CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF RHENIUM CLUSTERS [{Re 6(μ 3-Q) 8}(imz-[1,2-a]py) 6]Br 2

CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF RHENIUM CLUSTERS [{Re ₆(μ ₃-Q) ₈}(imz-[1,2-a]py) ₆]Br ₂. / Bardin, V. A.; Ivanov, A. A.; Konovalov, D. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 10, 10.2020, p. 1624-1629.

Research output: Contribution to journal › Article › peer-review

Bardin, VA, Ivanov, AA, Konovalov, D, Smolentsev, A & Shestopalov, MA 2020, 'CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF RHENIUM CLUSTERS [{Re ₆(μ ₃-Q) ₈}(imz-[1,2-a]py) ₆]Br ₂', Journal of Structural Chemistry, vol. 61, no. 10, pp. 1624-1629. https://doi.org/10.1134/S0022476620100157

Bardin, V. A., Ivanov, A. A., Konovalov, D., Smolentsev, A., & Shestopalov, M. A. (2020). CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF RHENIUM CLUSTERS [{Re ₆(μ ₃-Q) ₈}(imz-[1,2-a]py) ₆]Br ₂. Journal of Structural Chemistry, 61(10), 1624-1629. https://doi.org/10.1134/S0022476620100157

Bardin VA, Ivanov AA, Konovalov D, Smolentsev A, Shestopalov MA. CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF RHENIUM CLUSTERS [{Re ₆(μ ₃-Q) ₈}(imz-[1,2-a]py) ₆]Br ₂. Journal of Structural Chemistry. 2020 Oct;61(10):1624-1629. doi: 10.1134/S0022476620100157

Bardin, V. A. ; Ivanov, A. A. ; Konovalov, D. et al. / CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF RHENIUM CLUSTERS [{Re ₆(μ ₃-Q) ₈}(imz-[1,2-a]py) ₆]Br ₂. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 10. pp. 1624-1629.

@article{4d212676158643b68d54691bc7f4adf3,

title = "CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF RHENIUM CLUSTERS [{Re 6(μ 3-Q) 8}(imz-[1,2-a]py) 6]Br 2",

abstract = "Abstract: Octahedral rhenium cluster complexes of the composition [{Re 6(μ 3-Q) 8}(imz-[1,2-a]py) 6]Br 2, where Q = S, Se, are obtained by the interaction of Cs n[{Re 6(μ 3-Q 8)}Br 6] (n = 4 for Q = S; n = 3 for Q = Se) with an excess of imidazo-[1,2-а]pyridine in a sealed glass ampoule at 180 °С within two days. Both compounds are isostructural and crystallize in the trigonal space group R 3. The crystal structure of the complexes represents three differently directed chains of [{Re 6Q 8}(imz-[1,2-a]py) 6] 2+ cations and bromine anions linked with each other by С–H⋯Br⋯H–C hydrogen bonds. The compounds obtained have pronounced luminescence with emission maxima at 652 nm and 678 nm for Q = S, Se respectively. ",

keywords = "rhenium, crystal structure, octahedral chalcogenide clusters, imidazo-[1,2-a]pyridine, luminescence, HEXARHENIUM(III) CLUSTERS, BASIS-SET, COMPLEXES, METHYLATION, FAMILY, BR, CL, imidazo-[1,2-а]pyridine",

author = "Bardin, {V. A.} and Ivanov, {A. A.} and D. Konovalov and A. Smolentsev and Shestopalov, {M. A.}",

year = "2020",

month = oct,

doi = "10.1134/S0022476620100157",

language = "English",

volume = "61",

pages = "1624--1629",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "10",

}

TY - JOUR

T1 - CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF RHENIUM CLUSTERS [{Re 6(μ 3-Q) 8}(imz-[1,2-a]py) 6]Br 2

AU - Bardin, V. A.

AU - Ivanov, A. A.

AU - Konovalov, D.

AU - Smolentsev, A.

AU - Shestopalov, M. A.

PY - 2020/10

Y1 - 2020/10

N2 - Abstract: Octahedral rhenium cluster complexes of the composition [{Re 6(μ 3-Q) 8}(imz-[1,2-a]py) 6]Br 2, where Q = S, Se, are obtained by the interaction of Cs n[{Re 6(μ 3-Q 8)}Br 6] (n = 4 for Q = S; n = 3 for Q = Se) with an excess of imidazo-[1,2-а]pyridine in a sealed glass ampoule at 180 °С within two days. Both compounds are isostructural and crystallize in the trigonal space group R 3. The crystal structure of the complexes represents three differently directed chains of [{Re 6Q 8}(imz-[1,2-a]py) 6] 2+ cations and bromine anions linked with each other by С–H⋯Br⋯H–C hydrogen bonds. The compounds obtained have pronounced luminescence with emission maxima at 652 nm and 678 nm for Q = S, Se respectively.

AB - Abstract: Octahedral rhenium cluster complexes of the composition [{Re 6(μ 3-Q) 8}(imz-[1,2-a]py) 6]Br 2, where Q = S, Se, are obtained by the interaction of Cs n[{Re 6(μ 3-Q 8)}Br 6] (n = 4 for Q = S; n = 3 for Q = Se) with an excess of imidazo-[1,2-а]pyridine in a sealed glass ampoule at 180 °С within two days. Both compounds are isostructural and crystallize in the trigonal space group R 3. The crystal structure of the complexes represents three differently directed chains of [{Re 6Q 8}(imz-[1,2-a]py) 6] 2+ cations and bromine anions linked with each other by С–H⋯Br⋯H–C hydrogen bonds. The compounds obtained have pronounced luminescence with emission maxima at 652 nm and 678 nm for Q = S, Se respectively.

KW - rhenium

KW - crystal structure

KW - octahedral chalcogenide clusters

KW - imidazo-[1,2-a]pyridine

KW - luminescence

KW - HEXARHENIUM(III) CLUSTERS

KW - BASIS-SET

KW - COMPLEXES

KW - METHYLATION

KW - FAMILY

KW - BR

KW - CL

KW - imidazo-[1,2-а]pyridine

UR - http://www.scopus.com/inward/record.url?scp=85106832922&partnerID=8YFLogxK

U2 - 10.1134/S0022476620100157

DO - 10.1134/S0022476620100157

M3 - Article

VL - 61

SP - 1624

EP - 1629

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 10

ER -

CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF RHENIUM CLUSTERS [{Re ₆(μ ₃-Q) ₈}(imz-[1,2-a]py) ₆]Br ₂

Standard

Harvard

APA

Vancouver

Author

BibTeX

RIS