Research output: Contribution to journal › Article › peer-review
Crystal structure and EPR spectra of (Bu4N)2[V(dmit)3]. / Fomenko, Ya S.; Gushchin, A. L.; Nadolinny, V. A. et al.
In: Journal of Structural Chemistry, Vol. 58, No. 5, 01.09.2017, p. 964-969.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Crystal structure and EPR spectra of (Bu4N)2[V(dmit)3]
AU - Fomenko, Ya S.
AU - Gushchin, A. L.
AU - Nadolinny, V. A.
AU - Abramov, P. A.
AU - Sokolov, M. N.
PY - 2017/9/1
Y1 - 2017/9/1
N2 - The tris-chelate complex of vanadium(IV) (Bu4N)2[V(dmit)3] is prepared from VCl3 and (Bu4N)2[Zn(dmit)2] (dmit = isotrithionedithiolate C3S5 2–) and characterized by single crystal XRD and mass spectrometry. The complex crystallizes in the space group Pna21 and has a distorted octahedral environment of vanadium. The complex is paramagnetic and gives a characteristic EPR spectrum in both solution and solid phase. The g factors and hyperfine interaction constants are determined.
AB - The tris-chelate complex of vanadium(IV) (Bu4N)2[V(dmit)3] is prepared from VCl3 and (Bu4N)2[Zn(dmit)2] (dmit = isotrithionedithiolate C3S5 2–) and characterized by single crystal XRD and mass spectrometry. The complex crystallizes in the space group Pna21 and has a distorted octahedral environment of vanadium. The complex is paramagnetic and gives a characteristic EPR spectrum in both solution and solid phase. The g factors and hyperfine interaction constants are determined.
KW - crystal structure
KW - dithiolate complexes
KW - EPR spectra
KW - vanadium
UR - http://www.scopus.com/inward/record.url?scp=85032292291&partnerID=8YFLogxK
U2 - 10.1134/S0022476617050158
DO - 10.1134/S0022476617050158
M3 - Article
AN - SCOPUS:85032292291
VL - 58
SP - 964
EP - 969
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 5
ER -
ID: 9873539