Z = 2, dcalc = 1.942 g/cm3, μ = 9.240 mm−1. Tetramethylcyclopentadienyl is a η5-coordinated ligand, 1,5-cyclooctadiene is a η4-coordinated ligand in the cis-cis conformation. According to the thermogravimetric data, the complex transfers to the gas phase congruently upon heating.

AB - Volatile iridium complex [Ir(cod)CpMe4] (CpMe4 is tetramettiylcyclopentadienyl, cod is 1,5-cyclooctadiene) is synthesized and characterized by IR and NMR spectroscopy methods. The complex is a solid phase under standard conditions and crystallizes in the form of colorless needle shaped crystals. The structure of [Ir(cod)CpMe4] is solved by X-ray diffraction: chemical formula IrC17H25, space group P-1, a = 6.4631(3) Å, b = 8.4620(4) Å, c = 13.5577(8) Å, α = 85.770(2)°, β = 84.611(2)°, γ = 78.013(2)°, V = 720.99(6) Å3, Z = 2, dcalc = 1.942 g/cm3, μ = 9.240 mm−1. Tetramethylcyclopentadienyl is a η5-coordinated ligand, 1,5-cyclooctadiene is a η4-coordinated ligand in the cis-cis conformation. According to the thermogravimetric data, the complex transfers to the gas phase congruently upon heating.

KW - 1,5-cyclooctadiene

KW - iridium(I)

KW - MOCVD precursor

KW - tetramethylcyclopentadiene

KW - thermogravimetric analysis

KW - X-ray diffraction analysis

KW - 1

KW - CHEMICAL-VAPOR-DEPOSITION

KW - 5-cyclooctadiene

KW - METAL

KW - IRIDIUM OXIDE-FILMS

UR - http://www.scopus.com/inward/record.url?scp=85088628247&partnerID=8YFLogxK

U2 - 10.1134/S0022476620030129

DO - 10.1134/S0022476620030129

M3 - Article

AN - SCOPUS:85088628247

VL - 61

SP - 456

EP - 465

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -

ID: 24833215