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Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li2Zn2(py)2(piv)6]. / Sapianik, A. A.; Dudko, E. R.; Samsonenko, D. G. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 12, 12.2020, p. 1957-1964.

Research output: Contribution to journal › Article › peer-review

Harvard

Sapianik, AA, Dudko, ER, Samsonenko, DG & Fedin, VP 2020, 'Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li2Zn2(py)2(piv)6]', Journal of Structural Chemistry, vol. 61, no. 12, pp. 1957-1964. https://doi.org/10.1134/S0022476620120148

APA

Sapianik, A. A., Dudko, E. R., Samsonenko, D. G., & Fedin, V. P. (2020). Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li2Zn2(py)2(piv)6]. Journal of Structural Chemistry, 61(12), 1957-1964. https://doi.org/10.1134/S0022476620120148

Vancouver

Sapianik AA, Dudko ER, Samsonenko DG, Fedin VP. Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li2Zn2(py)2(piv)6]. Journal of Structural Chemistry. 2020 Dec;61(12):1957-1964. doi: 10.1134/S0022476620120148

Author

Sapianik, A. A. ; Dudko, E. R. ; Samsonenko, D. G. et al. / Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li2Zn2(py)2(piv)6]. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 12. pp. 1957-1964.

BibTeX

@article{f654f3691cf54f0e95a7709fb81d46d1,
title = "Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li2Zn2(py)2(piv)6]",
abstract = "In the interaction of the heterometallic complex [Li2Zn2(py)2(piv)6] (piv– is the pivalate anion, py is pyridine) with 2,5-dibromoterephthalic acid (H2Br2-bdc) or 9,10-anthracenedicarboxylic acid (H2adc), two coordination polymers [Li(DMF)(HBr2-bdc)] (1) and (Me2NH2)[Zn(Hadc) (adc)]·DMF·H2O (2) are obtained. During the synthesis, the initial tetranuclear heterometallic fragment is completely fragmentated. When the same complex interacts with nitroterephthalic acid (H2NO2-bdc), a heterometallic metal-organic framework (Me2NH2)[LiZn(NO2- bdc)2]·DMF (3) is formed. Resulting coordination polymer 3 has a three-dimensional porous structure; binuclear heterometallic carboxylate moieties {LiZn(COO)3} act as secondary building blocks.",
keywords = "coordination polymers, heterometallic complexes, lithium, polycarboxylic acids, X-ray diffraction analysis, zinc, DESIGN, INFINITE POLYMERIC FRAMEWORKS",
author = "Sapianik, {A. A.} and Dudko, {E. R.} and Samsonenko, {D. G.} and Fedin, {V. P.}",
note = "Funding Information: The study was supported by the Russian Science Foundation (project No. 19-73-00171). Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = dec,
doi = "10.1134/S0022476620120148",
language = "English",
volume = "61",
pages = "1957--1964",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "12",

}

RIS

TY - JOUR

T1 - Crictal structure of metal-organic frameworks obtained from a heterometallic pivalate complex [Li2Zn2(py)2(piv)6]

AU - Sapianik, A. A.

AU - Dudko, E. R.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

N1 - Funding Information: The study was supported by the Russian Science Foundation (project No. 19-73-00171). Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/12

Y1 - 2020/12

N2 - In the interaction of the heterometallic complex [Li2Zn2(py)2(piv)6] (piv– is the pivalate anion, py is pyridine) with 2,5-dibromoterephthalic acid (H2Br2-bdc) or 9,10-anthracenedicarboxylic acid (H2adc), two coordination polymers [Li(DMF)(HBr2-bdc)] (1) and (Me2NH2)[Zn(Hadc) (adc)]·DMF·H2O (2) are obtained. During the synthesis, the initial tetranuclear heterometallic fragment is completely fragmentated. When the same complex interacts with nitroterephthalic acid (H2NO2-bdc), a heterometallic metal-organic framework (Me2NH2)[LiZn(NO2- bdc)2]·DMF (3) is formed. Resulting coordination polymer 3 has a three-dimensional porous structure; binuclear heterometallic carboxylate moieties {LiZn(COO)3} act as secondary building blocks.

AB - In the interaction of the heterometallic complex [Li2Zn2(py)2(piv)6] (piv– is the pivalate anion, py is pyridine) with 2,5-dibromoterephthalic acid (H2Br2-bdc) or 9,10-anthracenedicarboxylic acid (H2adc), two coordination polymers [Li(DMF)(HBr2-bdc)] (1) and (Me2NH2)[Zn(Hadc) (adc)]·DMF·H2O (2) are obtained. During the synthesis, the initial tetranuclear heterometallic fragment is completely fragmentated. When the same complex interacts with nitroterephthalic acid (H2NO2-bdc), a heterometallic metal-organic framework (Me2NH2)[LiZn(NO2- bdc)2]·DMF (3) is formed. Resulting coordination polymer 3 has a three-dimensional porous structure; binuclear heterometallic carboxylate moieties {LiZn(COO)3} act as secondary building blocks.

KW - coordination polymers

KW - heterometallic complexes

KW - lithium

KW - polycarboxylic acids

KW - X-ray diffraction analysis

KW - zinc

KW - DESIGN

KW - INFINITE POLYMERIC FRAMEWORKS

UR - http://www.scopus.com/inward/record.url?scp=85098050992&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/44755cfe-5758-309e-9339-0af5e16ef5ad/

U2 - 10.1134/S0022476620120148

DO - 10.1134/S0022476620120148

M3 - Article

AN - SCOPUS:85098050992

VL - 61

SP - 1957

EP - 1964

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 12

ER -

ID: 27329894